Mechanical behavior of chemically-treated hemp fibers reinforced composites subjected to moisture absorption

Natural Fibers Reinforced Composites (NFRC) are finding much interest as substitutes for glass- or carbon-reinforced composites thanks to their lightness, easy handling, processing and recyclability. However, their polarity makes them incompatible with hydrophobic thermoplastic matrices, leading to extended moisture adsorption which causes the debonding between fibers and matrix, affecting, thus, the mechanical properties of NFRCs. In the present work, NFRCs were manufactured using hemp fibers previously chemically treated with NaOH alkali solutions or (3-Glycidyloxypropyl) trimethoxysilane (GPTMS) solutions of various concentrations. To assess the effectiveness of the used chemical treatments in hindering the moisture adsorption and the entailed mechanical failure of the NFRCs, untreated and treated hemp fibers based composites were subjected to moisture adsorption test and then to tensile testing as a function of the chemical treatment, temperature and concentration of reagents. The results show that the treatments with 5 wt% of both NaOH and GPTMS are the most effective, reducing composites' water uptake from 7.74% to 6.46% and 5.58% respectively at room temperature, and from 9.67% to 8.19% and 8.13% respectively at 50 °C. Moreover, the comparison between the mechanical testing results carried out before and after the moisture adsorption test, shows that the water uptake induces mainly a stiffness decrease (about 50% when alkali treatments were used and about 60% using silane treatment), while not significantly affect the loading capability of the composites regardless of chemical treatment. However, the specimen obtained using 5 wt% GPTMS is more effective in the prevent the failure of the composite induced by water uptake

The static and time-dependent signature of ocean–continent and ocean–ocean subduction: the case studies of Sumatra and Mariana complexes

SUMMARY The anomalous density structure at subduction zones, both in the wedge and in the upper mantle, is analysed to shed light on the processes that are responsible for the characteristic gravity fingerprints of two types of subduction: ocean–continent and ocean–ocean. Our modelling is then performed within the frame of the EIGEN-6C4 gravitational disturbance pattern of two subductions representative of the above two types, the Sumatra and Mariana complexes, finally enabling the different characteristics of the two patterns to be observed and understood on a physical basis, including some small-scale details. A 2-D viscous modelling perpendicular to the trench accounts for the effects on the gravity pattern caused by a wide range of parameters in terms of convergence velocity, subduction dip angle and lateral variability of the crustal thickness of the overriding plate, as well as compositional differentiation, phase changes and hydration of the mantle. Plate coupling, modelled within a new scheme where the relative velocity at the plate contact results self-consistently from the thermomechanical evolution of the system, is shown to have an important impact on the gravity signature. Beyond the already understood general bipolar fingerprint of subduction, perpendicular to the trench, we obtain the density and gravity signatures of the processes occurring within the wedge and mantle that are responsible for the two different gravity patterns. To be compliant with the geodetic EIGEN-6C4 gravitational disturbance and to compare our predictions with the gravity at Sumatra and Mariana, we define a model normal Earth. Although the peak-to-peak gravitational disturbance is comparable for the two types of subductions, approximately 250 mGal, from both observations and modelling, encompassing the highest positive maximum on the overriding plates and the negative minimum on the trench, the trough is wider for the ocean–ocean subduction: approximately 300 km compared to approximately 180 km for the ocean–continent subduction. Furthermore, the gravitational disturbance pattern is more symmetric for the ocean–ocean subduction compared to the ocean–continent subduction in terms of the amplitudes of the two positive maxima over the overriding and subducting plates. Their difference is, for the ocean–ocean type, approximately one half of the ocean–continent one. These different characteristics of the two types of subductions are exploited herein in terms of the different crustal thicknesses of the overriding plate and of the different dynamics in the wedge and in the mantle for the two types of subduction, in close agreement with the gravity data

estimating the learning curve of solar pv balance of system for over 20 countries implications and policy recommendations

