Using QUAL2Kw as a Decision Support Tool: Considerations for Data Collection, Calibration, and Numeric Nutrient Criteria

The in-stream water quality model, QUAL2Kw, can provide guidance in watershed management decisions by linking changes in nutrient loads to responses in water quality. This model is particularly useful for determining wasteload allocations, aiding in total maximum daily load analyses, and developing numeric nutrient criteria. Unfortunately, states struggle to balance the data collection and modeling requirements to accomplish many of these water quality management tasks due to limited resources. This commonly results in routine data collection and monitoring efforts that do not satisfy the data requirements for modeling. To address this disconnect, this study presents a data collection and parameter calibration methodology suited to meet general QUAL2Kw modeling requirements. Then, with the goal of identifying a range of numeric nitrogen and phosphorus criteria, this general data collection and modeling strategy was applied to sites throughout Utah. To help automate and test scenarios targeted at tracking effects of loading and response combinations, a nutrient criteria tool was also developed to interface with these QUAL2Kw models. By implementing the tool on these models, input concentrations of ammonium (NH4+) ranging from 10 to 101 µg/L and inorganic phosphorus (PO4-) ranging from 1 to 14 µg/L were found to exceed thresholds of bottom algae, gross primary productivity, and ecosystem respiration. Conversely, NH4+ concentrations above 3,500 µg/L and PO4- above 490 µg/L exceeded dissolved oxygen thresholds of 5-6 mg/L in some applications. Some limitations of using mechanistic models in this manner were identified, including model capabilities (e.g., steady-state versus dynamic), inclusion of appropriate processes, uncertainty in calibrated parameters, and site-specific conditions. Although many problems will require more complex modeling efforts with significantly larger data collection efforts, this approach provides an initial framework that aids in the judicial use of resources to aid in watershed management decisions

Mentoring substructures and superstructures: an extension and reconceptualisation of the architecture for teacher mentoring

This paper presents the outcomes of an empirical investigation into the validity of Bryan Cunningham's thesis that the effectiveness of teacher mentoring is enhanced by a supportive institutional framework comprising eight ‘architectural design features’. It draws upon analyses of data from a mixed methods study of mentoring in the English Further Education sector. Data were generated via 40 semi-structured interviews with teachers, mentors and other stakeholders, and a national online survey of teachers of all subjects/vocational areas, completed by 392 respondents across all nine regions of England. The paper presents a reconceptualisation of the architecture for mentoring, which encompasses both a mentoring substructure and superstructure. Cunningham’s institutional architecture (reconceptualised as a mentoring substructure) is extended through the identification of additional design features, while limitations of the concept of an institutional mentoring architecture are exposed and evidence presented to show that a complementary superstructure is a necessary additional means of seeking to achieve optimally effective mentoring. A new research agenda is proposed to explore the extent to which the proposed mentoring substructure and superstructure are applicable in different professional and international contexts, and to identify common features of optimally supportive mentoring superstructures

Mechanism of Vanadium Leaching during Surface Weathering of Basic Oxygen Furnace Steel Slag Blocks: A Microfocus X-ray Absorption Spectroscopy and Electron Microscopy Study

© 2017 American Chemical Society. Basic oxygen furnace (BOF) steelmaking slag is enriched in potentially toxic V which may become mobilized in high pH leachate during weathering. BOF slag was weathered under aerated and air-excluded conditions for 6 months prior to SEM/EDS and μXANES analysis to determine V host phases and speciation in both primary and secondary phases. Leached blocks show development of an altered region in which free lime and dicalcium silicate phases were absent and Ca-Si-H was precipitated (CaCO 3 was also present under aerated conditions). μXANES analyses show that V was released to solution as V(V) during dicalcium silicate dissolution and some V was incorporated into neo-formed Ca-Si-H. Higher V concentrations were observed in leachate under aerated conditions than in the air-excluded leaching experiment. Aqueous V concentrations were controlled by Ca 3 (VO 4 ) 2 solubility, which demonstrate an inverse relationship between Ca and V concentrations. Under air-excluded conditions Ca concentrations were controlled by dicalcium silicate dissolution and Ca-Si-H precipitation, leading to relatively high Ca and correspondingly low V concentrations. Formation of CaCO 3 under aerated conditions provided a sink for aqueous Ca, allowing higher V concentrations limited by kinetic dissolution rates of dicalcium silicate. Thus, V release may be slowed by the precipitation of secondary phases in the altered region, improving the prospects for slag reuse

Options for modulating intra-specific competition in colonial pinnipeds: the case of harbour seals (Phoca vitulina) in the Wadden Sea

Colonial pinnipeds may be subject to substantial consumptive competition because they are large, slow-moving central place foragers. We examined possible mechanisms for reducing this competition by examining the diving behaviour of harbour seals (Phoca vitulina) after equipping 34 seals (11 females, 23 males) foraging from three locations; Romo, Denmark and Lorenzenplate and Helgoland, Germany, in the Wadden Sea area with time-depth recorders. Analysis of 319,021 dives revealed little between-colony variation but appreciable inter-sex differences, with males diving deeper than females, but for shorter periods. Males also had higher vertical descent rates. This result suggests that males may have higher overall swim speeds, which would increase higher oxygen consumption, and may explain the shorter dive durations compared to females. Intersex variation in swim speed alone is predicted to lead to fundamental differences in the time use of three-dimensional space, which may help reduce consumptive competition in harbour seals and other colonial pinnipeds

Low serum albumin levels prior to pediatric allogeneic HCT are associated with increased need for critical care interventions and increased 6-month mortality

Poor nutritional status in HCT patients is a negative prognostic factor. There are no pediatric studies evaluating albumin levels prior to HCT and need for critical care interventions. We hypothesized that pediatric patients with low albumin levels, routinely measured 30 days (±10 days) prior to allogeneic HCT, have a higher risk of critical care interventions in the post-transplant period. We performed a 5-year retrospective study of pediatric patients who underwent allogeneic HCT for any indication. Patients were categorized based on albumin level. Hypoalbuminemia was defined as <3.1 g/dL. A total of 73 patients were included, with a median age of 7.4 years (IQR 3.3, 13.2). Patients with hypoalbuminemia had higher needs for critical care interventions including non-invasive ventilation (44% vs 8%, P=.01), mechanical ventilation (67% vs 17%, P<.01), and vasoactive therapy (56% vs 16%, P=.01). Patients with hypoalbuminemia also had a higher 6-month mortality (56% vs 17%, P=.02). Our data demonstrate that children undergoing allogeneic HCT with hypoalbuminemia in the pretransplant period are more likely to require critical care interventions and have higher 6-month mortality. These findings identify an at-risk population in which nutritional improvements may be instituted prior to HCT in hopes of improving outcomes