165 research outputs found
A study of methanol and silicon monoxide production through episodic explosions of grain mantles in the Central Molecular Zone
Methanol (CHOH) is found to be abundant and widespread towards the
Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin
is, however, not fully understood. It was proposed that the high cosmic ray
ionisation rate in this region could lead to a more efficient non-thermal
desorption of this species formed on grain surfaces, but it would also mean
that this species is destroyed in a relatively short timescale. In a first
step, we run chemical models with a high cosmic ray ionisation rate and find
that this scenario can only reproduce the lowest abundances of methanol derived
in this region (10-10). In a second step, we investigate
another scenario based on episodic explosions of grain mantles. We find a good
agreement between the predicted abundances of methanol and the observations. We
find that the dominant route for the formation of methanol is through
hydrogenation of CO on the grains followed by the desorption due to the grain
mantle explosion. The cyclic aspect of this model can explain the widespread
presence of methanol without requiring any additional mechanism. We also model
silicon monoxide (SiO), another species detected in several molecular clouds of
the Galactic Centre. An agreement is found with observations for a high
depletion of Si (Si/H 10) with respect to the solar abundance.Comment: Accepted in MNRA
On the accretion process in a high-mass star forming region - A multitransitional THz Herschel-HIFI study of ammonia toward G34.26+0.15
[Abridged] Our aim is to explore the gas dynamics and the accretion process
in the early phase of high-mass star formation. The inward motion of molecular
gas in the massive star forming region G34.26+0.15 is investigated by using
high-resolution profiles of seven transitions of ammonia at THz frequencies
observed with Herschel-HIFI. The shapes and intensities of these lines are
interpreted in terms of radiative transfer models of a spherical, collapsing
molecular envelope. An accelerated Lambda Iteration (ALI) method is used to
compute the models. The seven ammonia lines show mixed absorption and emission
with inverse P-Cygni-type profiles that suggest infall onto the central source.
A trend toward absorption at increasingly higher velocities for higher
excitation transitions is clearly seen in the line profiles. The lines show only very weak emission, so these absorption profiles
can be used directly to analyze the inward motion of the gas. This is the first
time a multitransitional study of spectrally resolved rotational ammonia lines
has been used for this purpose. Broad emission is, in addition, mixed with the
absorption in the ortho-NH line, possibly tracing a molecular
outflow from the star forming region. The best-fitting ALI model reproduces the
continuum fluxes and line profiles, but slightly underpredicts the emission and
absorption depth in the ground-state ortho line . The derived
ortho-to-para ratio is approximately 0.5 throughout the infalling cloud core
similar to recent findings for translucent clouds in sight lines toward W31C
and W49N. We find evidence of two gas components moving inwards toward the
central region with constant velocities: 2.7 and 5.3 kms, relative
to the source systemic velocity. The inferred mass accretion rates derived are
sufficient to overcome the expected radiation pressure from G34.26+0.15.Comment: 20 pages, 18 figures, accepted by A&A 3 October 201
The ALMA-PILS survey: First tentative detection of 3-hydroxypropenal (HOCHCHCHO) in the interstellar medium and chemical modeling of the CHO isomers
Characterizing the molecular composition of solar-type protostars is useful
for improving our understanding of the physico-chemical conditions under which
the Sun and its planets formed. In this work, we analyzed the Atacama Large
Millimeter/submillimeter Array (ALMA) data of the Protostellar Interferometric
Line Survey (PILS), an unbiased spectral survey of the solar-type protostar
IRAS~16293--2422, and we tentatively detected 3-hydroxypropenal (HOCHCHCHO) for
the first time in the interstellar medium towards source B. Based on the
observed line intensities and assuming local thermodynamic equilibrium, its
column density is constrained to be 10 cm, corresponding to
an abundance of 10 relative to methanol, CHOH. Additional
spectroscopic studies are needed to constrain the excitation temperature of
this molecule. We included HOCHCHCHO and five of its isomers in the chemical
network presented in Manigand et al. (2021) and we predicted their chemical
evolution with the Nautilus code. The model reproduces the abundance of
HOCHCHCHO within the uncertainties. This species is mainly formed through the
grain surface reaction CHCHO + HCO HCOCHCHO, followed by
the tautomerization of HCOCHCHO into HOCHCHCHO. Two isomers, CHCOCHO
and CHCOHCHO, are predicted to be even more abundant than HOCHCHCHO.
