Tailored pyroresistive performance and flexibility by introducing a secondary thermoplastic elastomeric phase into graphene nanoplatelet (GNP) filled polymer composites for self-regulating heating devices

A guideline for the selection of a secondary elastomeric phase in self-regulating CPC blends.</p

New Perspectives on Glacial Geomorphology in Earth's Deep Time Record

International audienceThe deep time (pre-Quaternary) glacial record is an important means to understand the growth, development, and recession of the global cryosphere on very long timescales (10 6-10 8 Myr). Sedimentological description and interpretation of outcrops has traditionally played an important role. Whilst such data remain vital, new insights are now possible thanks to freely accessible aerial and satellite imagery, the widespread availability and affordability of Uncrewed Aerial Vehicles, and accessibility to 3D rendering software. In this paper, we showcase examples of glaciated landscapes from the Cryogenian, Ediacaran, Late Ordovician and Late Carboniferous where this approach is revolutionizing our understanding of deep time glaciation. Although some problems cannot be overcome (erosion or dissolution of the evidence), robust interpretations in terms of the evolving subglacial environment can be made. Citing examples from Australia (Cryogenian), China (Ediacaran), North and South Africa (Late Ordovician, Late Carboniferous), and Namibia (Late Carboniferous), we illustrate how the power of glacial geomorphology can be harnessed to interpret Earth's ancient glacial record

Dynamics of a stretched nonlinear polymer chain

We study the relaxation dynamics of a coarse-grained polymer chain at different degrees of stretching by both analytical means and numerical simulations. The macromolecule is modelled as a string of beads, connected by anharmonic springs, subject to a tensile force applied at the end monomer of the chain while the other end is fixed at the origin of coordinates. The impact of bond non-linearity on the relaxation dynamics of the polymer at different degrees of stretching is treated analytically within the Gaussian self-consistent approach (GSC) and then compared to simulation results derived from two different methods: Monte-Carlo (MC) and Molecular Dynamics (MD). At low and medium degrees of chain elongation we find good agreement between GSC predictions and the Monte-Carlo simulations. However, for strongly stretched chains the MD method, which takes into account inertial effects, reveals two important aspects of the nonlinear interaction between monomers: (i) a coupling and energy transfer between the damped, oscillatory normal modes of the chain, and (ii) the appearance of non-vanishing contributions of a continuum of frequencies around the characteristic modes in the power spectrum of the normal mode correlation functions.Comment: 17 pages, 9 figure

Radio and IR study of the massive star-forming region IRAS 16353-4636

Context. With the latest infrared surveys, the number of massive protostellar candidates has increased significantly. New studies have posed additional questions on important issues about the formation, evolution, and other phenomena related to them. Complementary to infrared data, radio observations are a good tool to study the nature of these objects, and to diagnose the formation stage. Aims. Here we study the far-infrared source IRAS 16353-4636 with the aim of understanding its nature and origin. In particular, we search for young stellar objects (YSOs), possible outflow structure, and the presence of non-thermal emission. Methods. Using high-resolution, multi-wavelength radio continuum data obtained with the Australia Telescope Compact Array, we image IRAS 16353-4636 and its environment from 1.4 to 19.6 GHz, and derive the distribution of the spectral index at maximum angular resolution. We also present new JHKs photometry and spectroscopy data obtained at ESO NTT. 13 CO and archival HI line data, and infrared databases (MSX, GLIMPSE, MIPSGal) are also inspected. Results. The radio continuum emission associated with IRAS 16353-4636 was found to be extended (~10 arcsec), with a bow-shaped morphology above 4.8 GHz, and a strong peak persistent at all frequencies. The NIR photometry led us to identify ten near-IR sources and classify them according to their color. We used the HI line data to derive the source distance, and analyzed the kinematical information from the CO and NIR lines detected. Conclusions. We have identified the source IRAS 16353-4636 as a new protostellar cluster. In this cluster we recognized three distinct sources: a low-mass YSO, a high-mass YSOs, and a mildly confined region of intense and non-thermal radio emission. We propose the latter corresponds to the terminal part of an outflow.Comment: To appear in A&A. 10 pages, 8 figure

