Cobalt-Based Catalysts for CO Preferential Oxidation

In this work, catalysts based on cobalt supported on ZrO2 and CeO2 and CoCeMnOx were studied for the CO preferential oxidation (COPrOx) in hydrogen-rich stream able to feed fuel cells. Among them, the CoCeMnOx formulation showed the highest CO conversion at low temperatures, while the cobalt oxide supported on ceria presented the best selectivity toward CO2. The Co3O4 spinel was the active phase for the CO preferential oxidation detected in all catalysts. However, the CoOx-CeO2 and CoCeMnOx catalysts resulted more active than cobalt oxide supported on zirconia. The presence of ceria close to cobalt species promotes the redox properties and enhances the catalytic activity. In the CoCeMnOx catalyst prepared by coprecipitation, the incorporation of Mn represented an additional positive effect. The presence of Mn promoted the reoxidation of Co2+ to Co3+ and, consequently, the activity increased at low temperature. By X-ray diffraction (XRD) of CoOx-ZrO2 and the CoOx-CeO2 catalysts, the Co3O4 spinel and ZrO2 or CeO2 were identified in agreement with laser-Raman spectra. At the same time, the CoCeMnOx catalyst, prepared by coprecipitation of precursor salts, showed an incipient development of a new phase (Mn,Co)3O4 mixed spinel, due to the intimate contact between elements

Trabajo temporal y siniestralidad laboral en España en el período 1988 - 1995.

Sin resume

Eco-geomorphological connectivity and coupling interactions at hillslope scale in drylands: Concepts and critical examples

The diagnosis of land degradation requires a deep understanding of ecosystem functioning and evolution. In dryland systems, in particular, research efforts must address the redistribution of scarce resources for vegetation, in a context of high spatial heterogeneity and non-linear response. This fact explains the prevalence of eco-hydrological perspectives interested in runoff processes and, the more recent, focused on connectivity as an indicator of system resource optimisation. From a geomorphological perspective and reviewing the concepts of eco-hydro-geomorphological interactions operating in ecosystems, this paper explores the effects of erosion on vegetation configuration through two case studies at different spatio-temporal scales. We focus on the structure-function linkage, specifically on how morphological traits relate with different stages in the erosional sequence, both in the abiotic and the biotic domain. Results suggest that vegetation dynamics are affected by structural boundary conditions at both scales, i.e. by surface armouring related with rock fragments at the patch scale, and by the degree of hillslope-channel coupling at the hillslope scale. Our preliminary results can serve as new working hypotheses about the structure-function interplay on hillslopes. All this, taking advantage of the recent technological achievements for acquiring very high-resolution geospatial data that offer new analytical possibilities in a range of scales

Light-Trap: A SiPM Upgrade for Very High Energy Astronomy and Beyond

With the development of the Imaging Atmospheric Cherenkov Technique (IACT), Gamma-ray astronomy has become one of the most interesting and productive fields of astrophysics. Current IACT telescope arrays (MAGIC, H.E.S.S, VERITAS) use photomultiplier tubes (PMTs) to detect the optical/near-UV Cherenkov radiation emitted due to the interaction of gamma rays with the atmosphere. For the next generation of IACT experiments, the possibility of replacing the PMTs with Silicon photomultipliers (SiPMs) is being studied. Among the main drawbacks of SiPMs are their limited active area (leading to an increase in the cost and complexity of the camera readout) and their sensitivity to unwanted wavelengths. Here we propose a novel method to build a relatively low-cost pixel consisting of a SiPM attached to a PMMA disc doped with a wavelength shifter. This pixel collects light over a much larger area than a single standard SiPM and improves sensitivity to near-UV light while simultaneously rejecting background. We describe the design of a detector that could also have applications in other fields where detection area and cost are crucial. We present results of simulations and laboratory measurements of a pixel prototype and from field tests performed with a 7-pixel cluster installed in a MAGIC telescope camera.Comment: Proceedings of the 35th International Cosmic Ray Conference (ICRC 2017), Bexco, Busan, Korea. Id:81

