128 research outputs found
A New Simple Chromo-fluorogenic Probe for NO2 Detection in Air
[EN] A new chromo-fluorogenic probe, consisting of a biphenyl derivative containing both a silylbenzyl ether and a N,N-dimethylamino group, for NO2 detection in the gas phase has been developed. A clear colour change from colourless to yellow together with an emission
quenching was observed when the probe reacted with NO2. A limit of detection to the naked eye of about 0.1 ppm was determined and the system was successfully applied to the detection of NO2 in realistic atmospheric conditions.We thank the Spanish Government (MAT2012‐38429‐C04) and Generalitat Valenciana (PROMETEOII/2014/047) for support. SCSIE (Universidad de Valencia) is gratefully acknowledged for all the equipment employed. We thank Dr. A. Múñoz from the CEAM (Valencia‐Spain) for her help for the development of the measures in real environment.Juarez, LA.; Costero, AM.; Sancenón Galarza, F.; Martínez-Máñez, R.; Parra Álvarez, M.; Gaviña Costero, P. (2015). A New Simple Chromo-fluorogenic Probe for NO2 Detection in Air. Chemistry - A European Journal. 21(24):8720-8722. doi:10.1002/chem.201500608S87208722212
Influence of Cation Size on the Fluorescent Properties of Bis-coronand Biphenyl-derived Complexes
Composite Accretion Disk and White Dwarf Photosphere Analyses of the FUSE and HST Observations of EY Cygni
We explore the origin of FUSE and HST STIS far UV spectra of the dwarf nova,
EY Cyg, during its quiescence using \emph{combined} high gravity photosphere
and accretion disk models as well as model accretion belts. The best-fitting
single temperature white dwarf model to the FUSE plus HST STIS spectrum of EY
Cygni has TK, log , with an Si abundance of 0.1 x
solar and C abundance of 0.2 x solar but the distance is only 301 pc. The
best-fitting composite model consists of white dwarf with TK,
log , plus an accretion belt with TK covering 27% of
the white dwarf surface with V km/s. The accretion belt
contributes 63% of the FUV light and the cooler white dwarf latitudes
contribute 37%. This fit yields a distance of 351 pc which is within 100 pc of
our adopted distance of 450 pc. EY Cyg has very weak C {\sc iv} emission and
very strong N {\sc v} emission, which is atypical of the majority of dwarf
novae in quiescence. We also conducted a morphological study of the
surroundings of EY Cyg using direct imaging in narrow nebular filters from
ground-based telescopes. We report the possible detection of nebular material^M
associated with EY Cygni. Possible origins of the apparently large N {\scv}/C
{\sc iv} emission ratio are discussed in the context of nova explosions,
contamination of the secondary star and accretion of nova abundance-enriched
matter back to the white dwarf via the accretion disk or as a descendant of a
precursor binary that survived thermal timescale mass transfer. The scenario
involving pollution of the secondary by past novae may be supported by the
possible presence of a nova remnant-like nebula around EY Cyg.Comment: To appear in AJ, Oct. 2004. 5 figures, including 2 color ones (2D
pictures
The Expanding Nebular Remnant of the Recurrent Nova RS Ophiuchi (2006): II. Modeling of Combined Hubble Space Telescope Imaging and Ground-based Spectroscopy
We report Hubble Space Telescope imaging, obtained 155 and 449 days after the
2006 outburst of the recurrent nova RS Ophiuchi, together with ground-based
spectroscopic observations, obtained from the Observatorio Astron\'omico
Nacional en San Pedro M\'artir, Baja California, M\'exico and at the
Observatorio Astrof\'isico Guillermo Haro, at Cananea, Sonora, M\'exico. The
observations at the first epoch were used as inputs to model the geometry and
kinematic structure of the evolving RS Oph nebular remnant. We find that the
modeled remnant comprises two distinct co-aligned bipolar components; a
low-velocity, high-density innermost (hour glass) region and a more extended,
high-velocity (dumbbell) structure. This overall structure is in agreement with
that deduced from radio observations and optical interferometry at earlier
epochs. We find that the asymmetry observed in the west lobe is an instrumental
effect caused by the profile of the HST filter and hence demonstrate that this
lobe is approaching the observer. We then conclude that the system has an
inclination to the line of sight of 39 degrees. This is in
agreement with the inclination of the binary orbit and lends support to the
