Elaboration and properties of plasticised chitosan-based exfoliated nano-biocomposites

A series of plasticised chitosan-based materials and nanocomposites were successfully prepared by thermomechanical kneading. During the processing, the montmorillonite (MMT) platelets were fully delaminated. The nanoclay type and content and the preparation method were seen to have an impact on the crystallinity, morphology, glass transition temperature, and mechanical properties of the samples. When higher content (5%) of MMT–Na+ or either content (2.5% or 5%) of chitosan-organomodified MMT (OMMT–Ch) was used, increases in crystallinity and glass transition temperature were observed. Compared to the neat chitosan, the plasticised chitosan-based nano-biocomposites showed drastically improved mechanical properties, which can be ascribed to the excellent dispersion and exfoliation of nanoclay and the strong affinity between the nanoclay and the chitosan matrix. The best mechanical properties obtained were Young's modulus of 164.3 MPa, tensile strength of 13.9 MPa, elongation at break of 62.1%, and energy at break of 0.671 MPa. While the degree of biodegradation was obviously increased by the presence of glycerol, a further increase might be observed especially by the addition of unmodified nanoclay. This could surprisingly contribute to full (100%) biodegradation after 160 days despite the well-known antimicrobial property of chitosan. The results in this study demonstrate the great potential of plasticised chitosan-based nano-biocomposites in applications such as e.g., biodegradable packaging materials

Sustainable Finance Ratings as the Latest Symptom of “Rating Addiction”

Using the widely accepted but rarely articulated concept of ‘rating addiction’, this piece aims to examine the recent entrance of the credit rating agencies into the sustainable finance field against the backdrop of ‘rating addiction’. Once the concept of ‘rating addiction’ is positioned, the effects of the addiction can be witnessed by even just a cursory glance at the history of the credit rating agencies, particularly their recent history. On that basis, this article provides a warning for regulators and the field with regards to the potentially negative effect that credit rating agencies can have upon the ever-growing and socially-important sustainable finance sector. Additionally, assessing the aptitude of the agencies in this sector, in comparison to the sector’s utilisation of their products, may provide further evidence of a system addicted to ratings

Improvements in the X-ray luminosity function and constraints on the Cosmological parameters from X-ray luminous clusters

We show how to improve constraints on \Omega_m, \sigma_8, and the dark-energy equation-of-state parameter, w, obtained by Mantz et al. (2008) from measurements of the X-ray luminosity function of galaxy clusters, namely MACS, the local BCS and the REFLEX galaxy cluster samples with luminosities L> 3 \times 10^{44} erg/s in the 0.1--2.4 keV band. To this aim, we use Tinker et al. (2008) mass function instead of Jenkins et al. (2001) and the M-L relationship obtained from Del Popolo (2002) and Del Popolo et al. (2005). Using the same methods and priors of Mantz et al. (2008), we find, for a \Lambda$CDM universe, \Omega_m=0.28^{+0.05}_{-0.04} and \sigma_8=0.78^{+0.04}_{-0.05}$ while the result of Mantz et al. (2008) gives less tight constraints $\Omega_m=0.28^{+0.11}_{-0.07}$ and \sigma_8=0.78^{+0.11}_{-0.13}. In the case of a wCDM model, we find \Omega_m=0.27^{+0.07}_{-0.06}, $\sigma_8=0.81^{+0.05}_{-0.06}$ and $w=-1.3^{+0.3}_{-0.4}$, while in Mantz et al. (2008) they are again less tight \Omega_m=0.24^{+0.15}_{-0.07}, \sigma_8=0.85^{+0.13}_{-0.20} and w=-1.4^{+0.4}_{-0.7}. Combining the XLF analysis with the f_{gas}+CMB+SNIa data set results in the constraint \Omega_m=0.269 \pm 0.012, \sigma_8=0.81 \pm 0.021 and w=-1.02 \pm 0.04, to be compared with Mantz et al. (2008), \Omega_m=0.269 \pm 0.016, \sigma_8=0.82 \pm 0.03 and w=-1.02 \pm 0.06. The tightness of the last constraints obtained by Mantz et al. (2008), are fundamentally due to the tightness of the $f_{gas}$+CMB+SNIa constraints and not to their XLF analysis. Our findings, consistent with w=-1, lend additional support to the cosmological-constant model.Comment: 9 pages, 4 Figures. A&A accepted. Paper Subitted Previously To Mantz et al 2009, arXiv:0909.3098 and Mantz et al 2009b, arXiv:0909.309

Geographically touring the eastern bloc: British geography, travel cultures and the Cold War

This paper considers the role of travel in the generation of geographical knowledge of the eastern bloc by British geographers. Based on oral history and surveys of published work, the paper examines the roles of three kinds of travel experience: individual private travels, tours via state tourist agencies, and tours by academic delegations. Examples are drawn from across the eastern bloc, including the USSR, Poland, Romania, East Germany and Albania. The relationship between travel and publication is addressed, notably within textbooks, and in the Geographical Magazine. The study argues for the extension of accounts of cultures of geographical travel, and seeks to supplement the existing historiography of Cold War geography

The XMM-BCS galaxy cluster survey: I. The X-ray selected cluster catalog from the initial 6 deg2^2

