Co-composting process of (Sugarbeet) vinasse and grape marc

4 páginas, 2 figuras, 1 tabla, 9 referencias.-- European Commission International Symposium.Beet vinasse, a high density liquid waste from the sugar industry, and grape marc, a primary by-product of wine production, could be recycled as fertilizers due to their high OM and nutrient contents. The direct incorporation of grape marc into agricultural land, a common practice, has become a serious problem because degradation products inhibiting root growth are released (Inbar et al., 1991). Furthermore, the direct aplication of vinasse has also several shortcomings because of its high salinity (EC 250–300 dS m–1), low P content (P2O5 0.012%) and liquid dense character (1.3 g cm–3). An alternative to overcome these disadvantages is the co-composting of vinasse with grape marc.Peer reviewe

NH4F Modified Al-SBA-15 Materials for Esterification of Valeric Acid to Alkyl Valerates

Al-SBA-15 materials were functionalized by ball milling with several niobium loadings (0.25–1 wt.%) and/or with several F- loadings, using NH4F as a precursor. The catalysts synthesized in this study were characterised by X-ray diffraction (XRD), N2 porosimetry, and diffuse reflection infrared spectroscopy (DRIFT) among others. The prepared materials shown, form moderate to high catalytic activities in the microwave-assisted transformation of valeric acid to ethyl valerate via esterification. The incorporation of fluoride anions either into Al-SBA-15 or on Nb1%/Al-SBA-15 led to a linear increase in valeric acid conversion with the F− content. Thus, F− modified mesoporous aluminosilicates efficiently catalyze the transformation of valeric acid into alkyl valerate esters as renewable fuels

Materialities, Space, Mind: Archaeology of Visual Cognition

A perceptual study of different styles of prehistoric Galician ceramics (from 6000 to 2000 BP) conducted by eye-tracking, underpins the material engagement of mind by showing that the visual world fosters the entanglement between doing, seeing, and designing through history. This text examines how materializations of human practices relate to cognition and to socio-cultural contexts. By combining evidence on the relationship between material culture and perceptual reactions, our text aims to understand the entanglement between the mind, objects and the world. We apply measurable and numeric techniques, providing an archaeometric approach to cognitive topics by combining neurosciences with interpretive and reflective research. This research provides new insights into the material culture, contributes to the understanding of the relationship between mind and the material world, and accounts for the transitive engagement between the way of thinking, seeing and making things. Thus, the text contributes to an understanding of the material forces driving perception and thought

Milk production and adjustment of lactation curve in the Florida caprine breed

Milk yield and average lactation curves is studied in the Florida caprine breed. 968 valid lactations are analyzed corresponding to 317 females kept under a semi-extensive management system, fed by grazing and additional in the feeding rack, with an average feed intake of 1783 g/day of dry matter in autumn-winter, 2938 g/day in spring and 1974 g/day in summer. The milking was done in the morning, and the milk control monthly. Milk production was determined with the adaptation of Carré to the Fleischmann method. A 71.6 percent of the lactations have a duration that fluctuates between 188 and 341 days, being the average duration 301.5 ± 3 days. The lactations that initiate in winter-spring are of shorter than the ones of summer-autumn (288.4±3.6 days vs 315.5±5.2 days), the same as the first lactation in comparison to the rest (283.7±4.8 days vs 310.5±3.8 days). The type of kidding doesn"t affect significantly the duration of the lactation. The milk yield to 210, 240, 270 days and complete lactation is 475.3±4.3 kg, 538.9±5.0 kg, 598.5±6.3 kg and 611.4±7.8 kg, respectively. The females that kid in winter-spring produce more quantity of milk until 270 days of lactation, although their production is less at complete lactation due to its shorter duration. The primiparous goats produce a 19-20 percent less quantity of milk than the multiparous goats, while the ones that kid more than one kid produce a 38-40 percent more than the ones having a simple kid or abortions. The Inverse polynomial and Incomplete gamma functions present a similar adjustment (R2= 0.943; CME=0.5361 and 0.5365), although they show differences in the components of the lactation curve: the initial production is estimated in 0.82 kg/d and 2.56 kg/d; maximum production in 2.71 kg/d and 2.68 kg/d; the peak production at day 27 and 13, and the decrese in 4.58 g/d and 4.32 g/d, respectively.Se estudia la producción láctea y la curva de lactación en caprinos de raza Florida. Se analizan 968 lactaciones válidas correspondientes a 317 hembras manejadas en un régimen semiextensivo, alimentadas a pasto más suplementación en pesebre, con un nivel de ingesta medio de 1783 g/día de materia seca en otoño-invierno, 2938 g/día en primavera y 1974 g/día en verano. El ordeño se efectuaba por la mañana, y el control lechero se realizaba mensualmente. La producción de leche se determinó con la adaptación de Carré al método de Fleishmann. El 71,6 p.100 de las lactaciones tienen una duración comprendida entre 188 y 341 días, siendo la duración media de 301,5±3 días. Las lactaciones que se inician en invierno-primavera son más cortas que las de verano-otoño (288,4±3,6 días vs 315,5±5,2 días), al igual que la primera lactación frente a las restantes (283,7±4,8 días vs 310,5±3,8 días). El tipo de parto no afecta significativamente la duración de la lactación. La producción de leche tipificada a 210, 240 y 270 días y a lactación completa es de 475,3±4,3 kg, 538,9±5,0 kg, 598,5±6,3 kg y 611,4±7,8 kg, respectivamente. Las hembras que paren en invierno- primavera producen mayor cantidad de leche hasta 270 días de lactación, en tanto que su producción es menor a lactación completa por su menor duración. Las cabras primíparas producen un 19-20 p.100 menos cantidad de leche que las multíparas, mientras que las que paren más de un cabrito producen un 38-40 p.100 más que las de parto simple o abortos. Las funciones Polinomial inversa y Gamma incompleta presentan un ajuste similar (R2= 0,943; C.M.E= 0,5361 y 0,5365), aunque muestran diferencias en las componentes de la curva de lactación: la producción inicial se estima en 0,82 kg/d y 2,56 kg/d, la producción máxima en 2,71 kg/d y 2,68 kg/d, el pico de lactación al día 27 y 13, y el descenso en 4,58 g/d y 4,32 g/d, respectivamente

