168 research outputs found
Electronic and atomic shell structure in aluminum nanowires
We report experiments on aluminum nanowires in ultra-high vacuum at room
temperature that reveal a periodic spectrum of exceptionally stable structures.
Two "magic" series of stable structures are observed: At low conductance, the
formation of stable nanowires is governed by electronic shell effects whereas
for larger contacts atomic packing dominates. The crossover between the two
regimes is found to be smooth. A detailed comparison of the experimental
results to a theoretical stability analysis indicates that while the main
features of the observed electron-shell structure are similar to those of
alkali and noble metals, a sequence of extremely stable wires plays a unique
role in Aluminum. This series appears isolated in conductance histograms and
can be attributed to "superdeformed" non-axisymmetric nanowires.Comment: 15 pages, 9 figure
Quantum Necking in Stressed Metallic Nanowires
When a macroscopic metallic wire is subject to tensile stress, it necks down
smoothly as it elongates. We show that nanowires with radii comparable to the
Fermi wavelength display remarkably different behavior. Using concepts from
fluid dynamics, a PDE for nanowire shape evolution is derived from a
semiclassical energy functional that includes electron-shell effects. A rich
dynamics involving movement and interaction of kinks connecting locally stable
radii is found, and a new class of universal equilibrium shapes is predicted.Comment: 4 pages, 3 postscript figures. New result on universal equilibrium
shape
The Order of Phase Transitions in Barrier Crossing
A spatially extended classical system with metastable states subject to weak
spatiotemporal noise can exhibit a transition in its activation behavior when
one or more external parameters are varied. Depending on the potential, the
transition can be first or second-order, but there exists no systematic theory
of the relation between the order of the transition and the shape of the
potential barrier. In this paper, we address that question in detail for a
general class of systems whose order parameter is describable by a classical
field that can vary both in space and time, and whose zero-noise dynamics are
governed by a smooth polynomial potential. We show that a quartic potential
barrier can only have second-order transitions, confirming an earlier
conjecture [1]. We then derive, through a combination of analytical and
numerical arguments, both necessary conditions and sufficient conditions to
have a first-order vs. a second-order transition in noise-induced activation
behavior, for a large class of systems with smooth polynomial potentials of
arbitrary order. We find in particular that the order of the transition is
especially sensitive to the potential behavior near the top of the barrier.Comment: 8 pages, 6 figures with extended introduction and discussion; version
accepted for publication by Phys. Rev.
Stability of Metal Nanowires at Ultrahigh Current Densities
We develop a generalized grand canonical potential for the ballistic
nonequilibrium electron distribution in a metal nanowire with a finite applied
bias voltage. Coulomb interactions are treated in the self-consistent Hartree
approximation, in order to ensure gauge invariance. Using this formalism, we
investigate the stability and cohesive properties of metallic nanocylinders at
ultrahigh current densities. A linear stability analysis shows that metal
nanowires with certain {\em magic conductance values} can support current
densities up to 10^11 A/cm^2, which would vaporize a macroscopic piece of
metal. This finding is consistent with experimental studies of gold nanowires.
Interestingly, our analysis also reveals the existence of reentrant stability
zones--geometries that are stable only under an applied bias.Comment: 12 pages, 6 figures, version published in PR
2-Chlorodeoxyadenosine (2-CDA) therapy in previously untreated patients with follicular stage III-IV non-Hodgkin's lymphoma
Decoupling of optoelectronic properties from morphological changes in sodium treated kesterite thin film solar cells
Sodium is typically used during the synthesis of kesterite thin films to enhance the performance of solar cells. As sodium tends to affect grain growth and morphology, it is difficult to analyse solely the electronic effects of sodium as dopant. To decouple the structural and electronic effects from each other, two processes were designed in this work to successfully incorporate sodium into a vacuum-processed Cu2ZnSnSe4absorber without changing the morphology. A thin layer of NaF is deposited before precursor deposition (Pre-NaF) or after absorber synthesis to undergo a post deposition treatment (NaF-PDT). While composition and distribution of matrix elements remain unchanged, the sodium concentration is increased upon sodium treatment up to 140 ppm as measured by inductively coupled plasma mass spectrometry. X-ray photoelectron spectroscopy showed that the surface composition was not altered. Within its detection limit, sodium was not present at the absorber surface. For a Pre-NaF sample measured with atom probe tomography a sodium concentration of 30 ppm was measured in a grain, suggesting that sodium might segregate at grain boundaries. The additional sodium content in the film leads to an increased acceptor concentration, which results in improved open-circuit voltage and fill factor.Financial support from the Swiss National Science Foundation (SNF)
in the network of the Indo-Swiss Joint Research Programme (ISJRP)
[IZLIZ2_157140/1] is gratefully acknowledged. T. Schwarz is grateful for the support of the
German Research Foundation (DFG) [Contract GA 2450/1-1]. R.
