512 research outputs found
Using hierarchical information-theoretic criteria to optimize subsampling of extensive datasets
This paper addresses the challenge of subsampling large datasets, aiming to generate a smaller dataset that retains a significant portion of the original information. To achieve this objective, we present a subsampling algorithm that integrates hierarchical data partitioning with a specialized tool tailored to identify the most informative observations within a dataset for a specified underlying linear model, not necessarily first-order, relating responses and inputs. The hierarchical data partitioning procedure systematically and incrementally aggregates information from smaller-sized samples into new samples. Simultaneously, our selection tool employs Semidefinite Programming for numerical optimization to maximize the information content of the chosen observations. We validate the effectiveness of our algorithm through extensive testing, using both benchmark and real-world datasets. The real-world dataset is related to the physicochemical characterization of white variants of Portuguese Vinho Verde. Our results are highly promising, demonstrating the algorithm's capability to efficiently identify and select the most informative observations while keeping computational requirements at a manageable level
A model-based framework assisting the design of vapor-liquid equilibrium experimental plans
In this paper we propose a framework for Model-based Sequential Optimal Design of Experiments to assist experimenters involved in Vapor-Liquid equilibrium characterization studies to systematically construct thermodynamically consistent models. The approach uses an initial continuous optimal design obtained via semidefinite programming, and then iterates between two stages (i) model fitting using the information available; and (ii) identification of the next experiment, so that the information content in data is maximized. The procedure stops when the number of experiments reaches the maximum for the experimental program or the dissimilarity between the parameter estimates during two consecutive iterations is below a given threshold. This methodology is exemplified with the D-optimal design of isobaric experiments, for characterizing binary mixtures using the NRTL and UNIQUAC thermodynamic models for liquid phase. Significant reductions of the confidence regions for the parameters are achieved compared with experimental plans where the observations are uniformly distributed over the domain
Low-energy quasiparticle excitations in dirty d-wave superconductors and the Bogoliubov-de Gennes kicked rotator
We investigate the quasiparticle density of states in disordered d-wave
superconductors. By constructing a quantum map describing the quasiparticle
dynamics in such a medium, we explore deviations of the density of states from
its universal form (), and show that additional low-energy
quasiparticle states exist provided (i) the range of the impurity potential is
much larger than the Fermi wavelength [allowing to use recently developed
semiclassical methods]; (ii) classical trajectories exist along which the
pair-potential changes sign; and (iii) the diffractive scattering length is
longer than the superconducting coherence length. In the classically chaotic
regime, universal random matrix theory behavior is restored by quantum
dynamical diffraction which shifts the low energy states away from zero energy,
and the quasiparticle density of states exhibits a linear pseudogap below an
energy threshold .Comment: 4 pages, 3 figures, RevTe
Microwave conductivity of YBaCuO including inelastic scattering
The fluctuation spectrum responsible for the inelastic scattering in
YBaCuO which was recently determined from consideration of the
in-plane optical conductivity in the infrared, is used to calculate the
temperature dependence of the microwave conductivity at several measured
frequencies. Reasonable overall agreement can only be achieved if, in addition,
some impurity scattering is included within a model potential intermediate
between weak (Born) and strong (unitary) limit.Comment: 15 pages, 5 figures accepted for publication in Phys. Rev.