Abstract Solar photovoltaic systems installed on homes and commercial building rooftops are deemed central for a low-carbon future. As capital costs of photovoltaics continue to fall, its role towards making buildings more sustainable and environmentally-friendly will continue to grow. Capital costs of a photovoltaic system comprise the module and balance-of-system costs. The latter refers to everything-else needed to make the photovoltaic system functional including cables, mounts, labor, etc. While modules are priced internationally, the balance-of-system cost is country-specific. Price developments of modules, which have been thoroughly studied in literature, followed an 80% learning curve. Research on the balance-of-system learning curve however, has not been as extensive. In this paper, we estimate for the first time the learning curve of balance-of-system costs in photovoltaics for more than 20 countries via an extensive dataset. Our calculations yield a global learning curve for the balance-of-system of 89%, which corresponds to a progress ratio of 11% compared with 20% for modules. Understanding the rate at which capital costs of photovoltaics are falling with such detail will aid in more effective renewable energy policy planning and budgeting. Finally, some steps requiring no financial commitment but can bring down balance-of-system costs are discussed, which greatly contribute to a cleaner and more sustainable future

Alterations in cellular metabolism modulate CD1d-mediated NKT-cell responses

Natural killer T (NKT) cells play a critical role in the host's innate immune response. CD1d-mediated presentation of glycolipid antigens to NKT cells has been established; however, the mechanisms by which NKT cells recognize infected or cancerous cells remain unclear. 5′-AMP activated protein kinase (AMPK) is a master regulator of lipogenic pathways. We hypothesized that activation of AMPK during infection and malignancy could alter the repertoire of antigens presented by CD1d and serve as a danger signal to NKT cells. In this study, we examined the effect of alterations in metabolism on CD1d-mediated antigen presentation to NKT cells and found that an infection with lymphocytic choriomeningitis virus rapidly increased CD1d-mediated antigen presentation. Hypoxia inducible factors (HIF) enhance T-cell effector functions during infection, therefore antigen presenting cells pretreated with pharmacological agents that inhibit glycolysis, induce HIF and activate AMPK were assessed for their ability to induce NKT-cell responses. Pretreatment with 2-deoxyglucose, cobalt chloride, AICAR and metformin significantly enhanced CD1d-mediated NKT-cell activation. In addition, NKT cells preferentially respond to malignant B cells and B-cell lymphomas express HIF-1α. These data suggest that targeting cellular metabolism may serve as a novel means of inducing innate immune responses

Effects of Bariatric Surgery on COVID-19: a Multicentric Study from a High Incidence Area

Introduction: The favorable effects of bariatric surgery (BS) on overall pulmonary function and obesity-related comorbidities could influence SARS-CoV-2 clinical expression. This has been investigated comparing COVID-19 incidence and clinical course between a cohort of patients submitted to BS and a cohort of candidates for BS during the spring outbreak in Italy. Materials and Methods: From April to August 2020, 594 patients from 6 major bariatric centers in Emilia-Romagna were administered an 87-item telephonic questionnaire. Demographics, COVID-19 incidence, suggestive symptoms, and clinical outcome parameters of operated patients and candidates to BS were compared. The incidence of symptomatic COVID-19 was assessed including the clinical definition of probable case, according to World Health Organization criteria. Results: Three hundred fifty-three operated patients (Op) and 169 candidates for BS (C) were finally included in the statistical analysis. While COVID-19 incidence confirmed by laboratory tests was similar in the two groups (5.7% vs 5.9%), lower incidence of most of COVID-19-related symptoms, such as anosmia (p: 0.046), dysgeusia (p: 0.049), fever with rapid onset (p: 0.046) were recorded among Op patients, resulting in a lower rate of probable cases (14.4% vs 23.7%; p: 0.009). Hospitalization was more frequent in C patients (2.4% vs 0.3%, p: 0.02). One death in each group was reported (0.3% vs 0.6%). Previous pneumonia and malignancies resulted to be associated with symptomatic COVID-19 at univariate and multivariate analysis. Conclusion: Patients submitted to BS seem to develop less severe SARS-CoV-2 infection than subjects suffering from obesity

Non-CO2 generating energy shares in the world : cross-country differences and polarization.

