6,575 research outputs found
The Implementation of the AIS/ACM IS 2010 Curriculum by Top US Universities: An Analysis of Catalogs and College Websites
Orbital magnetism in axially deformed sodium clusters: From scissors mode to dia-para magnetic anisotropy
Low-energy orbital magnetic dipole excitations, known as scissors mode (SM),
are studied in alkali metal clusters. Subsequent dynamic and static effects are
explored. The treatment is based on a self-consistent microscopic approach
using the jellium approximation for the ionic background and the Kohn-Sham mean
field for the electrons. The microscopic origin of SM and its main features
(structure of the mode in light and medium clusters, separation into low- and
high-energy plasmons, coupling high-energy M1 scissors and E2 quadrupole
plasmons, contributions of shape isomers, etc) are discussed. The scissors M1
strength acquires large values with increasing cluster size. The mode is
responsible for the van Vleck paramagnetism of spin-saturated clusters. Quantum
shell effects induce a fragile interplay between Langevin diamagnetism and van
Vleck paramagnetism and lead to a remarkable dia-para anisotropy in magnetic
susceptibility of particular light clusters. Finally, several routes for
observing the SM experimentally are discussed.Comment: 21 pages, 7 figure
Orbital Magnetic Dipole Mode in Deformed Clusters: A Fully Microscopic Analysis
The orbital M1 collective mode predicted for deformed clusters in a schematic
model is studied in a self-consistent random-phase-approximation approach which
fully exploits the shell structure of the clusters. The microscopic mechanism
of the excitation is clarified and the close correlation with E2 mode
established. The study shows that the M1 strength of the mode is fragmented
over a large energy interval. In spite of that, the fraction remaining at low
energy, well below the overwhelming dipole plasmon resonance, is comparable to
the strength predicted in the schematic model. The importance of this result in
view of future experiments is stressed.Comment: 10 pages, 3 Postscript figures, uses revte
The influence of the shape of Au nanoparticles on the catalytic current of fructose dehydrogenase
Graphite electrodes were modified with triangular (AuNTrs) or spherical (AuNPs) nanoparticles and further modified with fructose dehydrogenase (FDH). The present study reports the effect of the shape of these nanoparticles (NPs) on the catalytic current of immobilized FDH pointing out the different contributions on the mass transfer–limited and kinetically limited currents. The influence of the shape of the NPs on the mass transfer–limited and the kinetically limited current has been proved by using two different methods: a rotating disk electrode (RDE) and an electrode mounted in a wall jet flow-through electrochemical cell attached to a flow system. The advantages of using the wall jet flow system compared with the RDE system for kinetic investigations are as follows: no need to account for substrate consumption, especially in the case of desorption of enzyme, and studies of product-inhibited enzymes. The comparison reveals that virtually identical results can be obtained using either of the two techniques. The heterogeneous electron transfer (ET) rate constants (kS) were found to be 3.8 ± 0.3 s−1 and 0.9 ± 0.1 s−1, for triangular and spherical NPs, respectively. The improvement observed for the electrode modified with AuNTrs suggests a more effective enzyme-NP interaction, which can allocate a higher number of enzyme molecules on the electrode surface
Intensive insulin therapy versus glycemic control in critically ill patients: a prospective controlled trial
Abort Trigger False Positive and False Negative Analysis Methodology for Threshold-Based Abort Detection
This paper describes a quantitative methodology for bounding the false positive (FP) and false negative (FN) probabilities associated with a human-rated launch vehicle abort trigger (AT) that includes sensor data qualification (SDQ). In this context, an AT is a hardware and software mechanism designed to detect the existence of a specific abort condition. Also, SDQ is an algorithmic approach used to identify sensor data suspected of being corrupt so that suspect data does not adversely affect an AT's detection capability. The FP and FN methodologies presented here were developed to support estimation of the probabilities of loss of crew and loss of mission for the Space Launch System (SLS) which is being developed by the National Aeronautics and Space Administration (NASA). The paper provides a brief overview of system health management as being an extension of control theory; and describes how ATs and the calculation of FP and FN probabilities relate to this theory. The discussion leads to a detailed presentation of the FP and FN methodology and an example showing how the FP and FN calculations are performed. This detailed presentation includes a methodology for calculating the change in FP and FN probabilities that result from including SDQ in the AT architecture. To avoid proprietary and sensitive data issues, the example incorporates a mixture of open literature and fictitious reliability data. Results presented in the paper demonstrate the effectiveness of the approach in providing quantitative estimates that bound the probability of a FP or FN abort determination
Hostile media perception affects news bias, but not news sharing intentions.
