Interference of biodegradable plastics in the polypropylene recycling process

[EN] Recycling polymers is common due to the need to reduce the environmental impact of these materials. Polypropylene (PP) is one of the polymers called commodities polymers' and it is commonly used in a wide variety of short-term applications such as food packaging and agricultural products. That is why a large amount of PP residues that can be recycled are generated every year. However, the current increasing introduction of biodegradable polymers in the food packaging industry can negatively affect the properties of recycled PP if those kinds of plastics are disposed with traditional plastics. For this reason, the influence that generates small amounts of biodegradable polymers such as polylactic acid (PLA), polyhydroxybutyrate (PHB) and thermoplastic starch (TPS) in the recycled PP were analyzed in this work. Thus, recycled PP was blended with biodegradables polymers by melt extrusion followed by injection moulding process to simulate the industrial conditions. Then, the obtained materials were evaluated by studding the changes on the thermal and mechanical performance. The results revealed that the vicat softening temperature is negatively affected by the presence of biodegradable polymers in recycled PP. Meanwhile, the melt flow index was negatively affected for PLA and PHB added blends. The mechanical properties were affected when more than 5 wt.% of biodegradable polymers were present. Moreover, structural changes were detected when biodegradable polymers were added to the recycled PP by means of FTIR, because of the characteristic bands of the carbonyl group (between the band 1700-1800 cm(-1)) appeared due to the presence of PLA, PHB or TPS. Thus, low amounts (lower than 5 wt.%) of biodegradable polymers can be introduced in the recycled PP process without affecting the overall performance of the final material intended for several applications, such as food packaging, agricultural films for farming and crop protection.This research was funded by Conselleria d'Educacio, Investigacio, Cultura y Esport de la Generalitat Valenciana, grant number APOSTD/2018/209.Samper, M.; Bertomeu, D.; Arrieta, MP.; Ferri, JM.; López-Martínez, J. (2018). Interference of biodegradable plastics in the polypropylene recycling process. Materials. 11(10):1-18. https://doi.org/10.3390/ma11101886S1181110Plastics Europe, Plastics—The Facts 2017https://www.plasticseurope.org/application/files/5715/1717/4180/Plastics_the_facts_2017_FINAL_for_website_one_page.pdfAres, A., Bouza, R., Pardo, S. G., Abad, M. J., & Barral, L. (2010). Rheological, Mechanical and Thermal Behaviour of Wood Polymer Composites Based on Recycled Polypropylene. 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R., & Marconcini, J. M. (2016). Biodegradable Blends with Potential Use in Packaging: A Comparison of PLA/Chitosan and PLA/Cellulose Acetate Films. Journal of Polymers and the Environment, 24(4), 363-371. doi:10.1007/s10924-016-0785-4Avérous, L. (2004). Biodegradable Multiphase Systems Based on Plasticized Starch: A Review. Journal of Macromolecular Science, Part C: Polymer Reviews, 44(3), 231-274. doi:10.1081/mc-200029326Armentano, I., Fortunati, E., Burgos, N., Dominici, F., Luzi, F., Fiori, S., … Kenny, J. M. (2015). Processing and characterization of plasticized PLA/PHB blends for biodegradable multiphase systems. Express Polymer Letters, 9(7), 583-596. doi:10.3144/expresspolymlett.2015.55Arrieta, M. P., López, J., Rayón, E., & Jiménez, A. (2014). Disintegrability under composting conditions of plasticized PLA–PHB blends. Polymer Degradation and Stability, 108, 307-318. doi:10.1016/j.polymdegradstab.2014.01.034Garcia-Garcia, D., Ferri, J. 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Study of the Properties of a Biodegradable Polymer Filled with DierentWood Flour Particles