proposal that this morphology is due to the interaction of the outburst ejecta
with either an accretion disk around the central white dwarf and/or a
pre-existing red giant wind that is significantly denser in the equatorial
regions of the binary than at the poles. The second epoch HST observation was
also modeled. However, as no spectra were taken at this epoch, it is more
difficult to constrain any model. Nevertheless, we demonstrate that between the
two HST epochs the outer dumbbell structure seems to have expanded linearly.Comment: 33 pages, 9 figures, 1 table, accepted for publication in Ap
Unconventional OFF–ON Response of a Mono(calix[4]arene)-Substituted BODIPY Sensor for Hg2+ through Dimerization Reversion
A new selective fluorogenic chemosensor for Hg2+, which combines a calixarene derivative with a BODIPY core as a fluorescent reporter, is described. The remarkable change in its fluorogenic properties in DMSO and CHCl3 has been analyzed. A study of its spectral properties on dilution, along with molecular modeling studies, allowed us to explain that this behavior involves the formation of a J-dimer, as well as how the sensing mechanism of Hg2+ proceeds
YSOVAR: Six pre-main-sequence eclipsing binaries in the Orion Nebula Cluster
Eclipsing binaries (EBs) provide critical laboratories for empirically
testing predictions of theoretical models of stellar structure and evolution.
Pre-main-sequence (PMS) EBs are particularly valuable, both due to their rarity
and the highly dynamic nature of PMS evolution, such that a dense grid of PMS
EBs is required to properly calibrate theoretical PMS models. Analyzing
multi-epoch, multi-color light curves for 2400 candidateOrion Nebula Cluster
(ONC) members from our Warm Spitzer Exploration Science Program YSOVAR, we have
identified 12 stars whose light curves show eclipse features. Four of these 12
EBs are previously known. Supplementing our light curves with follow-up optical
and near-infrared spectroscopy, we establish two of the candidates as likely
field EBs lying behind the ONC. We confirm the remaining six candidate systems,
however, as newly identified ONC PMS EBs. These systems increase the number of
known PMS EBs by over 50% and include the highest mass (Theta1 Ori E, for which
we provide a complete set of well-determined parameters including component
masses of 2.807 and 2.797 solar masses) and longest period (ISOY
J053505.71-052354.1, P \sim 20 days) PMS EBs currently known. In two cases
(Theta1 Ori E and ISOY J053526.88-044730.7), enough photometric and
spectroscopic data exist to attempt an orbit solution and derive the system
parameters. For the remaining systems, we combine our data with literature
information to provide a preliminary characterization sufficient to guide
follow-up investigations of these rare, benchmark systems.Comment: Accepted by Ap
Isomerization and Redox Tuning: Reorganizing the Maya Blue Puzzle from Synthetic, Spectral, and Electrochemical Issues
[EN] A new approach to describe the composition of Maya blue (MB), an ancient organic- inorganic hybrid material, is presented. It is based on the analysis of attenuated total reflection-Fourier transform infrared (ATR-FTIR), Raman spectroscopy, UV-visible (vis) spectroscopic, and electrochemical data for indigo and dehydroindigo plus palygorskite hybrids, including a novel methodology using electrocatalytic effects on the oxygen reduction reaction. As a result, it is concluded that MB results from the tautomerization of indigo-to-indigo hemienol and the subsequent oxidation of these isomeric forms to dehydroindigo, all associated with the palygorskite clay framework, at temperatures above 100 degrees C. This model is also consistent with C-13 NMR data on indigo plus sepiolite hybrids. A consistent set of thermochemical parameters is obtained from ATR-FTIR, solid-state electrochemistry, and UV-vis diffuse reflectance spectra for the successive isomerization and redox tuning processes experienced by palygorskite-associated indigo.Projects PID2020-113022GB-I00 and RTI2018-100910-BC42, supported by MCIN/AEI/10.13039/501100011033 are gratefully acknowledged for all of the equipment employed. NMR was registered at the U26 facility of ICTS "NANBIOSIS" at the SCSIE of the Universitat of Valencia.Doménech-Carbó, A.; Costero, AM.; Gil Grau, S.; Montoya, N.; López-Carrasco, A.; Sáez, JA.; Arroyo, P.... (2021). Isomerization and Redox Tuning: Reorganizing the Maya Blue Puzzle from Synthetic, Spectral, and Electrochemical Issues. The Journal of Physical Chemistry. 125(47):26188-26200. https://doi.org/10.1021/acs.jpcc.1c0793226188262001254