A Modular Mobile Robotic Platform to Assist People with Different Degrees of Disability

Robotics to support elderly people in living independently and to assist disabled people in carrying out the activities of daily living independently have demonstrated good results. Basically, there are two approaches: one of them is based on mobile robot assistants, such as Care-O-bot, PR2, and Tiago, among others; the other one is the use of an external robotic arm or a robotic exoskeleton fixed or mounted on a wheelchair. In this paper, a modular mobile robotic platform to assist moderately and severely impaired people based on an upper limb robotic exoskeleton mounted on a robotized wheel chair is presented. This mobile robotic platform can be customized for each user’s needs by exploiting its modularity. Finally, experimental results in a simulated home environment with a living room and a kitchen area, in order to simulate the interaction of the user with different elements of a home, are presented. In this experiment, a subject suffering from multiple sclerosis performed different activities of daily living (ADLs) using the platform in front of a group of clinicians composed of nurses, doctors, and occupational therapists. After that, the subject and the clinicians replied to a usability questionnaire. The results were quite good, but two key factors arose that need to be improved: the complexity and the cumbersome aspect of the platform.This work was supported by the AIDE project through Grant Agreement No. 645322 of the European Commission, by the Conselleria d’Educacio, Cultura i Esport of Generalitat Valenciana, by the European Social Fund—Investing in your future, through the grant ACIF 2018/214, and by the Promoción de empleo joven e implantación de garantía juvenil en I+D+I 2018 through the grant PEJ2018-002670-A

Evaluation of factors influencing road dust loadings in a Latin American urban center

Vehicle non-exhaust emissions are a major component of particle matter, including the direct wear of tires, brakes, road, and the resuspension of deposited particles. It is suggested that resuspended PM (RPM) emissions can be at the same magnitude or even larger than combustion emissions in urban centers. Factors affecting RPM can be included in four categories: road characteristics, traffic condition, land use, and meteorology. In order to study and evaluate these influencing factors, road dust less than 10 micrometers (RD10) was collected in 41 sites across Bogotá. The sampling points had diverse characteristics. RD10 levels varied between 1.0 and 45.8 mg/m2 with an average of 8.9 ± 8.4 mg/m2. Lower RD10 values were observed when vegetation density was high, pavement condition good, driving speeds fast and construction activities absent. On the contrary, RD10 increased under heavy-duty traffic influence and dry conditions. Among dust mitigation measures, management of land-use variables could be as important as traffic control and road maintenance.Implications: This study documented for the first time in Latin America dust loadings less than 10 micrometers, information that can be used to estimate resuspended particle matter emissions in the region. The influence of meteorology, traffic characteristics, road condition, and land-use variables was analyzed and quantified. The management of land-use variables could be as important as traffic control and road maintenance for road dust mitigation. Further research interests are discussed

Controlled manipulation of enzyme specificity through immobilization-induced flexibility constraints