[EN] Lignocellulosic wood flour particles with three different sizes were used to reinforce Solanyl® type bioplastic in three compositions (10, 20, and 30 wt.%) and further processed by melt-extrusion and injection molding to simulate industrial conditions. The wood flour particles were morphologically and granulometric analyzed to evaluate their use as reinforcing filler. The Fuller method on wood flour particles was successfully applied and the obtained results were subsequently corroborated by the mechanical characterization. The rheological studies allowed observing how the viscosity was affected by the addition of wood flour and to recover information about the processing conditions of the biocomposites. Results suggest that all particles can be employed in extrusion processes (shear rate less than 1000 s¿1 ). However, under injection molding conditions, biocomposites with high percentages of wood flour or excessively large particles may cause an increase in defective injected-parts due to obstruction of the gate in the mold. From a processing point of view and based on the biocomposites performance, the best combination resulted in Solanyl® type biopolymer reinforced with wood flour particles loaded up to 20 wt.% of small and medium particles size. The obtained biocomposites are of interest for injected molding parts for several industrial applications.Parres, F.; Peydro, MA.; Juárez Varón, D.; Arrieta, MP.; Aldas, M. (2020). Study of the Properties of a Biodegradable Polymer Filled with DierentWood Flour Particles. Polymers. 12(12):1-24. https://doi.org/10.3390/polym12122974124121

Cursos nivelatorios: experiencia para para mitigar la deserción académica precoz

Evento organizado por la Universidad Peruana de Ciencias Aplicadas (UPC) el 16 de Julio de 2019, en el Campus Villa. Lima, Perú.Conferencia que aborda las estrategias para mitigar la deserción académica precoz

Influence of Silver Nitrate on Somatic Embryogenesis Induction in Arabica Coffee (Coffea arabica L.).

Plant somatic embryogenesis (SE) has been defined as the formation of embryos from a single or group of haploid or somatic cells [1, 2]. Low frequency (LFSE) and high frequency somatic embryogenesis (HFSE) have been described. In the first type, somatic embryos are induced directly from pro-embryogenic cells of explants, while in the second, they originate from embryogenic callus [1]. It has been suggested that in LFSE the origin of somatic embryos is unicellular, whereas in HFSE has been described as unicellular or multicellular [3]. SE is a powerful biotechnological tool used to propagate elite plants or to conserve important genotypes [4]. Moreover, SE offers an efficient in vitro regeneration approach as a fundamental step in plant genetic improvement for studying basic aspects of ontogenesis of somatic embryos [5]. In Coffea spp., the first studies of SE have been reported at the beginning of 1970 [6]. Since then, a large quantity of LFSE and HFSE protocols have been optimized demonstrating that coffee is not a recalcitrant species for SE [4]. In the LFSE the somatic embryos are obtained faster (approximately 70 days) using only one medium meanwhile in HFSE several media are used and somatic embryo formation takes 9-10 months [4]. Although, in LFSE small number of somatic embryos are obtained (around 10 per explant) compared to hundreds of somatic embryos obtained per gram of embryogenic calli [4], the unicellular origin of somatic embryos in LFSE represents an advantage for the chemical and physical mutagenesis, genetic transformation and genetic editing, since prevents or reduces the appearance of chimeras [7]. In C. arabica and C. canephora many factors (such as genotype, explant type, the physiological state, age and growth conditions of the donor plants, the season of collection, nutrient composition of the medium, the volume of dissolved CO2 or O2 in the culture flask, and plant growth regulators) that affect LFSE induction have been studied [3, 8, 9, 10, 11, 12, 13]. However, few studies reported the effect of silver nitrate on LFSE using leaf explants of C. arabica L. and to the best of our knowledge it has not been analyzed using Caturra and Catuaí, which are two economic important producer cultivars in Costa Rica. Since SE is genotype dependent, the culture medium need to be modified for the different genotypes [7].Therefore, the objective of this study was to determine the influence of the benzyladenine (BAP), indole-3-acetic acid (IAA), and silver nitrate (AgNO3) on low frequency somatic embryogenesis using leaf explants of Coffea arabica L. cultivars Caturra and Catuaí

Practical study of optical stellar interferometry

In this work we present an observational technique and a detailed analysis of the stellar interferograms produced by three bright stars: Betelgeuse, Rigel and Sirius. It is shown that the atmospheric turbulence is responsible for the reduction of the long-exposure fringe visibility of the obtained interference patterns. By using different baselines in our interferometer, we are able to distinguish the decay of the visibility with the baseline, how different parameters such us the diameter of the holes in our interferometer or their distribution affects the pattern, and to measure the turbulence with the estimation of the Fried parameter r0. The work and methodology are presented as a method for postgraduate students that targets practical learning of optical interferometry in astronomy and how it is affected by several causes, such as the atmospheric turbulence.Comment: 11 pages, 6 figures, paper submitted and accepted to AJ

