Critical adsorption at chemically structured substrates

We consider binary liquid mixtures near their critical consolute points and exposed to geometrically flat but chemically structured substrates. The chemical contrast between the various substrate structures amounts to opposite local preferences for the two species of the binary liquid mixtures. Order parameters profiles are calculated for a chemical step, for a single chemical stripe, and for a periodic stripe pattern. The order parameter distributions exhibit frustration across the chemical steps which heals upon approaching the bulk. The corresponding spatial variation of the order parameter and its dependence on temperature are governed by universal scaling functions which we calculate within mean field theory. These scaling functions also determine the universal behavior of the excess adsorption relative to suitably chosen reference systems

Massive Field-Theory Approach to Surface Critical Behavior in Three-Dimensional Systems

The massive field-theory approach for studying critical behavior in fixed space dimensions $d<4$ is extended to systems with surfaces.This enables one to study surface critical behavior directly in dimensions $d<4$ without having to resort to the $\epsilon$ expansion. The approach is elaborated for the representative case of the semi-infinite |\bbox{\phi}|^4 $n$-vector model with a boundary term {1/2} c_0\int_{\partial V}\bbox{\phi}^2 in the action. To make the theory uv finite in bulk dimensions $3\le d<4$, a renormalization of the surface enhancement $c_0$ is required in addition to the standard mass renormalization. Adequate normalization conditions for the renormalized theory are given. This theory involves two mass parameter: the usual bulk `mass' (inverse correlation length) $m$, and the renormalized surface enhancement $c$. Thus the surface renormalization factors depend on the renormalized coupling constant $u$ and the ratio $c/m$. The special and ordinary surface transitions correspond to the limits $m\to 0$ with $c/m\to 0$ and $c/m\to\infty$, respectively. It is shown that the surface-enhancement renormalization turns into an additive renormalization in the limit $c/m\to\infty$. The renormalization factors and exponent functions with $c/m=0$ and $c/m=\infty$ that are needed to determine the surface critical exponents of the special and ordinary transitions are calculated to two-loop order. The associated series expansions are analyzed by Pad\'e-Borel summation techniques. The resulting numerical estimates for the surface critical exponents are in good agreement with recent Monte Carlo simulations. This also holds for the surface crossover exponent $\Phi$.Comment: Revtex, 40 pages, 3 figures, and 8 pictograms (included in equations

Local investigations on the gas-liquid mass transfer around Taylor bubbles flowing in a meandering millimetric square channel

Gas-liquid mass transfer around Taylor bubbles moving in a meandering millimetric square channel was locally visualized and characterized in the present study. For that, the colorimetric technique proposed by Dietrich et al. (2013) was implemented. With this technique, the evolution of equivalent oxygen concentration fields in the liquid slugs passing through one and several bends was firstly described. In particular, it was observed how the flow structure (recirculation zones) inside the liquid slugs were twisted and split by the periodic bends (centrifugal effect), until reaching, after several bends, a uniform O2 concentration inside the liquid slugs. The influence of the “turning point”, joining two “straight” sections of meandering channel was also highlighted: a slowing down of the gas-liquid mass transfer was clearly shown. Volumetric mass transfer coefficients were determined at last by fitting the experimental axial profiles of averaged oxygen concentrations in the liquid slugs (before the turning point) with the ones predicted by a classical plug-flow model

Scratching the surface:Footprint of a late Carboniferous ice sheet

International audienceField observations in conjunction with aerial images from an unmanned aerial vehicle were used to create the first map of a glacial unconformity underlying the late Carboniferous Dwyka Group of South Africa. Crosscutting relationships reveal that the glacial unconformity at Oorlogskloof, in which flutes, grooves, and striae were ploughed into unconsolidated sand, formed in a three-phased process charting a periodic shift in the locus of subglacial erosion. The unconformity formed by a periodically decoupled ice sheet in a probable tidewater setting. This model contrasts with earlier views that the structures simply record progressive ice-margin liftoff during transgression, and they provide unique insight into the complex temporal development of a 300 Ma subglacial environment

Local hydrodynamics investigation within a dynamic filtration unit under laminar flow

Conference: 9th International Symposium on Mixing in Industrial ProcessesLocation: Birmingham, ENGLANDDate: JUN 25-28, 2017A dynamic filtration module, called a Rotating and Vibrating Filtration (R.V.F.) module, was designed and dedicated to the treatment of highly viscous fluid, such as fermentation broth or liquid food. To this end, an experimental study was undertaken, using a laminar flow regime with a viscous Newtonian model fluid in a dynamic filtration module in order to quantify the effect of local hydrodynamics on filtration. Instantaneous velocity fields can be measured and analyzed within an R.V.F. by using Particle Image Velocimetry (P.I.V.). In this study, we applied P.I.V. to study the laminar local hydrodynamics in 3 different slices within the 3 mm gap between the membrane and the impeller and 3 vertical slices at different radial positions, with rotation speeds from 0 to 10 Hz. Radial and vertical profiles of tangential velocity were then plotted. Proper Orthogonal Decomposition (P.O.D.) was applied to the P.I.V. data to discriminate between mean flow and fluctuating velocities induced by the periodic motion of the impeller. Thus, viscous shear stress profiles were deduced in terms of both mean shear stress profile and root mean squared (r.m.s.) fluctuating shear stress profile; wall values were then deduced. With this approach, we were able to quantify the distribution of viscous shear stress at the wall (membrane), in terms of mean value and r.m.s. contribution. Dynamic filtration efficiency was thus enlightened by local hydrodynamics. (C) 2018 Institution of Chemical Engineers