Hostile media perception (HMP) theory suggests that partisans perceive neutral coverage of news by outlets opposite to their political leaning as biased against their side. We conducted two pre-registered online experiments to assess the effect of HMP on news bias and news sharing intentions regarding two salient and controversial topics in the US: police conduct (Study 1, N = 817) and COVID-19 norms (Study 2, N = 819). Results show that partisans perceive neutral coverage of news by outlets opposite to their political leaning as biased, even when we account for their prior beliefs regarding the media outlet and news content. However, HMP seems to be limited in its consequences, as it has little impact on partisans' willingness to share news from outlets of opposite political leaning, even though the news is perceived as biased
To the attention of mobile software developers: Guess what, test your app!
Software testing is an important phase in the software development life-cycle
because it helps in identifying bugs in a software system before it is shipped
into the hand of its end users. There are numerous studies on how developers
test general-purpose software applications. The idiosyncrasies of mobile
software applications, however, set mobile apps apart from general-purpose
systems (e.g., desktop, stand-alone applications, web services). This paper
investigates working habits and challenges of mobile software developers with
respect to testing. A key finding of our exhaustive study, using 1000 Android
apps, demonstrates that mobile apps are still tested in a very ad hoc way, if
tested at all. However, we show that, as in other types of software, testing
increases the quality of apps (demonstrated in user ratings and number of code
issues). Furthermore, we find evidence that tests are essential when it comes
to engaging the community to contribute to mobile open source software. We
discuss reasons and potential directions to address our findings. Yet another
relevant finding of our study is that Continuous Integration and Continuous
Deployment (CI/CD) pipelines are rare in the mobile apps world (only 26% of the
apps are developed in projects employing CI/CD) --- we argue that one of the
main reasons is due to the lack of exhaustive and automatic testing.Comment: Journal of Empirical Software Engineerin
Spectrally-resolved UV photodesorption of CH4 in pure and layered ices
Context. Methane is among the main components of the ice mantles of
insterstellar dust grains, where it is at the start of a rich solid-phase
chemical network. Quantification of the photon-induced desorption yield of
these frozen molecules and understanding of the underlying processes is
necessary to accurately model the observations and the chemical evolution of
various regions of the interstellar medium. Aims. This study aims at
experimentally determining absolute photodesorption yields for the CH4 molecule
as a function of photon energy. The influence of the ice composition is also
investigated. By studying the methane desorption from layered CH4:CO ice,
indirect desorption processes triggered by the excitation of the CO molecules
is monitored and quantified. Methods. Tunable monochromatic VUV light from the
DESIRS beamline of the SOLEIL synchrotron is used in the 7 - 13.6 eV (177 - 91
nm) range to irradiate pure CH4 or layers of CH4 deposited on top of CO ice
samples. The release of species in the gas phase is monitored by quadrupole
mass spectrometry and absolute photodesorption yields of intact CH4 are
deduced. Results. CH4 photodesorbs for photon energies higher than ~9.1 eV
(~136 nm). The photodesorption spectrum follows the absorption spectrum of CH4,
which confirms a desorption mechanism mediated by electronic transitions in the
ice. When it is deposited on top of CO, CH4 desorbs between 8 and 9 eV with a
pattern characteristic of CO absorption, indicating desorption induced by
energy transfer from CO molecules. Conclusions. The photodesorption of CH4 from
the pure ice in various interstellar environments is around 2.0 x 10^-3
molecules per incident photon. Results on CO-induced indirect desorption of CH4
provide useful insights for the generalization of this process to other
molecules co-existing with CO in ice mantles
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