The Initial Mass Function of the Orion Nebula Cluster across the H-burning limit
We present a new census of the Orion Nebula Cluster (ONC) over a large field
of view (>30'x30'), significantly increasing the known population of stellar
and substellar cluster members with precisely determined properties. We develop
and exploit a technique to determine stellar effective temperatures from
optical colors, nearly doubling the previously available number of objects with
effective temperature determinations in this benchmark cluster. Our technique
utilizes colors from deep photometry in the I-band and in two medium-band
filters at lambda~753 and 770nm, which accurately measure the depth of a
molecular feature present in the spectra of cool stars. From these colors we
can derive effective temperatures with a precision corresponding to better than
one-half spectral subtype, and importantly this precision is independent of the
extinction to the individual stars. Also, because this technique utilizes only
photometry redward of 750nm, the results are only mildly sensitive to optical
veiling produced by accretion. Completing our census with previously available
data, we place some 1750 sources in the Hertzsprung-Russel diagram and assign
masses and ages down to 0.02 solar masses. At faint luminosities, we detect a
large population of background sources which is easily separated in our
photometry from the bona fide cluster members. The resulting initial mass
function of the cluster has good completeness well into the substellar mass
range, and we find that it declines steeply with decreasing mass. This suggests
a deficiency of newly formed brown dwarfs in the cluster compared to the
Galactic disk population.Comment: 16 pages, 18 figures. Accepted for publication in The Astrophysical
Journa
Thiophene-Fused Tropones as Chemical Warfare Agent-Responsive Building Blocks
We report the synthesis of dithienobenzotropone-based conjugated alternating copolymers by direct arylation polycondensation. Postpolymerization modification by hydride reduction yields cross-conjugated, reactive hydroxyl-containing copolymers that undergo phosphorylation and ionization upon exposure to the chemical warfare agent mimic diethylchlorophosphate (DCP). The resulting conjugated, cationic copolymer is highly colored and facilitates the spectroscopic and colorimetric detection of DCP in both solution and thin-film measurements.United States. Defense Threat Reduction Agency. Chemical and Biological Technologies Department (Grant BA12PHM123
HST measures of Mass Accretion Rates in the Orion Nebula Cluster
The present observational understanding of the evolution of the mass
accretion rates (Macc) in pre-main sequence stars is limited by the lack of
accurate measurements of Macc over homogeneous and large statistical samples of
young stars. Such observational effort is needed to properly constrain the
theory of star formation and disk evolution. Based on HST/WFPC2 observations,
we present a study of Macc for a sample of \sim 700 sources in the Orion Nebula
Cluster, ranging from the Hydrogen-burning limit to M\ast \sim 2M\odot. We
derive Macc from both the U-band excess and the H{\alpha} luminosity
(LH{\alpha}), after determining empirically both the shape of the typical
accretion spectrum across the Balmer jump and the relation between the
accretion luminosity (Lacc) and LH{\alpha}, that is Lacc/L\odot =
(1.31\pm0.03)\cdotLH{\alpha}/L\odot + (2.63\pm 0.13). Given our large
statistical sample, we are able to accurately investigate relations between
Macc and the parameters of the central star such as mass and age. We clearly
find Macc to increase with stellar mass, and decrease over evolutionary time,
but we also find strong evidence that the decay of Macc with stellar age occurs
over longer timescales for more massive PMS stars. Our best fit relation
between these parameters is given by: log(Macc/M\odot\cdotyr)=(-5.12 \pm 0.86)
-(0.46 \pm 0.13) \cdot log(t/yr) -(5.75 \pm 1.47)\cdot log(M\ast/M\odot) +
(1.17 \pm 0.23)\cdot log(t/yr) \cdot log(M\ast/M\odot). These results also
suggest that the similarity solution model could be revised for sources with
M\ast > 0.5M\odot. Finally, we do not find a clear trend indicating
environmental effects on the accretion properties of the sources.Comment: 17 pages, 15 figures, accepted for publication in Ap
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