Kinematics and rifting processes of the Liguro-Provençal Basin, Western Mediterranean

The Liguro-Provençal Basin, situated at the junction of the Northern Apennines and the Western Alps, formed due to the rollback subduction of the Adriatic-African plate underneath Europe and the subsequent upper plate extension in the Oligocene to early Miocene times. The opening of the basin was accompanied by the counter-clockwise rotation of the Corsica-Sardinia block relative to Europe until 16 Ma, with the basin widening towards the southwest. It remains controversial if the extension ever reached seafloor spreading with the production of oceanic crust, or whether it led to anomalously thin continental crust and/or to mantle exhumation. Although considered as tectonically inactive today, the Liguro-Provençal Basin shows active seismicity, indicating compression and possible basin inversion (Thorwart et al. 2021). Thus it is crucial to better understand the opening of the basin and the tectonic inheritance due to rifting in order to interpret the present-day seismicity. To this end, we compiled existing geological and geophysical data, including recent data from the 4DMB project (“Mountain Building Processes in Four Dimensions”), to constrain the crustal and sedimentary thicknesses throughout the basin. We focus specifically on two profiles in the NE (Corsica-Provence) and SW (Sardinia-Gulf of Lion) parts of the basin, along the opening direction of the basin. For each selected profile we calculated the average velocity using the kinematic reconstructions of Le Breton et al. (2021) and the amount of extension using an aerial balancing approach. We then compared these profiles and amounts of extension with results of coupled thermo-mechanical of asymmetric rifting and surface processes modelling using Aspect and Fastscape codes from Neuharth et al. (2022). The results of the thermo-mechanical modelling fit very well the present-day geometry of the rifted continental crust, with a wider hyper-extended rifted margin on the European and a narrower rifted margin on the Corsica-Sardinia side. Rifting migrated southeastward through time and seems to not have reached oceanic spreading nor mantle exhumation in the northeast part of the basin, as observed in the most recent seismic profile A401A-SMPL obtained within the 4DMB SPP project. Towards the southwest, the model confirms the presence of exhumed mantle, as proposed in previous study (Jolivet et al. 2015). The synthesis of geophysical data and thermomechanical modelling also fits very well in the existing kinematic reconstructions from 35 to 0 Ma of the Western Mediterranean, allowing us to infer the lateral extent of oceanic crust and exhumed mantle domains within the basin. Finally, present-day compressional seismicity seems to reactivate rift-related structures

Screening masses in neutral two-flavor color superconductor

The Debye and Meissner screening masses of the gluons and the photon in neutral and beta-equilibrated dense two-flavor quark matter are calculated. The results are presented in a general form that can be used in gapped as well as gapless color superconducting phases. The results for the magnetic screening masses indicate that the system develops a chromomagnetic instability. Possible consequences of the instability are discussed.Comment: 29 pages, 2 figures. Minor corrections. References added. Version accepted to Phys. Rev.

X-shooter, NACO, and AMBER observations of the LBV Pistol Star \footnote{Based on ESO runs 85.D-0182A, 085.D-0625AC}

We present multi-instruments and multi-wavelengths observations of the famous LBV star Pistol Star. These observations are part of a larger program about early O stars at different metallicities. The Pistol star has been claimed as the most massive star known, with 250 solar masses. We present the preliminary results based on X-Shooter spectra, as well as the observations performed with the VLTI-AMBER and the VLT-NACO adaptive optics. The X-shooter spectrograph allows to obtain simultaneously a spectrum from the UV to the K-band with a resolving power of $\sim$15000. The preliminary results obtained indicate that Pistol Star has similar properties of Eta Car, including shells of matter, but also the binarity. Other objects of the program, here briefly presented, were selected for their particular nature: early O stars with mass discrepancies between stellar evolution models and observations, discrepancies with the wind momentum luminosity relation.Comment: Poster at the 39th LIAC, submitted version of the proceeding

First Gale Western Butte Capping-Unit Compositions, and Relationships to Earlier Units Along Curiosity's Traverse

The Curiosity rover has been traversing through the clay-bearing unit (Glen Torridon; GT), approaching Greenheugh pediment, a large, fan-shaped surface surrounding the mouth of Gediz Vallis on the lower slope of Mt. Sharp. The pediment unconformably overlies the underlying bedrock, and is hence younger than units of the Mt. Sharp group. Orbital imaging of the pediment has shown it to have a slightly lower albedo and higher thermal inertia than neighboring units, to be relatively retentive of craters (e.g., erosion resistant), and to exhibit curved bedforms suggestive of lithified eolian bedforms. No diagnostic spectral signature has been observed from orbit. Recent rover positions allowed remote imaging of the contact between Greenheugh pediment and the eroded Murray formation strata below it, showing that the pediment capping material is cross-bedded and relatively thin (1-3 m), and suggesting that the pediment may have been much larger at one time. As Curiosity approached the edge of the pediment, the team investigated two buttes named Central and Western. The latter butte contains dark capping material that initially looked similar to the pediment cap, but close inspection revealed important physical differences. Here we report on compositions from ChemCam of two float rocks that appear to have rolled down from the capping unit, and on potential relation-ships to other targets along the traverse of the rover