Tectonic events, continental intraplate volcanism, and mantle plume activity in northern Arabia: constraints form geochemistry and Ar-Ar dating of Syrian lavas

New (40)Ar/(39)Ar ages combined with chemical and Sr, Nd, and Pb isotope data for volcanic rocks from Syria along with published data of Syrian and Arabian lavas constrain the spatiotemporal evolution of volcanism, melting regime, and magmatic sources contributing to the volcanic activity in northern Arabia. Several volcanic phases occurred in different parts of Syria in the last 20 Ma that partly correlate with different tectonic events like displacements along the Dead Sea Fault system or slab break-off beneath the Bitlis suture zone, although the large volume of magmas and their composition suggest that hot mantle material caused volcanism. Low Ce/Pb (<20), Nb/Th (<10), and Sr, Nd, and Pb isotope variations of Syrian lavas indicate the role of crustal contamination in magma genesis, and contamination of magmas with up to 30% of continental crustal material can explain their (87)Sr/(86)Sr. Fractionation-corrected major element compositions and REE ratios of uncontaminated lavas suggest a pressure-controlled melting regime in western Arabia that varies from shallow and high-degree melt formation in the south to increasingly deeper regions and lower extents of the beginning melting process northward. Temperature estimates of calculated primary, crustally uncontaminated Arabian lavas indicate their formation at elevated mantle temperatures (T(excess) similar to 100-200 degrees C) being characteristic for their generation in a plume mantle region. The Sr, Nd, and Pb isotope systematic of crustally uncontaminated Syrian lavas reveal a sublithospheric and a mantle plume source involvement in their formation, whereas a (hydrous) lithospheric origin of lavas can be excluded on the basis of negative correlations between Ba/La and K/La. The characteristically high (206)Pb/(204)Pb (similar to 19.5) of the mantle plume source can be explained by material entrainment associated with the Afar mantle plume. The Syrian volcanic rocks are generally younger than lavas from the southern Afro-Arabian region, indicating a northward progression of the commencing volcanism since the arrival of the Afar mantle plume beneath Ethiopia/Djibouti some 30 Ma ago. The distribution of crustally uncontaminated high (206)Pb/(204)Pb lavas in Arabia indicates a spatial influence of the Afar plume of similar to 2600 km in northward direction with an estimated flow velocity of plume material on the order of 22 cm/a

CIPWFULL: A FORTRAN Program for Calculation of Comprehensive CIPW Norms of Igneous Rocks

CIPWFULL is a user-friendly, stand-alone FORTRAN software program that is designed to calculate the comprehensive CIPW normative mineral composition of igneous rocks and strictly adheres to the original formulation of the CIPW protocol. This faithful adherence alleviates inaccuracies in normative mineral calculations by programs commonly used by petrologists. Additionally, several of the most important petrological and mineralogical parameters of igneous rocks are calculated by the program. Along with all the regular major oxide elements, all the significant minor elements whose contents can potentially effect the CIPW normative mineral composition are included. CIPWFULL also calculates oxidation ratios for igneous rock samples that have only one oxidation state of iron reported in the specimen analysis. It also provides an option for normalization of analyses to unity on a hydrous-free basis in order to facilitate comparison of norms among rock groups. Other capabilities of the program cater for rare situations, like the presence of cancrinite or exclusion from the norm calculation of rare rocks like carbonatite. Several mineralogical, petrological and discriminatory parameters and indexes are additionally calculated by the CIPWFULL program. The CIPWFULL program is very efficient and flexible and allows for a user-defined free-format input of all the chemical species, and it permits feeding of minor elements as parts per million or oxide percentages. Results of calculations are printed in a formatted ASCII text file and may be optionally casted into a space-delimited text files that are ready to be imported to general spreadsheet programs. CIPWFULL is DOS-based and is implemented on WINDOWS and mainframe platforms