A long-period Cepheid variable in the starburst cluster VdBH222

Galactic starburst clusters play a twin role in astrophysics, serving as laboratories for the study of stellar physics and also delineating the structure and recent star formation history of the Milky Way. In order to exploit these opportunities we have undertaken a multi-epoch spectroscopic survey of the red supergiant dominated young massive clusters thought to be present at both near and far ends of the Galactic Bar. Significant spectroscopic variability suggestive of radial pulsations was found for the yellow supergiant VdBH 222 #505. Follow-up photometric investigations revealed modulation with a period of ~23.325d; both timescale and pulsational profile are consistent with a Cepheid classification. As a consequence #505 may be recognised as one of the longest period Galactic cluster Cepheids identified to date and hence of considerable use in constraining the bright end of the period/luminosity relation at solar metallicities. In conjunction with extant photometry we infer a distance of ~6kpc for VdBH222 and an age of ~20Myr. This results in a moderate reduction in both integrated cluster mass (~2x10^4Msun) and the initial stellar masses of the evolved cluster members (~10Msun). As such, VdBH222 becomes an excellent test-bed for studying the properties of some of the lowest mass stars observed to undergo type-II supernovae. Moreover, the distance is in tension with a location of VdBH 222 at the far end of the Galactic Bar. Instead a birthsite in the near 3kpc arm is suggested; providing compelling evidence of extensive recent star formation in a region of the inner Milky Way which has hitherto been thought to be devoid of such activity

Family Trouble: Heteronormativity, emotion work and queer youth mental health

Conflict with the family about sexual orientation and gender diversity is a key risk factor associated with poor mental health in youth populations. Findings presented here derive from a UK study that employed an interdisciplinary critical mental health approach that de-pathologized emotional distress and conceptualised families as social and affective units that are created through everyday practices. Our aim was to explore how family relationships foster, maintain or harm the mental health and wellbeing of LGBTQ+ youth. Data were generated through exploratory visual, creative and digital qualitative methods in two phases. Phase 1 involved digital/paper emotion maps and interviews with LGBTQ+ youth aged 16-25 (n=12) and family member/mentor interviews (n=7). Phase 2 employed diary methods and follow-up interviews (n=9). The data analytic strategy involved three stages: individual case analysis; cross-sectional thematic analysis; and metainterpretation. We found that family relationships impacted on queer youth mental health in complex ways that were related to the establishment of their autonomous queer selves, the desire to remain belonging to their family and the need to maintain a secure environment. The emotion work involved in navigating identity, belonging and security was made difficult because of family heteronormativity, youth autonomy and family expectations and had a stark impact on queer youth mental health and wellbeing. Improving the mental health of LGBTQ+ youth requires a much deeper understanding of the emotionality of family relationships and the difficulties negotiating these as a young person

Dual Mechanism of Interleukin-3 Receptor Blockade by an Anti-Cancer Antibody

SummaryInterleukin-3 (IL-3) is an activated T cell product that bridges innate and adaptive immunity and contributes to several immunopathologies. Here, we report the crystal structure of the IL-3 receptor α chain (IL3Rα) in complex with the anti-leukemia antibody CSL362 that reveals the N-terminal domain (NTD), a domain also present in the granulocyte-macrophage colony-stimulating factor (GM-CSF), IL-5, and IL-13 receptors, adopting unique “open” and classical “closed” conformations. Although extensive mutational analyses of the NTD epitope of CSL362 show minor overlap with the IL-3 binding site, CSL362 only inhibits IL-3 binding to the closed conformation, indicating alternative mechanisms for blocking IL-3 signaling. Significantly, whereas “open-like” IL3Rα mutants can simultaneously bind IL-3 and CSL362, CSL362 still prevents the assembly of a higher-order IL-3 receptor-signaling complex. The discovery of open forms of cytokine receptors provides the framework for development of potent antibodies that can achieve a “double hit” cytokine receptor blockade

A CH3CN and HCO+ survey towards southern methanol masers associated with star formation

We present the initial results of a 3-mm spectral line survey towards 83 methanol maser selected massive star-forming regions. Here we report observations of the J=5-4 and 6-5 rotational transitions of methyl cyanide (CH3CN) and the J=1-0 transition of HCO+and H13CO+. CH3CN emission is detected in 58 sources (70 %) of our sample). We estimate the temperature and column density for 37 of these using the rotational diagram method. The temperatures we derive range from 28-166 K, and are lower than previously reported temperatures, derived from higher J transitions. We find that CH3CN is brighter and more commonly detected towards ultra-compact HII (UCHII) regions than towards isolated maser sources. Detection of CH3CN towards isolated maser sources strongly suggests that these objects are internally heated and that CH3CN is excited prior to the UCHII phase of massive star-formation. HCO+ is detected towards 82 sources (99 % of our sample), many of which exhibit asymmetric line profiles compared to H13CO+. Skewed profiles are indicative of inward or outward motions, however, we find approximately equal numbers of red and blue-skewed profiles among all classes. Column densities are derived from an analysis of the HCO+ and H13CO+ line profiles. 80 sources have mid-infrared counterparts: 68 seen in emission and 12 seen in absorption as `dark clouds'. Seven of the twelve dark clouds exhibit asymmetric HCO+ profiles, six of which are skewed to the blue, indicating infalling motions. CH3CN is also common in dark clouds, where it has a 90 % detection rate.Comment: 29 pages, 16 figures. Accepted for publication in MNRAS. For associated online figures please see http://www.phys.unsw.edu.au/~crp/papers/cpurcell_2005_online.pd