Tetragonal CuO: A new end member of the 3d transition metal monoxides

Monoclinic CuO is anomalous both structurally as well as electronically in the 3$d$ transition metal oxide series. All the others have the cubic rock salt structure. Here we report the synthesis and electronic property determination of a tetragonal (elongated rock salt) form of CuO created using an epitaxial thin film deposition approach. In situ photoelectron spectroscopy suggests an enhanced charge transfer gap $\Delta$ with the overall bonding more ionic. As an end member of the 3d transition monoxides, its magnetic properties should be that of a high $T_N$ antiferromagnet

Two-Speed Britain : rural Internet Use

The research described herein was supported by the award made by the RCUK Digital Economy programme to the dot.rural Digital Economy Hub; award reference: EP/G066051/1.Publisher PDFPublisher PDFPublisher PD

Social media in the changing ecology of news: The Fourth and

Abstract: This paper provides a case study of the changing patterns of news production and consumption in the UK that are being shaped by the Internet and related social media. Theoretically, this focus addresses concern over whether the Internet is undermining the Fourth Estate role of the press in liberal democratic societies. The case study draws from multiple methods, including survey research of individuals in Britain from 2003-2011, analysis of log files of journalistic sites, and interviews with journalists. Survey research shows a step-jump in the use of online news since 2003 but a levelling off since 2009. However, the apparent stability in news consumption masks the growing role of social network sites. The analyses show that the Fourth Estate -the institutional news media -is using social media to enhance their role in news production and dissemination. However, networked individuals have used social media to source and distribute their own information in ways that achieve a growing independence from the Fourth Estate journalism. As more information moves online and individuals become routinely linked to the Internet, an emerging Fifth Estate, built on the activities of networked individuals sourcing and distributing their own information, is developing a synergy with the Fourth Estate as each builds on and responds to the other in this new news ecology. Comparative data suggests that this phenomenon is likely to characterize the developing news ecology in other liberal democratic societies as well, but more comparative research is required to establish the validity of this model

Live versus Archive: Comparing a Web Archive and to a Population of Webpages

With its seemingly limitless scope, the World Wide Web promises enormous advantages, along with enormous problems, to researchers who seek to use it as a source of data. Websites change continually and a high level of flux makes it challenging to capture a snapshot of the web, or even a cross-section of a small subset of the web. A web archive, such as those at the Internet Archive, promises to store and deliver repeated cross-sections of the entire web, and it also offers the potential for longitudinal analysis. Whether this potential is realized depends on the extent to which the archive has truly captured the web. Therefore, a crucial question for Internet researchers is: ‘How good are the archival data?’ We ask if there are systematic biases in the Internet Archive, using a case study to address this question. Specifically, we are interested in whether biases exist in the British websites stored in the Internet Archive data. We find that the Internet Archive contains a surprisingly small subset, about 24%, of the webpages of the website that we use for our case study (the travel site, TripAdvisor). Furthermore, the subset of data we found in the Internet Archive appears to be biased and is not a random sample of the webpages on the site. The archived data we examine has a bias toward prominent webpages. This bias could create serious problems for research using archived websites

Blurring the Boundaries? New social media, new social research: Developing a network to explore the issues faced by researchers negotiating the new research landscape of online social media platforms

This paper emerges from a programme of workshops and social media activities exploring the impact of social media on social science research funded by NCRM during 2012-13. The New Social Media, New Social Science? Network (NSMNSS) brought together an international network of interdisciplinary researchers to discuss the possibilities and challenges these new social media platforms and worlds pose for social science researchers. The main questions we sought to address in our networked activities were

Resilience as a concept for understanding family caregiving of adults with Chronic Obstructive Pulmonary Disease (COPD): an integrative review

Abstract Aims: This paper was a report of the synthesis of evidence on examining the origins and definitions of the concept of resilience, investigating its application in chronic illness management and exploring its utility as a means of understanding family caregiving of adults with Chronic Obstructive Pulmonary Disease. Background: Resilience is a concept that is becoming relevant to understanding how individuals and families live with illness, especially long-term conditions. Caregivers of adults with Chronic Obstructive Pulmonary Disease must be able to respond to exacerbations of the condition and may themselves experience cognitive imbalances. Yet, resilience as a way of understanding family caregiving of adults with COPD is little explored. Design: Literature review – integrative review. Data sources: CINAHL, PubMed, Google Scholar and EBSCO were searched between 1989–2015. Review methods: The principles of rapid evidence assessment were followed. Results: We identified 376 relevant papers: 20 papers reported the presence of the concept of resilience in family caregivers of chronic diseases patients but only 12 papers reported the presence of the concept of resilience in caregivers of Chronic Obstructive Pulmonary Disease patients and have been included in the synthesis. The term resilience in Chronic Obstructive Pulmonary Disease caregiving is most often understood using a deficit model of health

The metabolic cost of flagellar motion in Pseudomonas putida KT2440

Although the flagellar machinery of environmental bacteria endows cells with a phenomenal survival device, it also consumes much of the metabolic currency necessary for fuelling such a vigorous nanomotor. The physiological cost of flagella-related functions of the soil bacterium Pseudomonas putida KT2440 was examined and quantified through the deletion of a ∼ 70 kb DNA segment of the genome (∼ 1.1%), which includes relevant structural and regulatory genes in this micro-organism. The resulting strain lacked the protruding polar cords that define flagella in the wild-type P. putida strain and was unable of any swimming motility while showing a significant change in surface hydrophobicity. However, these deficiencies were otherwise concomitant with clear physiological advantages: rapid adaptation of the deleted strain to both glycolytic and gluconeogenic carbon sources, increased energy charge and, most remarkably, improved tolerance to oxidative stress, reflecting an increased NADPH/NADP+ ratio. These qualities improve the endurance of nonflagellated cells to the metabolic fatigue associated with rapid growth in rich medium. Thus, flagellar motility represents the archetypal tradeoff involved in acquiring environmental advantages at the cost of a considerable metabolic burden.This study was supported by the BIO and FEDER CONSOLIDER-INGENIO Program, the MICROME, STFLOW and ARISYS Contracts of the EU, the ERANET-IB program and the PROMT Project of the CAM.Peer reviewe