Spectroscopic studies of these molecules are essential in searching for them in
IRAS~16293--2422 and other astrophysical sources.Comment: Accepted in A&A Letter
Deuterated water in the solar-type protostars NGC 1333 IRAS 4A and IRAS 4B
Aims. The aim of this paper is to study deuterated water in the solar-type
protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance
distribution with other star-forming regions, and to constrain their HDO/H2O
ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based
telescopes, we observed several HDO lines covering a large excitation range
(Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE
radiative transfer codes were then used to determine the HDO abundance profiles
in these sources. Results. The HDO fundamental line profiles show a very broad
component, tracing the molecular outflows, in addition to a narrower emission
component and a narrow absorbing component. In the protostellar envelope of
NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with
respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11}, respectively,
whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10},
respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing
outer layer with an enhanced abundance of deuterated water is required to
reproduce the absorbing components seen in the fundamental lines at 465 and 894
GHz in both sources. This water-rich layer is probably extended enough to
encompass the two sources as well as parts of the outflows. In the outflows
emanating from NGC1333 IRAS4A, the HDO column density is estimated at about
(2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An
HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In
the warm inner regions of these two sources, we estimate the HDO/H2O ratios at
about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold
envelope of IRAS4A, whose possible origin is discussed in relation to formation
processes of HDO and H2O.Comment: 16 pages, 13 figure
ALMA observations of doubly deuterated water: Inheritance of water from the prestellar environment
Establishing the origin of the water D/H ratio in the Solar System is central
to our understanding of the chemical trail of water during the star and planet
formation process. Recent modeling suggests that comparisons of the DO/HDO
and HDO/HO ratios are a powerful way to trace the chemical evolution of
water and, in particular, determine whether the D/H ratio is inherited from the
molecular cloud or established locally. We seek to determine the DO column
density and derive the DO/HDO ratios in the warm region toward the low-mass
Class 0 sources B335 and L483. The results are compared with astrochemical
models and previous observations to determine their implications for the
chemical evolution of water. We present ALMA observations of the DO
transition at 316.8 GHz toward B335 and L483 at 0.5" ( 100 au)
resolution, probing the inner warm envelope gas. The column densities of
DO, HDO, and HO are determined by synthetic spectrum modeling
and direct Gaussian fitting, under the assumption of a single excitation
temperature and similar spatial extent for the three water isotopologs. DO
is detected toward both sources in the inner warm envelope. The derived
DO/HDO ratios is for L483 and
for B335. The high DO/HDO ratios are a strong
indication of chemical inheritance of water from the prestellar phase down to
the inner warm envelope. This implies that the local cloud conditions in the
prestellar phase, such as temperatures and timescales, determine the water
chemistry at later stages and could provide a source of chemical
differentiation in young systems. In addition, the observed DO/HO
ratios support an observed dichotomy in the deuterium fractionation of water
toward isolated and clustered protostars, namely, a higher D/H ratio toward
isolated sourcesComment: Accepted for publication in A&A. Revision fixes typo in titl
The first ALMA view of IRAS 16293-2422: Direct detection of infall onto source B and high-resolution kinematics of source A
Aims: We focus on the kinematical properties of a proto-binary to study the
infall and rotation of gas towards its two protostellar components. Methods: We
present ALMA Science Verification observations with high-spectral resolution of
IRAS 16293-2422 at 220.2 GHz. The wealth of molecular lines in this source and
the very high spectral resolution offered by ALMA allow us to study the gas
kinematics with unprecedented detail. Results: We present the first detection
of an inverse P-Cygni profile towards source B in the three brightest lines.
The line profiles are fitted with a simple two-layer model to derive an infall
rate of 4.5x10^-5 Msun/yr. This infall detection would rule-out the previously
suggested possibility that source B is a T Tauri star. A position velocity
diagram for source A shows evidence for rotation with an axis close to the
line-of-sight.Comment: Accepted by A&A Letters. 4 pages, 3 figures, 3 appendices (one for
Tables, one for additional figures). This second version includes small
language modifications and changes to keep the letter within the 4 page limi
Nitrogen hydrides in the cold envelope of IRAS16293-2422
Nitrogen is the fifth most abundant element in the Universe, yet the
gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen
hydrides are key molecules of nitrogen chemistry. Their abundance ratios place
strong constraints on the production pathways and reaction rates of
nitrogen-bearing molecules. We observed the class 0 protostar IRAS16293-2422
with the heterodyne instrument HIFI, covering most of the frequency range from
0.48 to 1.78~THz at high spectral resolution. The hyperfine structure of the
amidogen radical o-NH2 is resolved and seen in absorption against the continuum
of the protostar. Several transitions of ammonia from 1.2 to 1.8~THz are also