The aim of this paper is to examine the spatial distribution of non-CO2 generating energy sources in the world for the period 1990–2009, paying special attention to the evolution of cross-country disparities. To this end, after carrying out a classical convergence analysis, a more thorough investigation of the entire distribution is presented by examining its external shape, the intra-distribution dynamics and the long-run equilibrium distribution. This analysis reveals the existence of a weak, rather insignificant, convergence process and that large crosscountry differences are likely to persist in the long-run. Next, as polarization indicators are a proper way of appraising potential conflict in international environmental negotiations, we test whether, or not, the distribution dynamics concurs with the presence of polarization. Our results indicate that two poles can be clearly differentiated, one with high and other with low non-CO2 generating energy shares. In view of these findings, and to ensure a fair transition to a sustainable energy system, the paper calls for the development of an ambitious clean energy agenda, especially in countries with low non-CO2 generating energy shares

Stress corrosion cracking behavior of welding joint of high strength steel

Nowadays, high-strength steel structures are increasingly being used in marine or soil environments, but low attention has been paid on the corrosion and stress corrosion cracking problem. In this paper, the susceptibility to stress corrosion cracking (SCC) of butt-welding joints of Strenx (R) 700 (S690QL high strength steel) both in marine and acid-polluted marine atmospheres was studied, by using slow strain rate tensile (SSRT) test. The seawater corrosion environment was considered and it was prepared following the ASTM D1141. To study the influence of the environment pH, NaOH 0,1M solutions and pure H2SO4 were used to adjust the pH of the simulated seawater solution to 8 and 4, respectively. The slow strain rate tensile tests (SSRT) with a crosshead speed of 0.000017 mm/s were carried out at room temperature (approximately 25 degrees C). After failure, the SCC susceptibility was evaluated acquiring the elongation loss rate and the reduction-in-area loss rate. The fracture surfaces were analyzed by SEM observation

L'arte in opera. Itinerari di G\ue9rard Genette

Delineazione complessiva della figura e del pensiero di Genette, con particolare riferimento, da varie angolazioni, alla sua riflessione estetica, approdo fondamentale di un lungo viaggio fra varie discipline: retorica, poetica, narratologia, teoria della critica

Mechanical behavior of chemically-treated hemp fibers reinforced composites subjected to moisture absorption

Natural Fibers Reinforced Composites (NFRC) are finding much interest as substitutes for glass-or carbon-reinforced composites thanks to their lightness, easy handling, processing and recyclability. However, their polarity makes them incompatible with hydrophobic thermoplastic matrices, leading to extended moisture adsorption which causes the debonding between fibers and matrix, affecting, thus, the mechanical properties of NFRCs. In the present work, NFRCs were manufactured using hemp fibers previously chemically treated with NaOH alkali solutions or (3-Glycidyloxypropyl) trimethoxysilane (GPTMS) so-lutions of various concentrations. To assess the effectiveness of the used chemical treat-ments in hindering the moisture adsorption and the entailed mechanical failure of the NFRCs, untreated and treated hemp fibers based composites were subjected to moisture adsorption test and then to tensile testing as a function of the chemical treatment, tem-perature and concentration of reagents. The results show that the treatments with 5 wt% of both NaOH and GPTMS are the most effective, reducing composites' water uptake from 7.74% to 6.46% and 5.58% respectively at room temperature, and from 9.67% to 8.19% and 8.13% respectively at 50 degrees C. Moreover, the comparison between the mechanical testing results carried out before and after the moisture adsorption test, shows that the water uptake induces mainly a stiffness decrease (about 50% when alkali treatments were used and about 60% using silane treatment), while not significantly affect the loading capability of the composites regardless of chemical treatment. However, the specimen obtained using 5 wt% GPTMS is more effective in the prevent the failure of the composite induced by water uptake.(c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)