258 research outputs found
Local boron doping quantification in homoepitaxial diamond structures
The capability of transmission electronmicroscopy (TEM) using the high angle annular dark fieldmode (HAADF,also labelled Z-contrast) to quantify boron concentration, in the high doping range between 1019cm−3 and 1021cm−3, is demonstrated. Thanks to the large relative variation of atomic number Z between carbon and boron, doping concentration maps and profiles are obtained with a nanometer-scale resolution. A novel numerical simulation procedure allows the boron concentration quantification and demonstrates the high sensitivity and
spatial resolution of the technique.4 page
Influence of the substrate type on CVD grown homoepitaxial diamond layer quality by cross sectional TEM and CL analysis
To assess diamond-based semiconducting devices, a reduction of point defect levels and an accurate control of doping are required as well as the control of layer thickness. Among the analyses required to improve such parameters, cross sectional studies should take importance in the near future. The present contribution shows
how FIB (focused ion beam) preparations followed by electron microscopy related techniques as TEM or CL allowed to performanalysis versus depth in the layer, doping and point defect levels. Three samples grown along the sameweek in the same machinewith identical growth conditions but on different substrates (CVD-IIIa (110)
oriented, CVD-optical grade (100) oriented and a HPHT-Ib (100) oriented) are studied. Even though A-band is observed by CL, no dislocation is observed by CTEM. Point defect type and level are shown to substantially change with respect to the substrate type as well as the boron doping levels that vary within an order of magnitude. H3 present in the epilayer grown on HPHT type of substrate is replaced by T1 and NE3 point defects for epilayers grown on the CVD type one. An increase of excitonic transitions through LO phonons is also shown to take place near the surface while only TO ones are detected deeper in the epilayer. Such results highlight the importance of choosing the correct substrate.5 page
A simple ESR identification methodology for electrolytic capacitors condition monitoring
Electrolytic capacitors are usually used in power electronic systems for smoothing, energy storage or
filtering. They have the best overall performance for these objectives being a critical element in the
design of these systems, in several applications, with different requirements. But, unfortunately, in most
cases, they are the most life-limiting device. The expected life of electrolytic capacitors depends on their
internal temperature and is determined by the ratio of the electrolyte solution evaporation used in their
fabrication. The deterioration caused by this evaporation is reflected in electrical parameters, mainly the
equivalent series resistance (ESR). As the volume of the electrolyte decreases, ESR increases and
capacitance decreases. Additionally, the increase in ESR has a positive feedback effect since it leads the
temperature to increase and this in turn leads to further evaporation of the electrolyte leading to the ESR
increase and so forth.
This paper presents a simple ESR identification methodology for electrolytic capacitors condition
monitoring in view of preventive maintenance to signal the need of maintenance and or replacement. The
identification methodology is based on a simple continuous-time model and some recursive prediction
error methods, namely, Kalman filter, gradient and forgetting factor approaches. Simulation and
experimental data acquired from a step down converter were used with these algorithms. The identification methodology is also suitable for different power converter topologies
Traveling length and minimal traveling time for flow through percolation networks with long-range spatial correlations
We study the distributions of traveling length l and minimal traveling time t
through two-dimensional percolation porous media characterized by long-range
spatial correlations. We model the dynamics of fluid displacement by the
convective movement of tracer particles driven by a pressure difference between
two fixed sites (''wells'') separated by Euclidean distance r. For strongly
correlated pore networks at criticality, we find that the probability
distribution functions P(l) and P(t) follow the same scaling Ansatz originally
proposed for the uncorrelated case, but with quite different scaling exponents.
We relate these changes in dynamical behavior to the main morphological
difference between correlated and uncorrelated clusters, namely, the
compactness of their backbones. Our simulations reveal that the dynamical
scaling exponents for correlated geometries take values intermediate between
the uncorrelated and homogeneous limiting cases
Distribution of black flies (Diptera: Simuliidae) in the State of Espírito Santo, Brazil
Entre os anos de 2004 e 2008 foram realizadas coletas de Simuliidae em várias localidades no Estado do Espírito Santo, Brasil. No total, 66 córregos e rios das doze principais bacias hidrográficas do estado foram amostrados. Dezessete espécies foram coletadas, sendo que nove delas representam ocorrências novas para o estado (Simulium pertinax, S. jujuyense, S. rubrithorax, S. subnigrum, S. travassosi, S. spinibranchium, S. hirtipupa, S. lutzianum e S. anamariae), duplicando o número de espécies conhecidas no estado.We conducted a freshwater survey from 2004 to 2008 in several localities of Espírito Santo, Brazil. In total, 66 streams and rivers were sampled in the 12 hydrographic basins of the state. We collected and identified 17 species of which nine represent new records (Simulium pertinax, S. jujuyense, S. rubrithorax, S. subnigrum, S. travassosi, S. spinibranchium, S. hirtipupa, S. lutzianum e S. anamariae). These findings doubled the number of records of black fly species to the State of Espírito Santo, Brazil
Automatic structures for semigroup constructions
We survey results concerning automatic structures for semigroup
constructions, providing references and describing the corresponding automatic
structures. The constructions we consider are: free products, direct products,
Rees matrix semigroups, Bruck-Reilly extensions and wreath products.Comment: 22 page
Superconductivity in the SU(N) Anderson Lattice at U=\infty
We present a mean-field study of superconductivity in a generalized N-channel
cubic Anderson lattice at U=\infty taking into account the effect of a
nearest-neighbor attraction J. The condition U=\infty is implemented within the
slave-boson formalism considering the slave bosons to be condensed. We consider
the -level occupancy ranging from the mixed valence regime to the Kondo
limit and study the dependence of the critical temperature on the various model
parameters for each of three possible Cooper pairing symmetries (extended s,
d-wave and p-wave pairing) and find interesting crossovers. It is found that
the d- and p- wave order parameters have, in general, very similar critical
temperatures. The extended s-wave pairing seems to be relatively more stable
for electronic densities per channel close to one and for large values of the
superconducting interaction J.Comment: Seven Figures; one appendix. Accepted for publication in Phys. Rev.
Growth inhibitory effects of 3′-nitro-3-phenylamino nor-beta-lapachone against HL-60: A redox-dependent mechanism
AbstractIn this study, the cytotoxicity, genotoxicity and early ROS generation of 2,2-dimethyl-(3H)-3-(N-3′-nitrophenylamino)naphtho[1,2-b]furan-4,5-dione (QPhNO2) were investigated and compared with those of its precursor, nor-beta-lapachone (nor-beta), with the main goal of proposing a mechanism of antitumor action. The results were correlated with those obtained from electrochemical experiments held in protic (acetate buffer pH 4.5) and aprotic (DMF/TBABF4) media in the presence and absence of oxygen and with those from dsDNA biosensors and ssDNA in solution, which provided evidence of a positive interaction with DNA in the case of QPhNO2. QPhNO2 caused DNA fragmentation and mitochondrial depolarization and induced apoptosis/necrosis in HL-60 cells. Pre-treatment with N-acetyl-l-cysteine partially abolished the observed effects related to the QPhNO2 treatment, including those involving apoptosis induction, indicating a partially redox-dependent mechanism. These findings point to the potential use of the combination of pharmacology and electrochemistry in medicinal chemistry
Estudo da divergência genética entre quatro linhagens de matrizes de frangos de corte utilizando técnicas de análise multivariada
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