Feasibility study for a secondary Na/S battery

The feasibility of a moderate temperature Na battery was studied. This battery is to operate at a temperature in the range of 100-150 C. Two kinds of cathode were investigated: (1) a soluble S cathode consisting of a solution of Na2Sn in an organic solvent and (2) an insoluble S cathode consisting of a transition metal dichalcogenide in contact with a Na(+)ion conducting electrolyte. Four amide solvents, dimethyl acetamide, diethyl acetamide, N-methyl acetamide and acetamide, were investigated as possible solvents for the soluble S cathode. Results of stability and electrochemical studies using these solvents are presented. The dialkyl substituted amides were found to be superior. Although the alcohol 1,3-cyclohexanediol was found to be stable in the presence of Na2Sn at 130 C, its Na2Sn solutions did not appear to have suitable electrochemical properties

Collection of forage crop germplasm throughout Iowa

A successful forage breeding program starts with a supply of germplasm containing adequate genetic diversity to serve as the foundation for better cultivars. No collection of forage breeding materials unique to Iowa has been done in 50 years. In this project, plants were collected from 20 pastures throughout the state. The plants\u27 mere presence suggested that they had already survived the drought, cold temperatures, and extensive grazing that occur in Iowa, which made them good subjects for breeding purposes

‘A double-edged sword. This is powerful but it could be used destructively’: Perspectives of early career education researchers on learning analytics

Learning analytics has been increasingly outlined as a powerful tool for measuring, analysing, and predicting learning experiences and behaviours. The rising use of learning analytics means that many educational researchers now require new ranges of technical analytical skills to contribute to an increasingly data-heavy field. However, it has been argued that educational data scientists are a ‘scarce breed’ (Buckingham Shum et al., 2013) and that more resources are needed to support the next generation of early career researchers in the education field. At the same time, little is known about how early career education researchers feel towards learning analytics and whether it is important to their current and future research practices. Using a thematic analysis of a participatory learning analytics workshop discussions with 25 early career education researchers, we outline in this article their ambitions, challenges and anxieties towards learning analytics. In doing so, we have provided a roadmap for how the learning analytics field might evolve and practical implications for supporting early career researchers’ development

Coccolithophore fluxes in the open tropical North Atlantic: influence of thermocline depth, Amazon water, and Saharan dust

Coccolithophores are calcifying phytoplankton and major contributors to both the organic and inorganic oceanic carbon pumps. Their export fluxes, species composition, and seasonal patterns were determined in two sediment trap moorings (M4 at 12 degrees N, 49 degrees W and M2 at 14 degrees N, 37 degrees W) collecting settling particles synchronously from October 2012 to November 2013 at 1200 m of water depth in the open equatorial North Atlantic. The two trap locations showed a similar seasonal pattern in total coccolith export fluxes and a predominantly tropical coccolithophore settling assemblage. Species fluxes were dominated throughout the year by lower photic zone (LPZ) taxa (Florisphaera profunda, Gladiolithus flabellatus) but also included upper photic zone (UPZ) taxa (Umbellosphaera spp., Rhabdosphaera spp., Umbilicosphaera spp., Helicosphaera spp.). The LPZ flora was most abundant during fall 2012, whereas the UPZ flora was more important during summer. In spite of these similarities, the western part of the study area produced persistently higher fluxes, averaging 241 x 10(7) +/- 76 x 10(7) coccoliths m(-2) d(-1) at station M4 compared to only 66 x 10(7) +/- 31 x 10(7) coccoliths m(-2) d(-1) at station M2. Higher fluxes at M4 were mainly produced by the LPZ species, favoured by the westward deepening of the thermocline and nutricline. Still, most UPZ species also contributed to higher fluxes, reflecting enhanced productivity in the western equatorial North Atlantic. Such was the case of two marked flux peaks of the more opportunistic species Gephyrocapsa muellerae and Emiliania huxleyi in January and April 2013 at M4, indicating a fast response to the nutrient enrichment of the UPZ, probably by wind-forced mixing. Later, increased fluxes of G. oceanica and E. huxleyi in October-November 2013 coincided with the occurrence of Amazon-River-affected surface waters. Since the spring and fall events of 2013 were also accompanied by two dust flux peaks, we propose a scenario in which atmospheric dust also provided fertilizing nutrients to this area. Enhanced surface buoyancy associated with the river plume indicates that the Amazon acted not only as a nutrient source, but also as a surface density retainer for nutrients supplied from the atmosphere. Nevertheless, lower total coccolith fluxes during these events compared to the maxima recorded in November 2012 and July 2013 indicate that transient productivity by opportunistic species was less important than "background" tropical productivity in the equatorial North Atlantic. This study illustrates how two apparently similar sites in the tropical open ocean actually differ greatly in ecological and oceanographic terms. The results presented here provide valuable insights into the processes governing the ecological dynamics and the downward export of coccolithophores in the tropical North Atlantic.Netherlands Organization for Scientific Research (NWO) [822.01.008]; European Research Council (ERC) [311152]; University of Bremen; European Union [600411]info:eu-repo/semantics/publishedVersio

Feminist foreign policy in Israel and Germany? The Women, Peace, and Security agenda, development policy, and female representation