seen in absorption. These lines trace the low-density envelope of the
protostar. Column densities and abundances are estimated for each hydride. We
find that NH:NH2:NH3=5:1:300. {Dark clouds chemical models predict steady-state
abundances of NH2 and NH3 in reasonable agreement with the present
observations, whilst that of NH is underpredicted by more than one order of
magnitude, even using updated kinetic rates. Additional modelling of the
nitrogen gas-phase chemistry in dark-cloud conditions is necessary before
having recourse to heterogen processes
The ALMA Protostellar Interferometric Line Survey (PILS): First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA
The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. This paper introduces a systematic survey, "Protostellar Interferometric Line Survey (PILS)" of the Class 0 protostellar binary IRAS 16293-2422 using the Atacama Large Millimeter/submillimeter Array (ALMA). The survey covers the full frequency range from 329 to 363 GHz (0.8 mm) with additional targeted observations at 3.0 and 1.3 mm. More than 10,000 features are detected toward one component in the protostellar binary. Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center, these two species are over-abundant relative to methanol, possibly an indication of formation at low temperatures in CO-rich ices. Both 13C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximately 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde. Measurements of the 13C-species lead to a 12C:13C ratio of approximately 30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12CO and 13CO ices sublimate. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle
First detection of ND in the solar-mass protostar IRAS16293-2422
In the past decade, much progress has been made in characterising the
processes leading to the enhanced deuterium fractionation observed in the ISM
and in particular in the cold, dense parts of star forming regions such as
protostellar envelopes. Very high molecular D/H ratios have been found for
saturated molecules and ions. However, little is known about the deuterium
fractionation in radicals, even though simple radicals often represent an
intermediate stage in the formation of more complex, saturated molecules. The
imidogen radical NH is such an intermediate species for the ammonia synthesis
in the gas phase. Herschel/HIFI represents a unique opportunity to study the
deuteration and formation mechanisms of such species, which are not observable
from the ground. We searched here for the deuterated radical ND in order to
determine the deuterium fractionation of imidogen and constrain the deuteration
mechanism of this species. We observed the solar-mass Class 0 protostar
IRAS16293-2422 with the heterodyne instrument HIFI as part of the Herschel key
programme CHESS (Chemical HErschel Surveys of Star forming regions). The
deuterated form of the imidogen radical ND was detected and securely identified
with 2 hyperfine component groups of its fundamental transition in absorption
against the continuum background emitted from the nascent protostar. The 3
groups of hyperfine components of its hydrogenated counterpart NH were also
detected in absorption. We derive a very high deuterium fractionation with an
[ND]/[NH] ratio of between 30 and 100%. The deuterium fractionation of imidogen
is of the same order of magnitude as that in other molecules, which suggests
that an efficient deuterium fractionation mechanism is at play. We discuss two
possible formation pathways for ND, by means of either the reaction of N+ with
HD, or deuteron/proton exchange with NH.Comment: Accepted; To appear in A&A Herschel/HIFI Special Issu
Herschel/HIFI observations of spectrally resolved methylidyne signatures toward the high-mass star-forming core NGC6334I
In contrast to extensively studied dense star-forming cores, little is known
about diffuse gas surrounding star-forming regions. We study molecular gas in
the high-mass star-forming region NGC6334I, which contains diffuse, quiescent
components that are inconspicuous in widely used molecular tracers such as CO.
We present Herschel/HIFI observations of CH toward NGC6334I observed as part of
the CHESS key program. HIFI resolves the hyperfine components of its J=3/2-1/2
transition, observed in both emission and absorption. The CH emission appears
close to the systemic velocity of NGC6334I, while its measured linewidth of 3
km/s is smaller than previously observed in dense gas tracers such as NH3 and
SiO. The CH abundance in the hot core is 7 10^-11, two to three orders of
magnitude lower than in diffuse clouds. While other studies find distinct
outflows in, e.g., CO and H2O toward NGC6334I, we do not detect outflow
signatures in CH. To explain the absorption signatures, at least two absorbing
components are needed at -3.0 and +6.5 km/s with N(CH)=7 10^13 and 3 10^13
cm^-2. Two additional absorbing clouds are found at +8.0 and 0.0 km/s, both
with N(CH)=2 10^13 cm^-2. Turbulent linewidths for the four absorption
components vary between 1.5 and 5.0 km/s in FWHM. We constrain physical
properties of our CH clouds by matching our CH absorbers with other absorption
signatures. In the hot core, molecules such as H2O and CO trace gas that is
heated and dynamically influenced by outflow activity, whereas CH traces more
quiescent material. The four CH absorbers have column densities and turbulent
properties consistent with diffuse clouds: two are located near NGC6334, and
two are unrelated foreground clouds. Local density and dynamical effects
influence the chemical composition of physical components of NGC6334, causing
some components to be seen in CH but not in other tracers, and vice versa.Comment: Accepted by A&A Letters; 5 pages, 1 figure; v2: minor textual and
typographical change
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