The XMM-Newton - Blanco Cosmology Survey project (XMM-BCS) is a coordinated X-ray, optical and mid-infrared cluster survey in a field also covered by Sunyaev-Zel'dovich effect surveys by the South Pole Telescope and the Atacama Cosmology Telescope. The aim of the project is to study the cluster population in a 14 deg$^2$ field. In this work, we present a catalog of 46 X-ray selected clusters from the initial 6 deg$^2$ survey core. We describe the XMM-BCS source detection pipeline and derive physical properties of the clusters. We provide photometric redshift estimates derived from the BCS imaging data and spectroscopic redshift measurements for a low redshift subset of the clusters. We derive the cluster log N - log S relation using an approximation to the survey selection function and find it in good agreement with previous studies. We carry out an initial comparison between X-ray luminosity derived masses and masses from optical estimators from the Southern Cosmology Survey for a subset of the cluster sample. Optical masses based on cluster richness and total optical luminosity are found to be significantly higher than the X-ray values. (abridged)Comment: Accepted to A&A. Version with full resolution images and better layout is available at the author or at A&A. 34 pages, 35 figures, 18 table

Positron emission tomography and magnetic resonance imaging methods and datasets within the Dominantly Inherited Alzheimer Network (DIAN)

The Dominantly Inherited Alzheimer Network (DIAN) is an international collaboration studying autosomal dominant Alzheimer disease (ADAD). ADAD arises from mutations occurring in three genes. Offspring from ADAD families have a 50% chance of inheriting their familial mutation, so non-carrier siblings can be recruited for comparisons in case-control studies. The age of onset in ADAD is highly predictable within families, allowing researchers to estimate an individual's point in the disease trajectory. These characteristics allow candidate AD biomarker measurements to be reliably mapped during the preclinical phase. Although ADAD represents a small proportion of AD cases, understanding neuroimaging-based changes that occur during the preclinical period may provide insight into early disease stages of 'sporadic' AD also. Additionally, this study provides rich data for research in healthy aging through inclusion of the non-carrier controls. Here we introduce the neuroimaging dataset collected and describe how this resource can be used by a range of researchers

Positron emission tomography and magnetic resonance imaging methods and datasets within the dominantly inherited Alzheimer network (DIAN)

The Dominantly Inherited Alzheimer Network (DIAN) is an international collaboration studying autosomal dominant Alzheimer disease (ADAD). ADAD arises from mutations occurring in three genes. Offspring from ADAD families have a 50% chance of inheriting their familial mutation, so non-carrier siblings can be recruited for comparisons in case–control studies. The age of onset in ADAD is highly predictable within families, allowing researchers to estimate an individual’s point in the disease trajectory. These characteristics allow candidate AD biomarker measurements to be reliably mapped during the preclinical phase. Although ADAD represents a small proportion of AD cases, understanding neuroimaging-based changes that occur during the preclinical period may provide insight into early disease stages of ‘sporadic’ AD also. Additionally, this study provides rich data for research in healthy aging through inclusion of the non-carrier controls. Here we introduce the neuroimaging dataset collected and describe how this resource can be used by a range of researchers

Resolution of inflammation: a new therapeutic frontier

Dysregulated inflammation is a central pathological process in diverse disease states. Traditionally, therapeutic approaches have sought to modulate the pro- or anti-inflammatory limbs of inflammation, with mixed success. However, insight into the pathways by which inflammation is resolved has highlighted novel opportunities to pharmacologically manipulate these processes — a strategy that might represent a complementary (and perhaps even superior) therapeutic approach. This Review discusses the state of the art in the biology of resolution of inflammation, highlighting the opportunities and challenges for translational research in this field

The Genome Sequence of the Leaf-Cutter Ant Atta cephalotes Reveals Insights into Its Obligate Symbiotic Lifestyle

Leaf-cutter ants are one of the most important herbivorous insects in the Neotropics, harvesting vast quantities of fresh leaf material. The ants use leaves to cultivate a fungus that serves as the colony's primary food source. This obligate ant-fungus mutualism is one of the few occurrences of farming by non-humans and likely facilitated the formation of their massive colonies. Mature leaf-cutter ant colonies contain millions of workers ranging in size from small garden tenders to large soldiers, resulting in one of the most complex polymorphic caste systems within ants. To begin uncovering the genomic underpinnings of this system, we sequenced the genome of Atta cephalotes using 454 pyrosequencing. One prediction from this ant's lifestyle is that it has undergone genetic modifications that reflect its obligate dependence on the fungus for nutrients. Analysis of this genome sequence is consistent with this hypothesis, as we find evidence for reductions in genes related to nutrient acquisition. These include extensive reductions in serine proteases (which are likely unnecessary because proteolysis is not a primary mechanism used to process nutrients obtained from the fungus), a loss of genes involved in arginine biosynthesis (suggesting that this amino acid is obtained from the fungus), and the absence of a hexamerin (which sequesters amino acids during larval development in other insects). Following recent reports of genome sequences from other insects that engage in symbioses with beneficial microbes, the A. cephalotes genome provides new insights into the symbiotic lifestyle of this ant and advances our understanding of host–microbe symbioses