Extraction of silymarin compounds from milk thistle (Silybum marianum) seed using hot, liquid water as the solvent

High-value specialty chemicals are usually obtained from natural products by extracting with generally regarded as safe (GRAS) solvents. Because organic solvents are quite often used, high operating and disposal costs occur. When compared to traditional solvents, water is an interesting alternative because of its low operating and disposal costs. Milk thistle contains compounds (taxifolin, silychristin, silydianin, silybinin A, and silybinin B) that display hepatoxic protection properties. This paper examines the batch extraction of silymarin compounds from milk thistle seed meal in 50°C, 70°C, 85°C and 100°C water as a function of time. For taxifolin, silychristin, silybinin A, and silybinin B, extraction with 100°C water resulted in the highest yields. After 210 min of extraction at 100°C, the yield of taxifolin was 1.2 mg/g of seed while the yields of silychristin, silybinin A, and silybinin B were 5.0, 1.8 and 3.3 mg/g of seed, respectively. The ratios of the extracted compounds, and particularly the ratios at long extraction times, showed that the more polar compounds (taxifolin and silychristin) were preferentially extracted at 85°C, while the less polar silybinin was preferentially extracted at 100°C

Dynamical Effects from Asteroid Belts for Planetary Systems

The orbital evolution and stability of planetary systems with interaction from the belts is studied using the standard phase-plane analysis. In addition to the fixed point which corresponds to the Keplerian orbit, there are other fixed points around the inner and outer edges of the belt. Our results show that for the planets, the probability to move stably around the inner edge is larger than the one to move around the outer edge. It is also interesting that there is a limit cycle of semi-attractor for a particular case. Applying our results to the Solar System, we find that our results could provide a natural mechanism to do the orbit rearrangement for the larger Kuiper Belt Objects and thus successfully explain the absence of these objects beyond 50 AU.Comment: accepted by International Journal of Bifurcation and Chaos in Aug. 2003, AAS Latex, 27 pages with 6 color figure

Upper bounds on success probabilities in linear optics

We develop an abstract way of defining linear-optics networks designed to perform quantum information tasks such as quantum gates. We will be mainly concerned with the nonlinear sign shift gate, but it will become obvious that all other gates can be treated in a similar manner. The abstract scheme is extremely well suited for analytical as well as numerical investigations since it reduces the number of parameters for a general setting. With that we show numerically and partially analytically for a wide class of states that the success probability of generating a nonlinear sign shift gate does not exceed 1/4 which to our knowledge is the strongest bound to date.Comment: 8 pages, typeset using RevTex4, 5 EPS figure

Energy from Agriculture

During the past few years, the demand for energy and petrochemicals has grown at a pace so rapid that our reserves of fossil fuels, once considered inexhaustible, are now being quickly depleted. To help lessen this impending problem, alternative sources of energy must be rapidly developed. Of the many new sources of energy being studied, solar energy, undisputedly, is the most inexhaustible. Energy from the sun, incident upon the earth\u27s surface, exceeds by nearly three orders of magnitude the total energy consumption today. Furthermore, it is not subject to nationalistic boundaries and its use would be compatible with our environmental goals. Several methods of using solar energy are under investigation

The CORALIE survey for southern extra-solar planets. X. A Hot Jupiter orbiting HD73256

Recent radial-velocity measurements obtained with the CORALIE spectrograph on the 1.2-m Euler Swiss telescope at La Silla unveil the presence of a new Jovian-mass Hot Jupiter around HD 73256. The 1.85-M_Jup planet moves on an extremely short-period (P=2.5486 d), quasi-circular orbit. The best Keplerian orbital solution is presented together with an unsuccessful photometric planetary-transit search performed with the SAT Danish telescope at La Silla. Over the time span of the observations, the photometric follow-up of the candidate has nevertheless revealed a P=14-d photometric periodicity corresponding to the rotational period of the star. This variation as well as the radial-velocity jitter around the Keplerian solution are shown to be related to the fair activity level known for HD 73256.Comment: 7 pages, 7 figures. Accepted in A&

Microstructural strain energy of α-uranium determined by calorimetry and neutron diffractometry

The microstructural contribution to the heat capacity of α-uranium was determined by measuring the heat-capacity difference between polycrystalline and single-crystal samples from 77 to 320 K. When cooled to 77 K and then heated to about 280 K, the uranium microstructure released (3±1) J/mol of strain energy. On further heating to 300 K, the microstructure absorbed energy as it began to redevelop microstrains. Anisotropic strain-broadening parameters were extracted from neutron-diffraction measurements on polycrystals. Combining the strain-broadening parameters with anisotropic elastic constants from the literature, the microstructural strain energy is predicted in the two limiting cases of statistically isotropic stress and statistically isotropic strain. The result calculated in the limit of statistically isotropic stress was (3.7±0.5) J/mol K at 77 K and (1±0.5) J/mol at room temperature. In the limit of statistically isotropic strain, the values were (7.8±0.5) J/mol K at 77 K and (4.5±0.5) J/mol at room temperature. In both cases the changes in the microstructural strain energy showed good agreement with the calorimetry

Optical Polarization and Spectral Variability in the M87 Jet

During the last decade, M87's jet has been the site of an extraordinary variability event, with one knot (HST-1) increasing by over a factor 100 in brightness. Variability was also seen on timescales of months in the nuclear flux. Here we discuss the optical-UV polarization and spectral variability of these components, which show vastly different behavior. HST-1 shows a highly significant correlation between flux and polarization, with P increasing from $\sim 20$ at minimum to >40% at maximum, while the orientation of its electric vector stayed constant. HST-1's optical-UV spectrum is very hard ($\alpha_{UV-O}\sim0.5$, $F_\nu\propto\nu^{-\alpha}$), and displays "hard lags" during epochs 2004.9-2005.5, including the peak of the flare, with soft lags at later epochs. We interpret the behavior of HST-1 as enhanced particle acceleration in a shock, with cooling from both particle aging and the relaxation of the compression. We set 2$\sigma$ upper limits of $0.5 \delta$ parsecs and 1.02$c$ on the size and advance speed of the flaring region. The slight deviation of the electric vector orientation from the jet PA, makes it likely that on smaller scales the flaring region has either a double or twisted structure. By contrast, the nucleus displays much more rapid variability, with a highly variable electric vector orientation and 'looping' in the $(I,P)$ plane. The nucleus has a much steeper spectrum ($\alpha_{UV-O} \sim 1.5$) but does not show UV-optical spectral variability. Its behavior can be interpreted as either a helical distortion to a steady jet or a shock propagating through a helical jet.Comment: 14 pages, 7 figures, ApJ, in pres

Impacts of Extension Education on Improving Residential Stormwater Quality: Monitoring Results

The project reported in this article evaluated whether stormwater quality could be improved by educating homeowners and implementing best management practices in a suburban neighborhood. Nitrogen, phosphorus, and bacteria levels from two watersheds were compared using the paired watershed approach. Resident surveys, property site assessments, soil tests, and water quality and quantity monitoring were conducted. A x2-analysis of survey data indicated no significant changes in measured behavior. Significant (p=0.01) reductions in NO3-N and fecal coliform bacteria concentrations occurred; however, total nitrogen concentrations did not change significantly