BIOTIC AND ABIOTIC EVENTS IN A SHALLOW CARBONATE PLATFORM (UPPER CRETACEOUS, SOUTH PYRENEAN MARGIN)

Πραγματοποιήθηκε μία λεπτoμεpής ιζηματολογική και παλαιοντολογική μελέτη των αποθέσεων ανθρακικής πλατφόρμας της περιοχής Serres Marginals (νότιο περιθώριο της Λεκάνης των Πυρρηναίων) και αναγνωρίσθηκαν τρεις ακολουθίες ρηχών ανθρακικών αποθέσεων (Cl, C2 και C3). Εντός των αποθέσεων ρηχής πλατφόρμας περιγράφονται ενδιάμεσης ενέργειας υποπαλιρροιακές έως ενδοπαλιρροιακές φάσεις, αβαθείς άμμοι υψηλής ενέργειας καθώς και λιμνοθαλάσσια έως λιμναία περιβάλλοντα.A detailed sedimentological and paleontological study of the Late Santonian-Late Campanian carbonate platform deposits of the Serres Marginals area (South margin of the Pyrenean Basin) has been performed. Three depositional shallow carbonate sequences have been distinguished (CI, C2 and C3). Within the shallow platform sequences moderate energy subtidal to intertidal, high energy sand-shoal, protected lagoon and restricted lagoon to lacustrine fades have been identified

Incision and width changes caused by dam removal. Experiments and data analysis

River morphodynamics and sediment transportRiver morphology and morphodynamic

A Light Calibration System for the ProtoDUNE-DP Detector

A LED-based fiber calibration system for the ProtoDUNE-Dual Phase (DP) photon detection system (PDS) has been designed and validated. ProtoDUNE-DP is a 6x6x6 m3 liquid argon time-projection-chamber currently being installed at the Neutrino Platform at CERN. The PDS is based on 36 8-inch photomultiplier tubes (PMTs) and will allow triggering on cosmic rays. The system serves as prototype for the PDS of the final DUNE DP far detector in which the PDS also has the function to allow the 3D event reconstruction on non-beam physics. For this purpose an equalized PMT response is desirable to allow using the same threshold definition for all PMT groups, simplifying the determination of the trigger efficiency. The light calibration system described in this paper is developed to provide this and to monitor the PMT performance in-situ.Comment: 15 pages, 5 figure

Analytical methodologies based on LC–MS/MS for monitoring selected emerging compounds in liquid and solid phases of the sewage sludge

In this work, two analytical methodologies based on liquid chromatography coupled to tandem mass spectrometry (LC–MS/MS) were developed for quantification of emerging pollutants identified in sewage sludge after a previous wide-scope screening. The target list included 13 emerging contaminants (EC): thiabendazole, acesulfame, fenofibric acid, valsartan, irbesartan, salicylic acid, diclofenac, carbamazepine, 4-aminoantipyrine (4- AA), 4-acetyl aminoantipyrine (4-AAA), 4-formyl aminoantipyrine (4-FAA), venlafaxine and benzoylecgonine. The aqueous and solid phases of the sewage sludge were analyzed making use of Solid-Phase Extraction (SPE) and UltraSonic Extraction (USE) for sample treatment, respectively. The methods were validated at three concentration levels: 0.2, 2 and 20mg L 1 for the aqueous phase, and 50, 500 and 2000mg kg 1 for the solid phase of the sludge. In general, the method was satisfactorily validated, showing good recoveries (70–120%) and precision (RSD < 20%). Regarding the limit of quantification (LOQ), it was below 0.1mg L 1 in the aqueous phase and below 50mg kg 1 in the solid phase for the majority of the analytes. The method applicability was tested by analysis of samples from a wider study on degradation of emerging pollutants in sewage sludge under anaerobic digestion. The key benefits of these methodologies are: SPE and USE are appropriate sample procedures to extract selected emerging contaminants from the aqueous phase of the sewage sludge and the solid residue. LC–MS/MS is highly suitable for determining emerging contaminants in both sludge phases. Up to our knowledge, the main metabolites of dipyrone had not been studied before in sewage sludge. ãFinancial support of Generalitat Valenciana (Prometeo II/2014/023,ISIC/2014/016