It is thought that during immobilization enzymes, as dynamic biomolecules, may become distorted and this may alter their catalytic properties. However, the effects of different immobilization strategies on enzyme rigidity or flexibility and their consequences in specificity and stereochemistry at large scale has not been yet clearly evaluated and understood. This was here investigated by using as model an ester hydrolase, isolated from a bacterium inhabiting a karstic lake, with broad substrate spectrum (72 esters being converted; 61.5 U mg−1 for glyceryl tripropionate) but initially non-enantiospecific. We found that the enzyme (7 nm × 4.4 nm × 4.2 nm) could be efficiently ionic exchanged inside the pores (9.3 nm under dry conditions) of amino-functionalized ordered mesoporous material (NH2-SBA-15), achieving a protein load of 48 mg g−1, and a specific activity of 4.5 ± 0.1 U mg−1. When the enzyme was site-directed immobilized through His interaction with an immobilized cationon the surface of two types of magnetic micro-particles through hexahistidine-tags, protein loads up to 10.2 μg g−1 and specific activities of up to 29.9 ± 0.3 U mg−1, were obtained. We found that ionically exchanged enzyme inside pores of NH2-SBA-15 drastically narrowed the substrate range (17 esters), to an extent much higher than ionically exchanged enzyme on the surface of magnetic micro-particles (up to 61 esters). This is attributed to differences in surface chemistry, particle size, and substrate accessibility to the active site tunnel. Our results also suggested, for the first time, that immobilization of enzymes in pores of similar size may alter the enzyme structures and produce enzyme active centers with different configuration which promote stereochemical conversions in a manner different to those arising from surface immobilization, where the strength of the ionic exchange also has an influence. This was shown by demonstrating that when the enzyme was introduced inside pores with a diameter (under dry conditions) slightly higher than that of the enzyme crystal structure a biocatalyst enantiospecific for ethyl (R)-4-chloro-3-hydroxybutyrate was produced, a feature not found when using wider pores. By contrast, immobilization on the surface of ferromagnetic microparticles produced selective biocatalysts for methyl (S)-(+)-mandelate or methyl (S)-lactate depending on the functionalization. This study illustrates the benefits of extensive analysis of the substrate spectra to better understand the effects of different immobilization strategies on enzyme flexibility/rigidity, as well as substrate specificity and stereochemistry. Our results will help to design tunable materials and interfaces for a controlled manipulation of specificity and to transform non-enantiospecific enzymes into stereo-chemically substrate promiscuous biocatalysts capable of converting multiple chiral molecules.This project received funding from the European Union’s Horizon 2020 research and innovation program Blue Growth: Unlockingthe potential of Seas and Oceans under grant agreement no. 634486 (project acronym INMARE). This research was also supported by the grants PCIN-2014-107 (within ERA NET IB2 grant nr. ERA-IB-14-030 - MetaCat), PCIN-2017-078 (within the ERA-MarineBiotech grant ProBone), BIO2014-54494-R, MAT2016-77496-R, BIO2017-85522-R, and CTQ2016-79138-R from the Spanish Ministry of Economy, Industry and Competitiveness. A.B. acknowledges the support from the Spanish Ministry of Economy, Industry and Competitiveness (MAT2017-88808-R grant), María de Maeztu Units of Excellence Programme (MDM-2016-0618), and the Diputación de Guipúzcoa for current funding in the frame of Gipuzkoa Fellows program. G.D. thanks the German Federal Ministry of Education and Research (BMBF, Grant No. 031A095C) for funding in the frame of the Molecular Interaction Engineering program (Biotechnologie 2020+). The authors gratefully acknowledge financial support provided by the European Regional Development Fund (ERDF). C.C. thanks the Spanish Ministry of Economy, Industry and Competitiveness for a PhD fellowship (Grant BES-2015-073829).Peer ReviewedPostprint (published version

Perceived influence of oral health upon quality of life in heart transplant patients

Objective: A study was made of heart transplant patient perception of the influence of oral health upon quality of life, based on the Oral Health Impact Profile (OHIP-49) questionnaire validated for Spanish speaking subjects. Design: A cross-sectional evaluation was made of the heart transplant patients followed-up on in the Heart Transplantation Unit of Reina Sofía University Hospital (Spain), using the OHIP-49 questionnaire. The included patients were all over age 18 and signed the corresponding informed consent to participation in the study. The data were entered in a database and analyzed using the SPSS statistical package. Results: A total of 150 heart transplant patients (118 males and 32 females, with a mean age of 54.94 years; range 19-79) were studied. The subjects showed a poor perceived influence of oral health upon quality of life, with a mean score of 24.43 out of a possible total of 196 points. Women showed significantly improved perception of the influence of oral health upon quality of life versus men. Conclusions: The subjects in our study showed a poor perceived influence of oral health upon quality of life