La Importancia de la capacitación para una mejor calidad en el servicio y atención al cliente en la industria restaurantera de la ciudad de Managua

Tesis (Licenciatura en Turismo y Administración Hotelera)--Universidad Americana, Managua, 2004Este proyecto elabora un estudio sobre la importancia de la capacitacion en el servicio atencion al cliente del personal de nivel operativo, del sector restaurantero de la ciudad de Managua

Sterically restricted tin phosphines, stabilized by weak intramolecular donor-acceptor interactions

Funding: Engineering and Physical Sciences Research Council (EPSRC)Four related sterically restricted pen-substituted acenaphthenes have been prepared containing mixed tin phosphorus moieties in the proximal 5,6-positions (Acenap[SnR3][(PPr2)-Pr-i]; Acenap = acenaphthene-5,6-diyl; R-3 = Ph-3 (1), Ph2Cl (2), Me2Cl (3), Bu2Cl (4)). The degree of intramolecular P-Sn bonding within the series was investigated by X-ray crystallography, solution and solid-state NMR spectroscopy, and density functional theory (DFT/B3LYP/SBKJC/PCM) calculations. All members of the series adopt a conformation such that the phosphorus lone pair is located directly opposite the tin center, promoting an intramolecular donor acceptor P -> Sn type interaction. The extent of covalent bonding between Sn and P is found to be much greater in triorganotin chlorides 2-4 in comparison with the triphenyl derivative 1. Coordination of a highly electronegative chlorine atom naturally increases the Lewis acidity of the tin center, enhancing the Ip(P)-sigma*(Sn-Y) donor acceptor 3c-4e type interaction, as indicated by conspicuously short Sn-P peri distances and significant (1)J(P-31,Sn-119) spin spin coupling constants (SSCCs) in the range 740-754 Hz. Evidence supporting the presence of this interaction was also found in solid-state NMR spectra of some of the compounds which exhibit an indirect spin spin coupling on the same order of magnitude as observed in solution. DFT calculations confirm the increased covalent bonding between P and Sn in 2-4, with notable WBIs of ca. 0.35 obtained, in comparison to 0.1 in 1.PostprintPeer reviewe

Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2

The Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged for financial support. The theoretical part of this work was supported by the Russian Science Foundation (Project 14-13-00832).Autoprotolysis of the metastable acid (C6F5)3BOPPh2OH, prepared in situ by the reaction of the rather weak Brønsted acid Ph2PO2H with the strong Lewis acid B(C6F5)3, gave rise to the formation of the eight-membered ring [Ph2POB(C6F5)2O]2 and C6F5H. The conjugate base was isolated as stable sodium crown ether salt [Na(15-crown-5)][Ph2PO2B(C6F5)3].Publisher PDFPeer reviewe

IVAP-PPL instrumento de valoración de actitudes prosociales en personas privadas de la libertad

Curso de Especial Interés : Victimología y CriminologíaEl presente trabajo, tiene como objetivo el diseño de un instrumento que valore actitudes prosociales en personas privadas de la libertad. Entendiendo que una persona privada de la libertad tal como lo afirma (Gómez, 2015) es aquel sujeto que se encuentra con medida intramural en cualquier establecimiento de orden carcelario o penitenciario a nivel nacional o internacional. El IVAP-PPL, es una escala desarrollada con el objetivo de valorar las actitudes prosociales en hombres que se encuentren condenados por el delito de hurto, que se encuentren en fase de alta seguridad y realizando el programa de tratamiento penitenciario responsabilidad integral con la vida-RIV. El IVAP-PPL será una herramienta de apoyo para el programa RIV con la cual será posible tomar decisiones frente a la transición de fase de tratamiento de los PPL; adicionalmente servirá para medir indicadores de prosocialidad en quienes se encuentren realizando RIV por medio de un test-re test.1. Resumen 2. Introducción 3. Marco teórico 4. Marco Legal 5. Marco ético 6. Objetivos 7. Justificación 8. Estudio de Mercadeo 9. Resultados 10. Características Generales del IVAP-PPL 11. Discusión 12. Referencias 13. ApéndicesPregradoPsicólog

Speckle-pattern visibility of light transmitted through a multimode optical fiber

We show that the reduction in visibility of the speckle pattern obtained from laser light that has been passed through a step-index light guide can be found from a knowledge of the model dispersion of the guide, and the bandwidth of the laser beam

Strategia graduale integrata in undici fasi: un approccio mimetico al processo di trasferimento nella didattica della traduzione