Thermally-activated shape memory effect on biodegradable nanocomposites based on PLA/PCL blend reinforced with hydroxyapatite

[EN] In this work, the effect of the addition of different amount of nanosized hydroxyapatite (nHA) on the shape memory behavior of blends based on poly (lactic acid) (PLA) and poly (epsilon-caprolactone) (PCL) has been studied. In particular PLA/PCL blend with 70 wt % PLA has been reinforced with 0.5, 1 and 3 wt % nHA. Moreover, the relationship between the morphology and the final properties of the nanocomposites has been investigated by field emission scanning electron microscopy, confocal Raman spectroscopy and atomic force microscopy. In particular, PeakForce has been used to study quantitative nanomechanical properties of the multifunctional materials leading to conclusion that nHA increase the phase separation between PLA and PCL as well as act as reinforcements for the PCL-rich phase of the nanocomposites. Furthermore, excellent thermally-activated shape memory response has been obtained for all the nanocomposites at 55 degrees C. Finally, the disintegration under composting conditions at laboratory scale level was studied in order to confirm the biodegradable character of these nanocomposites. Indeed, these materials are able to be used for biomedical issues as well as for packaging applications where both thermally-activated shape memory effect and biodegradability are requested.Authors thank the Spanish Ministry of Economy, Industry and Competitiveness, MINEICO, (MAT2017-88123-P) and the Regional Government of Madrid (S2013/MIT-2862) for the economic support. M.P.A. and L.P. acknowledge the Juan de la Cierva (FJCI-2014-20630) and Ramon y Cajal (RYC-2014-15595) contracts from the MINEICO, respectively. The authors also thanks CSIC for the I-Link project (I-Link1149).Peponi, L.; Sessini, V.; Arrieta, MP.; Navarro-Baena, I.; Sonseca Olalla, Á.; Dominici, F.; Giménez Torres, E.... (2018). Thermally-activated shape memory effect on biodegradable nanocomposites based on PLA/PCL blend reinforced with hydroxyapatite. Polymer Degradation and Stability. 151:36-51. https://doi.org/10.1016/j.polymdegradstab.2018.02.019S365115

HCV clearance patterns in saliva and serum of patients with chronic HCV infection under interferon plus ribavirin therapy

This is the peer reviewed version of the article which has been published in final form at Wiley Online Library. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archiving[Abstract] Statements of the problem:  Hepatitis C virus (HCV)-RNA is often present in saliva of HCV-infected patients, with plasma viral load being the only known predictable factor. Interferon plus ribavirin therapy yields a sustained reduction in HCV viremia. This study aimed to assess the presence of HCV in saliva and serum specimens from patients undergoing this combination therapy (CT). Method of study:  Paired serum and saliva specimens were collected from 44 chronic HCV-infected patients at basal time, 4 and 12 weeks after CT onset, at the end of treatment and 6 months latter. Serum HCV-RNA levels were determined by the polymerase chain reaction (PCR) Amplicor system. Presence of HCV-RNA in saliva was tested by a highly sensitive non-commercialized nested-PCR. Results:  The HCV-RNA was detected in 26 saliva specimens at basal time (59.1%). In 34.1% of cases, a concordance viral clearance pattern in serum and saliva was observed in both responders (pattern 1a) and non-responders (pattern 1b). In pattern 2 (13.6% of cases), HCV was detected longer during CT in serum than in saliva (pattern 2a) or in saliva than in serum (pattern 2b). In 11.3% of patients, viral clearance was corroborated either in their serum (pattern 3a) or in their saliva (pattern 3b), but not in both fluids. Of the eight primary responders with 1a clearance pattern, seven were sustained responders. None of the patients with 2a clearance pattern was a sustained responder. Of the two primary responders showing the 3b salivary pattern, one had already relapsed in the first 6 months of follow up. Conclusions:  The present results suggest that the monitoring of salivary levels of HCV would be a helpful means of determining sustained antiviral effects of interferon and ribavirin in the treatment of HCV disease