Semisolid processing characteristics of AM series Mg alloys by rheo-diecasting
The official published version of this Article can be found at the link below - Copyright @ 2006 ASM InternationalAn investigation has been made into the solidification behavior and microstructural evolution of AM50, AM70, and AM90 alloys during rheo-diecasting, their processibility, and the resulting mechanical properties. It was found that solidification of AM series alloys under intensive melt shearing in the unique twin-screw slurry maker during rheo-diecasting gave rise to numerous spheroidal primary magnesium (Mg) particles that were uniformly present in the microstructure. As a result, the network of the beta-Mg17Al12 phase was consistently interrupted by these spheroidal and ductile particles. Such a microstructure reduced the obstacle of deformation and the harmfulness of the beta-Mg17Al12 network on ductility, and therefore improved the ductility of rheo-diecast AM alloys. It was shown that, even with 9 wt pct Al, the elongation of rheo-diecast AM90 still achieved (9 +/- 1.2) pct. Rheodiecasting thus provides an attractive processing route for upgrading the alloy specification of AM series alloys by increasing the aluminum (Al) content while ensuring ductility. Assessment of the processibility of AM series alloys for semisolid processing showed that high Al content AM series alloys are more suitable for rheo-diecasting than low Al content alloys, because of the lower sensitivity of solid fraction to temperature, the lower liquidus temperature, and the smaller interval between the semisolid processing temperature and the complete solidification temperature.This work is supported by the EPSR
Optimal design of experiments for liquid–liquid equilibria characterization via semidefinite programming
Liquid–liquid equilibria (LLE) characterization is a task requiring considerable work and appreciable financial resources. Notable savings in time and effort can be achieved when the experimental plans use the methods of the optimal design of experiments that maximize the information obtained. To achieve this goal, a systematic optimization formulation based on Semidefinite Programming is proposed for finding optimal experimental designs for LLE studies carried out at constant pressure and temperature. The non-random two-liquid (NRTL) model is employed to represent species equilibria in both phases. This model, combined with mass balance relationships, provides a means of computing the sensitivities of the measurements to the parameters. To design the experiment, these sensitivities are calculated for a grid of candidate experiments in which initial mixture compositions are varied. The optimal design is found by maximizing criteria based on the Fisher Information Matrix (FIM). Three optimality criteria (D-, A- and E-optimal) are exemplified. The approach is demonstrated for two ternary systems where different sets of parameters are to be estimated
Chiral Dynamics and Fermion Mass Generation in Three Dimensional Gauge Theory
We examine the possibility of fermion mass generation in 2+1- dimensional
gauge theory from the current algebra point of view.In our approach the
critical behavior is governed by the fluctuations of pions which are the
Goldstone bosons for chiral symmetry breaking. Our analysis supports the
existence of an upper critical number of Fermion flavors and exhibits the
explicit form of the gap equation as well as the form of the critical exponent
for the inverse correlation lenght of the order parameterComment: Latex,10 pages,DFUPG 70/9
Huygens HASI servo accelerometer: a review and lessons learned
The Servo accelerometer constituted a vital part of the Huygens Atmospheric Structure Instrument (HASI): flown aboard the Huygens probe, it operated successfully during the probe's entry, descent, and landing on Titan, on 14th January 2005. This paper reviews the Servo accelerometer, starting from its development/assembly in the mid-1990s, to monitoring its technical performance through its seven-year long in-flight (or cruise) journey, and finally its performance in measuring acceleration (or deceleration) upon encountering Titan's atmosphere.
The aim of this article is to review the design, ground tests, in-flight tests and operational performance of the Huygens Servo accelerometer. Techniques used for data analysis and lessons learned that may be useful for accelerometry payloads on future planetary missions are also addressed.
The main finding of this review is that the conventional approach of having multiple channels to cover a very broad measurement range: from 10-6 g to the order of 10 g (where g = Earth's surface gravity, 9.8 m/s2), with on-board software deciding which of the channels to telemeter depending on the magnitude of the measured acceleration, works well. However, improvements in understanding the potential effects of the sensor drifts and ageing on the measurements can be achieved in future missions by monitoring the 'scale factor' – a measure of such sensors' sensitivity, along with the already implemented monitoring of the sensor's offset during the in-flight phase
Differential scanning calorimetry (DSC) and thermodynamic prediction of liquid fraction vs temperature for two high-performance alloys for semi-solid processing (Al-Si-Cu-Mg (319s) and Al-Cu-Ag (201))
There is a need to extend the application of semi-solid processing (SSP) to higher performance alloys such as 319s (Al-Si-Cu-Mg) and 201 (Al-Cu-Ag). The melting of these two alloys was investigated using differential scanning calorimetry (DSC) and thermodynamic prediction. The alloys had been processed by magneto-hydrodynamic (MHD) stirring before receipt to produce a microstructure suitable for SSP. The DSC results for the as-received MHD material were compared with those for material which has been taken through a complete DSC cycle and then reheated for a second DSC run. The effects of microsegregation were then analyzed. A higher liquid fraction for a particular temperature is found in the second DSC run than the first. Microstructural observations suggest this is because the intermetallics which form during the first cooling cycle tend to co-located. Quaternary and ternary reactions then occur during the second DSC heat and the co-location leads to enhanced peaks. The calculated liquid fraction is lower with 10 K/min DSC heating rate comparing with 3 K/min at a given temperature. The DSC scan rate must therefore be carefully considered if it is to be used to identify temperature parameters or the suitability of alloys for SSP. In addition, the starting material for DSC must represent the starting material for the SSP. With thermodynamic prediction, the equilibrium condition will provide better guidance for the thixoforming of MHD stirred starting material than the Scheil condition. The Scheil mode approximates more closely with a strongly microsegregated state
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