The work in this project was supported by the Engineering and Physical Sciences Research Council (EPSRC). M.B. wishes to thank EaStCHEM and the University of St Andrews for support.Three related series of peri‐substituted bis(tellurides) bearing naphthalene, acenaphthene and acenaphthylene backbones (Nap/Acenap/Aceyl(TeY)2 (Nap=naphthalene‐1,8‐diyl N ; Acenap=acenaphthene‐5,6‐diyl A ; Aceyl=acenaphthylene‐5,6‐diyl Ay ; Y=Ph 1 ; Fp 2 ; Tol 3 ; An‐p­ 4 ; An‐o­ 5 ; Tp 6 ; Mes 7 ; Tip 8 ) have been synthesised and their solid‐state structures determined by X‐ray crystallography. Molecular conformations were classified as a function of the two C9‐C‐Te‐C(Y) dihedral angles (θ); in the solid all members adopt AB or CCt configurations, with larger Te(aryl) moieties exclusively imposing the CCt variant. Exceptionally large J(125Te,125Te) spin–spin coupling constants between 3289–3848 Hz were obtained for compounds substituted by bulky Te(aryl) groups, implying these species are locked in a CCt‐type conformation. In contrast, compounds incorporating smaller Te(aryl) moieties are predicted to be rather dynamic in solution and afford much smaller J values (2050–2676 Hz), characteristic of greater populations of AB conformers with lower couplings. This conformational dependence of through‐space coupling is supported by DFT calculations.PostprintPeer reviewe

Revisión bibliográfica: repercusiones neurológicas y nefrológicas de la Eclampsia

La preeclampsia es un trastorno del embarazo asociado con hipertensión gestacional y disfunción de órganos diana. Los pacientes con eclampsia, por definición, tienen convulsiones como parte del síndrome clínico. Sin embargo, las pacientes con preeclampsia también pueden tener otros síntomas y déficits neurológicos. Ambos trastornos pueden asociarse con anomalías radiográficas similares a las del síndrome de encefalopatía posterior reversible, lo que sugiere una fisiopatología común o un espectro clínico unificado de trastornos. Este capítulo revisa la fisiopatología, la presentación clínica, los hallazgos diagnósticos y el pronóstico de pacientes con complicaciones neurológicas asociadas con preeclampsia y eclampsia. La eclampsia es una de las complicaciones rara vez presentadas en el embarazo, constituye a una de las primeras causas que producen una alta morbimortalidad materna, entre las manifestaciones neurológicas que se encuentra con frecuencia en la eclampsia son las alteraciones visuales, convulsiones, estupor, cefalea o coma teniendo presencia de síntomas y signos presentes en el tronco cerebral.&nbsp

Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interaction

The authors are thankful to the EPSRC, the EPSRC National Mass Spectrometry Service Centre (NMSSC) Swansea, the School of Chemistry St. Andrews, and EaStCHEM for support.A series of peri-substituted phosphorus-tellurium systems R’Te–Acenap–PR2 (R’ = Ph, p-An, Nap, Mes, Tip; R = iPr, Ph) exhibiting large “through space” spin-spin coupling constants and the “onset” of three-centre four-electron type interactions are presented. The influence of the substituents at the phosphorus and tellurium atoms as well as their behavior upon oxidation (with S, Se) or metal-coordination (Pt, Au) is discussed using NMR spectroscopy, single crystal X-ray diffraction, and advanced DFT studies including NBO, AIM and ELI-D analyses.PostprintPeer reviewe

Characterisation of a putative AraC transcriptional regulator from Mycobacterium smegmatis

MSMEG_0307 is annotated as a transcriptional regulator belonging to the AraC protein family and is located adjacent to the arylamine N-acetyltransferase (nat) gene in Mycobacterium smegmatis, in a gene cluster, conserved in most environmental mycobacterial species. In order to elucidate the function of the AraC protein from the nat operon in M. smegmatis, two conserved palindromic DNA motifs were identified using bioinformatics and tested for protein binding using electrophoretic mobility shift assays with a recombinant form of the AraC protein. We identified the formation of a DNA:AraC protein complex with one of the motifs as well as the presence of this motif in 20 loci across the whole genome of M. smegmatis, supporting the existence of an AraC controlled regulon. To characterise the effects of AraC in the regulation of the nat operon genes, as well as to gain further insight into its function, we generated a ΔaraC mutant strain where the araC gene was replaced by a hygromycin resistance marker. The level of expression of the nat and MSMEG_0308 genes was down-regulated in the ΔaraC strain when compared to the wild type strain indicating an activator effect of the AraC protein on the expression of the nat operon genes