This paper explores the relationship between feminist foreign policy (FFP) and a country’s national role conception (NRC). Specifically, it asks whether countries with ‘masculine’ NRCs are opposed to the pursuit of FFP while countries with a more ‘feminine’ national role conception are advocates of FFP. To this end, the paper conducts a comparative analysis of ‘masculine’ Israel and ‘feminine’ Germany along three domains: normative (with a focus on the Women, Peace, and Security [WPS] agenda), material (in relation to development policy), and institutional (with reference to female representation). Generally speaking, Germany has indeed undertaken broader and more substantive activities in pursuit of FFP goals than Israel. At the same time, Israel has clearly been more active than its ‘masculine’ role would suggest, and Germany less active and vocal than its ‘civilian power’ role would imply. Overall, the discussion suggests that whether countries pursue FFP goals is strongly influenced by the latter’s compatibility with the countries’ overarching NRCs, with party ideology, institutional autonomy, and intersection between gender policy and state interests playing a greater role regarding the specific levels of commitment and intensity shown in the pursuit of those goals

Controlling Silver Nanoparticle Size and Morphology with Photostimulated Synthesis

Photo-induced synthesis and control over the size and shape of colloidal silver nanoparticles is investigated in contrast to photo-stimulated aggregation of small nanoparticles into large fractal-type structures. The feasibility of light-driven nanoengineering which enables manipulation of the sizes and shapes of the isolated nanoparticles is studied by varying the amount and type of the stabilizing agent and the type of optical irradiation.Comment: 10 pages, 7 figures, 11 image

Dirac Gauginos and Kinetic Mixing

We present formulae for the calculation of Dirac gaugino masses at leading order in the supersymmetry breaking scale using the methods of analytic continuation in superspace and demonstrate a link with kinetic mixing, even for non-abelian gauginos. We illustrate the result through examples in field and string theory. We discuss the possibility that the singlet superfield that gives the U(1) gaugino a Dirac mass may be a modulus, and some consequences of the D-term coupling to the scalar component. We give examples of possible effects in colliders and astroparticle experiments if the modulus scalar constitutes decaying dark matter.Comment: 17 pages, no figures. Published version, one reference adde

Holocene earthquake-triggered mass-wasting events recorded in the sediments of Lake Puyehue (South-Central Chile)

Despite South-Central Chile’s high seismicity and the occurrence of earth’s largest instrumentally recorded earthquake (AD 1960; Mw: 9.5), paleoseismic data is still scarce for this region. In this study, very high-resolution reflection seismic profiles (3.5 kHz) in Lake Puyehue (41°S) were utilized to trace giant seismic events back into time. The seismic profiles show repeated occurrences of multiple mass-wasting deposits (slumps, debris flows, homogenites) occurring at a same seismic-stratigraphic horizon, indicating that they are coeval and caused by a single mass-wasting event of basin-wide importance. An age-depth model, based on 9 AMS radiocarbon datings and varve-counting on an 11 m-long sediment core, has been used to develop a “seismic chronostratigraphy”. It allows dating of the mass-wasting events by interpolation between dated seismic horizons to the distal parts of the mass-wasting deposits. The mass-wasting events are assumed to be earthquake-triggered because:The recentmost mass-wasting events correlate with the devastating historical earthquakes of AD 1575 and AD 1960.Synchronicity of multiple slope failures (mass-wasting events) requires a strong regional trigger, such as an earthquake. Consequently, local slope oversteepening at delta fronts or local fluid expulsion could not initiate such widespread events.South-Central Chile has been historically subjected to several strong (M > 8) subduction earthquakes and subduction processes have been constantly active since Mesozoic times.Multiple slope failures occur at water depths > 70 m, which rules out shallow instability triggers, such as storm wave action and lake-level fluctuations.This study reveals nine paleoseismic events during the Holocene with a mean recurrence rate of about 1000 yr, but with an overall relatively aperiodic occurrence (ranging between 400-2000 yrs.). The most prominent event took place around 1660 cal. yr. BP, evidenced by at least 29 simultaneous mass-movements and a homogenite deposit. Quantitative comparison of mass-wasting events related to the historical earthquakes of AD 1960 and AD 1575 showed significant differences (respectively 17 and 4 observed mass-wasting deposits) although these earthquakes are assumed to have had a comparable strength. This can be attributed to a lowered sedimentation rate on the potentially unstable slopes in the period 3000 cal. yr. BP – 500 cal. yr. BP, which would have made lacustrine earthquake recording less likely in AD 1575. The absence of mass-wasting deposits associated with other historical earthquakes (e.g.: AD 1737 (Ms: 7.5) and AD 1837 (Ms: 8)) indicates that only mega-earthquakes (Mw >8.5) within a range of about 300 km are recorded in the sedimentary sequence of Lake Puyehue.Reflection seismic profiles also show vertical fluidisation structures with large-scale sediment injections, which disturb the upper sedimentary sequences. The top of these fluidisation structures and diverse deformation levels could be spatially linked to seismically induced mass-wasting deposits and consequently indicate an additional method for lacustrine paleo-earthquake tracing.Several reconaissance seismic surveys on other glacigenic lakes in the Chilean Lake District also show promising paleoseismic records, which will offer the opportunity to correlate lacustrine records to reveal South-Central Chile’s paleoseismic history in detail and the earthquake registration capacities of its glacigenic lakes