The hydrogen and helium lines of the symbiotic binary Z And during its brightening at the end of 2002

High resolution observations in the region of the lines Halpha, He II 4686 and Hgamma of the spectrum of the symbiotic binary Z And were performed during its small-amplitude brightening at the end of 2002. The profiles of the hydrogen lines were double-peaked. These profiles give a reason to suppose that the lines can be emitted mainly by an optically thin accretion disc. The Halpha line is strongly contaminated by the emission of the envelope, therefore for consideration of accretion disc properties we use the Hgamma line. The Halpha line had broad wings which are supposed to be determined mostly from radiation damping but high velocity stellar wind from the compact object in the system can also contribute to their appearance. The Hgamma line had a broad emission component which is assumed to be emitted mainly from the inner part of the accretion disc. The line He II 4686 had a broad emission component too, but it is supposed to appear in a region of a high velocity stellar wind. The outer radius of the accretion disc can be calculated from the shift between the peaks. Assuming, that the orbit inclination can ranges from 47$^\circ$ to 76$^\circ$, we estimate the outer radius as 20 - 50 R_sun. The behaviour of the observed lines can be considered in the framework of the model proposed for interpretation of the line spectrum during the major 2000 - 2002 brightening of this binary.Comment: 19 pages, 5 figures. Accepted for publication in Astronomy Report

Holo-Omics:Integrated Host-Microbiota Multi-omics for Basic and Applied Biological Research

From ontogenesis to homeostasis, the phenotypes of complex organisms are shaped by the bidirectional interactions between the host organisms and their associated microbiota. Current technology can reveal many such interactions by combining multi-omic data from both hosts and microbes. However, exploring the full extent of these interactions requires careful consideration of study design for the efficient generation and optimal integration of data derived from (meta)genomics, (meta) transcriptomics, (meta)proteomics, and (meta)metabolomics. In this perspective, we introduce the holo-omic approach that incorporates multi-omic data from both host and microbiota domains to untangle the interplay between the two. We revisit the recent literature on biomolecular host-microbe interactions and discuss the im-plementation and current limitations of the holo-omic approach. We anticipate that the application of this approach can contribute to opening new research avenues and discoveries in biomedicine, biotechnology, agricultural and aquacultural sciences, nature conservation, as well as basic ecological and evolutionary research.The authors thank the following for funding their research: The Danish National Research Foundation award to M.T.P.G. (DNRF143), Villum Fonden grant to M.T. P.G. (17417), Lundbeckfonden grant to A.A. (R250-2017-1351), Danish Council for Independent Research grants to A.A. (DFF 5051-00033) and M.T.L. (DFF 8022-00005), ERC Consolidator Grant toM. T.P.G. (681396-Extinction Genomics), The Norwegian Seafood Research Fund -FHF grant to M.T.P.G. and M.T.L. (901436-HoloFish), H2020 Marie Sklodowska-Curie Individual Fellowship grant toM.T.L. (745723-HappyFish) and the European Union's Horizon 2020 Research and Innovation Programme grant to M.T.P.G., A.A. and M.T.L. (Grant Agreement No 817729 -HoloFood). Furthermore, the authors would like to thank Rob Dunn for his input and discussions

Oxygen reduction using a metal-free naphthalene diimide-based covalent organic framework electrocatalyst

A novel naphthalene diimide-based covalent organic framework (NDI-COF) has been synthesized and successfully exfoliated into COF nanosheets (CONs). Electrochemical measurements reveal that the naphthalene diimide units incorporated into NDI-CONs act as efficient electrocatalyst for oxygen reduction in alkaline media, showing its potential for the development of metal-free fuel cellsFinancial support from the Spanish Government (projects MAT2016-77608-C3-1-P, MAT2016-77608-C3-2-P, CTQ2017-84309-C2-1-R, MAT2017-85089-C2-1-R, FJCI-2017-33536 and RYC-2015-17730), the UCM (INV.GR.00.1819.10759) and the Madrid Regional Government (TRANSNANOAVANSENS-CM (S2018/NMT-4349)) is acknowledge