The energy density of layered oxide cathode materials increases with their Ni content, while the stability decreases and degradation becomes more severe. A common strategy to mitigate or prevent degradation is the application of protective coatings on the particle surfaces. In this article, a room-tem-perature, liquid-phase reaction of trimethylaluminum (TMA) and tetraethyl orthosilicate (TEOS) with adsorbed moisture on either LiNi0.85Co0.10Mn0.05O2or LiNiO2, yielding a hybrid coating that shows synergetic benefits compared to coatings from TMA and TEOS individually, is reported. The surface layer is investigated in long-term pouch full-cell studies as well as by electron micros-copy, X-ray photoelectron spectroscopy, and differential electrochemical mass spectrometry, demonstrating that it prevents degradation primarily by a fluorine-scavenging effect, and by reducing the extent of rock salt-type phase formation