Caballero acknowledges financial support from Spanish MINECO
within the RamĂłn y Cajal program [RYC-2011-08521], MINECO project
WINCOST [ENE2016-80788-C5-2-R] and from Spanish Ministry of
Education, Culture and Sport within the José Castillejo program [CAS
15/00070
From favorable atomic configurations to supershell structures: a new interpretation of conductance histograms
Title: From favorable atomic configurations to supershell structures: a new
interpretation of conductance histograms Authors: A. Hasmy (IVIC), E. Medina
(IVIC), P.A. Serena (CSIC,IVIC) Comments: 7 pages, 3 figures,
cond-mat.anwar.10825 Subj-class: Soft Condensed MatterComment: 7 pages, 3 figuresSubject: fput HMS.tex HMS-FIG1.ps HMS-FIG2.ps
HMS-FIG3.p
The number of transmission channels through a single-molecule junction
We calculate transmission eigenvalue distributions for Pt-benzene-Pt and
Pt-butadiene-Pt junctions using realistic state-of-the-art many-body
techniques. An effective field theory of interacting -electrons is used to
include screening and van der Waals interactions with the metal electrodes. We
find that the number of dominant transmission channels in a molecular junction
is equal to the degeneracy of the molecular orbital closest to the metal Fermi
level.Comment: 9 pages, 8 figure
Intention to Inform Relatives, Rates of Cascade Testing, and Preference for Patient-Mediated Communication in Families Concerned with Hereditary Breast and Ovarian Cancer and Lynch Syndrome: The Swiss CASCADE Cohort.
Cascade screening for Tier 1 cancer genetic conditions is a significant public health intervention because it identifies untested relatives of individuals known to carry pathogenic variants associated with hereditary breast and ovarian cancer (HBOC) and Lynch syndrome (LS). The Swiss CASCADE is a family-based, open-ended cohort, including carriers of HBOC- and LS-associated pathogenic variants and their relatives. This paper describes rates of cascade screening in relatives from HBOC- and LS- harboring families, examines carriers' preferences for communication of testing results, and describes theory-based predictors of intention to invite relatives to a cascade screening program. Information has been provided by 304 index cases and 115 relatives recruited from September 2017 to December 2021. On average, 10 relatives per index case were potentially eligible for cascade screening. Approximately 65% of respondents wanted to invite relatives to the cohort, and approximately 50% indicated a preference for patient-mediated communication of testing results, possibly with the assistance of digital technology. Intention to invite relatives was higher for first- compared to second- and third-degree relatives, but was not different between syndromes or based on relatives' gender. The family environment and carrying pathogenic variants predicts intention to invite relatives. Information helps optimize delivery of tailored genetic services
Macro-Climatic Distribution Limits Show Both Niche Expansion and Niche Specialization among C4 Panicoids
Grasses are ancestrally tropical understory species whose current dominance in warm open habitats is linked to the evolution of C4 photosynthesis. C4 grasses maintain high rates of photosynthesis in warm and water stressed environments, and the syndrome is considered to induce niche shifts into these habitats while adaptation to cold ones may be compromised. Global biogeographic analyses of C4 grasses have, however, concentrated on diversity patterns, while paying little attention to distributional limits. Using phylogenetic contrast analyses, we compared macro-climatic distribution limits among ~1300 grasses from the subfamily Panicoideae, which includes 4/5 of the known photosynthetic transitions in grasses. We explored whether evolution of C4 photosynthesis correlates with niche expansions, niche changes, or stasis at subfamily level and within the two tribes Paniceae and Paspaleae. We compared the climatic extremes of growing season temperatures, aridity, and mean temperatures of the coldest months. We found support for all the known biogeographic distribution patterns of C4 species, these patterns were, however, formed both by niche expansion and niche changes. The only ubiquitous response to a change in the photosynthetic pathway within Panicoideae was a niche expansion of the C4 species into regions with higher growing season temperatures, but without a withdrawal from the inherited climate niche. Other patterns varied among the tribes, as macro-climatic niche evolution in the American tribe Paspaleae differed from the pattern supported in the globally distributed tribe Paniceae and at family level.Fil: Aagesen, Lone. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Instituto de Botánica Darwinion. Academia Nacional de Ciencias Exactas, FĂsicas y Naturales. Instituto de Botánica Darwinion; ArgentinaFil: Biganzoli, Fernando. Universidad de Buenos Aires. Facultad de AgronomĂa. Departamento de MĂ©todos Cuantitativos y Sistemas de InformaciĂłn; Argentina. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas; ArgentinaFil: Bena, MarĂa Julia. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Instituto de Botánica Darwinion. Academia Nacional de Ciencias Exactas, FĂsicas y Naturales. Instituto de Botánica Darwinion; ArgentinaFil: Godoy BĂĽrki, Ana Carolina. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Instituto de Botánica Darwinion. Academia Nacional de Ciencias Exactas, FĂsicas y Naturales. Instituto de Botánica Darwinion; ArgentinaFil: Reinheimer, Renata. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - Santa Fe. Instituto de AgrobiotecnologĂa del Litoral. Universidad Nacional del Litoral. Instituto de AgrobiotecnologĂa del Litoral; ArgentinaFil: Zuloaga, Fernando Omar. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Instituto de Botánica Darwinion. Academia Nacional de Ciencias Exactas, FĂsicas y Naturales. Instituto de Botánica Darwinion; Argentin
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