Nanomechanics of a Hydrogen Molecule Suspended between Two Equally Charged Tips

Geometric configuration and energy of a hydrogen molecule centered between two point-shaped tips of equal charge are calculated with the variational quantum Monte-Carlo (QMC) method without the restriction of the Born-Oppenheimer (BO) approximation. Ground state nuclear distribution, stability, and low vibrational excitation are investigated. Ground state results predict significant deviations from the BO treatment that is based on a potential energy surface (PES) obtained with the same QMC accuracy. The quantum mechanical distribution of molecular axis direction and bond length at a sub-nanometer level is fundamental for understanding nanomechanical dynamics with embedded hydrogen. Because of the tips' arrangement, cylindrical symmetry yields a uniform azimuthal distribution of the molecular axis vector relative to the tip-tip axis. With approaching tips towards each other, the QMC sampling shows an increasing loss of spherical symmetry with the molecular axis still uniformly distributed over the azimuthal angle but peaked at the tip-tip direction for negative tip charge while peaked at the equatorial plane for positive charge. This directional behavior can be switched between both stable configurations by changing the sign of the tip charge and by controlling the tip-tip distance. This suggests an application in the field of molecular machines.Comment: 20 pages, 10 figure

Application-layer Performance Analysis of PRIME in Smart Metering Networks

This paper assesses the performance of actual PRIME v1.3.6 and PRIME v1.4 systems when used for Smart Metering applications. The analysis is performed at the application level using the DLMS/COSEM stack. Hence, it considers performance indicators that are of practical interest for distribution system operators, such as the availability and the average time needed to read the energy load profile of all the meters. To this end, two test networks with 112 smart meters have been deployed in the laboratory (to ensure the stability of the network). In one of them all the Service Nodes communicate directly with the Base Node, while there exist up to 5 switching levels in the other tested network. First, the PRIME v1.3.6 system is evaluated, stressing the significant performance gain that can be obtained by implementing some MAC layer strategies, which are compatible with the specification but not specifically defined on it. Then,the improvement offered by the PRIME v1.4 system is assessed.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

The complete theory of Maxwell and Proca fields

We present the most general ghost-free classical Lagrangian containing first-order derivatives and describing interacting real Abelian spin-one fields on Minkowski spacetime. We study both massive Proca and massless Maxwell fields and allow for a non-linear realization of mass, in the form of derivative self-interactions. Within this context, our construction notoriously extends the existing literature, which is limited to the case of a single Proca field and to multiple interacting Proca fields in the presence of a global rotational symmetry. In the limit of a single Proca field, we reproduce the known healthy interaction terms. We provide the necessary and sufficient conditions to ensure ghost-freedom in any multi-field setup. We observe that, in general, the said conditions are not satisfied by the rotationally symmetric multi-Proca interactions suggested so far, which implies that they propagate ghosts. Our theory admits a plethora of applications in a wide range of subjects. For illustrative purposes, we provide concrete proposals in holographic condensed matter and black hole physics.Comment: 6 pages. v2: References added. v3: Single Proca limit modified. v4: Journal version. This work is dedicated to Mar\'{i}a Jos\'{e} D\'{i}ez Segovian

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Los pinceles de la química

La química desarrolla un papel muy importante en diferentes campos de investigación. Normalmente cuando se habla de química la gente piensa en reacciones y síntesis de nuevos proyectos. Sin embargo, un campo poco conocido para la química es el mundo de la restauración de pinturas. Nombres tan conocidos como Lewis, Hückel, Diels-Alder se imparten en nuestras aulas, pero por qué se menosprecia los disolventes. Los solventes son muy importantes en las reacciones químicas aunque muchas veces los obviemos. En cambio, toman mucha relevancia al restaurar pinturas