80 research outputs found
Symmetry consideration and eg bands in NdNiO3 and YNiO3
Group theoretical analyses are applied to the magnetic and electronic
structures of NdNiO3 and YNiO3, whose electronic structures have been studied
very recently by the LSDA+U method. The Jahn-Teller distortion cannot satisfy
the experimentally observed magnetic diffraction. The resultant ground state
magnetic stuructures are monoclinic P_ba in NdNiO3 case and P_b2_1/a in YNiO3
case, respectively.Comment: 6 pages, 3 figures, Proc. Int. Symp. ISSP-Kashiwa 200
Generalized Zeta Functions and One-loop Corrections to Quantum Kink Masses
A method for describing the quantum kink states in the semi-classical limit
of several (1+1)-dimensional field theoretical models is developed. We use the
generalized zeta function regularization method to compute the one-loop quantum
correction to the masses of the kink in the sine-Gordon and cubic sinh-Gordon
models and another two systems with polynomial
self-interactions.Comment: 29 pages, 4 figures; version to appear in Nucl. Phys.
Semi-classical mass of quantum k-component topological kinks
We use the generalized zeta function regularization method to compute the
one-loop quantum correction to the masses of the TK1 and TK2 kinks in a
deformation of the O(N) linear sigma model on the real line.Comment: 25 pages, 1 figure, Appendix added; version to appear in Nucl. Phys.
Controlled Magnetic Anisotropy in Single Domain Mn-doped Biosynthesized Nanoparticles
Magnetotactic bacteria Magnetospirillum gryphiswaldense synthesize cubo-octahedral shaped magnetite nanoparticles, called magnetosomes, with a mean diameter of 40 nm. The high quality of the biosynthesized nanoparticles makes them suitable for numerous applications in fields like cancer therapy, among others.
The magnetic properties of magnetite magnetosomes can be tailored by doping them with transition metal elements, increasing their potential applications. In this work, we address the effect of Mn doping on the main properties of magnetosomes by the combination of structural and magnetic characterization techniques.
Energy-dispersive X-ray spectroscopy, X-ray absorption nearedge structure, and X-ray magnetic circular dichroism results reveal a Mn dopant percentage of utmost 2.3%, where Mn cations are incorporated as a combination of Mn2+ and Mn3+, preferably occupying tetrahedral and octahedral sites, respectively. Fe substitution by Mn notably alters the magnetic behavior of the doped magnetosomes. Theoretical modeling of the experimental hysteresis loops taken between 5 and 300 K with a modified Stoner-Wohlfarth approach highlights the different anisotropy contributions of the doped magnetosomes as a function of temperature. In
comparison with the undoped magnetosomes, Mn incorporation alters the magnetocrystalline anisotropy introducing a negative and larger cubic anisotropy down to the Verwey transition, which appears shifted to lower temperature values as a consequence of Mn doping. On the other hand, Mn-doped magnetosomes show a decrease in the uniaxial anisotropy in the whole temperature range, most likely associated with a morphological modification of the Mn-doped magnetosomes.The Spanish and Basque Governments are acknowledged for funding under project numbers MAT2017-
83631-C3-R and IT-1245-19, respectively
The African swine fever virus dynein-binding protein p54 induces infected cell apoptosis
AbstractA specific interaction of ASFV p54 protein with 8 kDa light chain cytoplasmic dynein (DLC8) has been previously characterized and this interaction is critical during virus internalization and transport to factory sites. During early phases of infection, the virus induces the initiation of apoptosis triggering activation of caspase-9 and -3. To analyze the role of the structural protein p54 in apoptosis, transient expression experiments of p54 in Vero cells were carried out which resulted in effector caspase-3 activation and apoptosis. Interestingly, p54 mutants, lacking the 13 aa dynein-binding motif lose caspase activation ability and pro-death function of p54. This is the first reported ASFV protein which induces apoptosis
Iron valence in double-perovskite (Ba,Sr,Ca)2FeMoO6: Isovalent substitution effect
In the Fe-Mo based B-site ordered double-perovskite, A2FeMoO6.0, with iron in
the mixed-valence II/III state, the valence value of Fe is not precisely fixed
at 2.5 but may be fine-tuned by means of applying chemical pressure at the
A-cation site. This is shown through a systematic 57Fe Mossbauer spectroscopy
study using a series of A2FeMoO6.0 [A = (Ba,Sr) or (Sr,Ca)] samples with high
degree of Fe/Mo order, the same stoichiometric oxygen content and also almost
the same grain size. The isomer shift values and other hyperfine parameters
obtained from the Mossbauer spectra confirm that Fe remains in the
mixed-valence state within the whole range of A constituents. However, upon
increasing the average cation size at the A site the precise valence of Fe is
found to decrease such that within the A = (Ba,Sr) regime the valence of Fe is
closer to II, while within the A = (Sr,Ca) regime it is closer to the actual
mixed-valence II/III state. As the valence of Fe approaches II, the difference
in charges between Fe and Mo increases, and parallel with this the degree of
Fe/Mo order increases. Additionally, for the less-ordered samples an increased
tendency of clustering of the anti-site Fe atoms is deduced from the Mossbauer
data.Comment: 19 pages, 6 figures, submitted to Phys. Rev.
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