Multi‐Element Surface Coating of Layered Ni‐Rich Oxide Cathode Materials and Their Long‐Term Cycling Performance in Lithium‐Ion Batteries

The energy density of layered oxide cathode materials increases with their Ni content, while the stability decreases and degradation becomes more severe. A common strategy to mitigate or prevent degradation is the application of protective coatings on the particle surfaces. In this article, a room-tem-perature, liquid-phase reaction of trimethylaluminum (TMA) and tetraethyl orthosilicate (TEOS) with adsorbed moisture on either LiNi0.85Co0.10Mn0.05O2or LiNiO2, yielding a hybrid coating that shows synergetic benefits compared to coatings from TMA and TEOS individually, is reported. The surface layer is investigated in long-term pouch full-cell studies as well as by electron micros-copy, X-ray photoelectron spectroscopy, and differential electrochemical mass spectrometry, demonstrating that it prevents degradation primarily by a fluorine-scavenging effect, and by reducing the extent of rock salt-type phase formation

The SN 393 -- SNR RX J1713.7-3946 (G347.3-0.5) Connection

Although the connection of the Chinese "guest" star of 393 AD with the Galactic supernova remnant RX J1713.7-3946 (G347.3-0.5) made by Wang et al. in 1997 is consistent with the remnant's relatively young properties and the guest star's projected position within the `tail' of the constellation Scorpius, there are difficulties with such an association. The brief Chinese texts concerning the 393 AD guest star make no comment about its apparent brightness stating only that it disappeared after 8 months. However, at the remnant's current estimated 1 - 1.3 kpc distance and A_v ~ 3 mag, its supernova should have been a visually bright object at maximum light (-3.5 to -5.0 mag) and would have remained visible for over a year. The peak brightness ~ 0 magnitude adopted by Wang et al. and others would require the RX J1713.7-3946 supernova to have been a very subluminous supernova event similar to or fainter than CCSNe like SN 2005cs. We also note problems connecting SN 393 with a European record in which the Roman poet Claudian describes a visually brilliant star in the heavens around 393 AD that could be readily seen even in midday. Although several authors have suggested this account may be a reference to the Chinese supernova of 393, Scorpius would not be visible near midday in March when the Chinese first reported the 393 guest star. We review both the Chinese and Roman accounts and calculate probable visual brightnesses for a range of supernova subtypes and conclude that neither the Chinese nor the Roman descriptions are easily reconciled with an expected RX J1713.7-3946 supernova brightness and duration.Comment: 7 pages includes 2 tables. Accepted for publication in AJ. Revised text regarding subluminous SN

Responding to the UN sustainability goals in transdisciplinary partnership through network action learning

The global water crisis, an enormous concern according to the World Economic Forum, poses a significant challenge to long-term sustainability, exacerbated by the high energy demand associated with water supply and treatment. As the renewable energy sector grows, the need for green technologies to support the water-energy nexus becomes evident. However, mere technological advancements are insufficient to address complex water-related challenges. This paper presents a transdisciplinary collaborative effort involving engineers, geographers, management researchers, and environmentalists working with practitioners in a cross-border network. The study explores through action learning research how, in a transdisciplinary partnership, network action learning influences the exploration and implementation of novel green technology and the development of innovation capabilities. The research is structured around three themes: green technology platforms, policy support and guidance, and dissemination and collaboration. It identifies the factors impacting technology exploration and application and how concurrently green innovation capabilities are developed. The study emphasizes the significance of transdisciplinary collaboration and offers valuable insights into addressing UN Sustainability Goals related to clean water, sustainable industry, and partnerships. It contributes to innovation capability theory and provides practical guidance to researchers, practitioners, and policymakers, emphasizing the need for holistic approaches to address the water-energy crisis and achieve sustainable development

AMI observations of unmatched Planck ERCSC LFI sources at 15.75 GHz

The Planck Early Release Compact Source Catalogue includes 26 sources with no obvious matches in other radio catalogues (of primarily extragalactic sources). Here we present observations made with the Arcminute Microkelvin Imager Small Array (AMI SA) at 15.75 GHz of the eight of the unmatched sources at declination > +10 degrees. Of the eight, four are detected and are associated with known objects. The other four are not detected with the AMI SA, and are thought to be spurious.Comment: 6 pages, 5 figures, 4 table

Recognizing true H5N1 infections in humans during confirmed outbreaks.

INTRODUCTION: The goal of this study was to evaluate whether any characteristics that are evident at presentation for urgent medical attention could be used to differentiate cases of H5N1 in the absence of viral testing. METHODOLOGY: Information about exposure to poultry, clinical signs and symptoms, treatments, and outcomes was abstracted from existing data in the global avian influenza registry (www.avianfluregistry.org) using standardized data collection tools for documented and possible cases of H5N1 infection who presented for medical attention between 2005-2011 during known H5N1 outbreaks in Azerbaijan, Indonesia, Pakistan and Turkey. RESULTS: Demography, exposure to poultry, and presenting symptoms were compared, with only the common symptoms of fever and headache presenting significantly more frequently in confirmed H5N1 cases than in possible cases. Reported exposure to  infected humans was also more common in confirmed cases. In contrast, unexplained respiratory illness, sore throat, excess sputum production, and rhinorrhea were more frequent in possible cases. Overall, oseltamivir treatment showed a survival benefit, with the greatest benefit shown in H5N1 cases who were treated within two days of symptom onset (51% reduction in case fatality). CONCLUSION: Since prompt treatment with antivirals conferred a strong survival benefit for H5N1 cases, presumptive antiviral treatment should be considered for all possible cases presenting during an outbreak of H5N1 as a potentially life-saving measure

Black Hole Spectroscopy: Testing General Relativity through Gravitational Wave Observations

Assuming that general relativity is the correct theory of gravity in the strong field limit, can gravitational wave observations distinguish between black hole and other compact object sources? Alternatively, can gravitational wave observations provide a test of one of the fundamental predictions of general relativity? Here we describe a definitive test of the hypothesis that observations of damped, sinusoidal gravitational waves originated from a black hole or, alternatively, that nature respects the general relativistic no-hair theorem. For astrophysical black holes, which have a negligible charge-to-mass ratio, the black hole quasi-normal mode spectrum is characterized entirely by the black hole mass and angular momentum and is unique to black holes. In a different theory of gravity, or if the observed radiation arises from a different source (e.g., a neutron star, strange matter or boson star), the spectrum will be inconsistent with that predicted for general relativistic black holes. We give a statistical characterization of the consistency between the noisy observation and the theoretical predictions of general relativity, together with a numerical example.Comment: 19 pages, 7 figure