Metallic properties of magnesium point contacts

We present an experimental and theoretical study of the conductance and stability of Mg atomic-sized contacts. Using Mechanically Controllable Break Junctions (MCBJ), we have observed that the room temperature conductance histograms exhibit a series of peaks, which suggests the existence of a shell effect. Its periodicity, however, cannot be simply explained in terms of either an atomic or electronic shell effect. We have also found that at room temperature, contacts of the diameter of a single atom are absent. A possible interpretation could be the occurrence of a metal-to-insulator transition as the contact radius is reduced, in analogy with what it is known in the context of Mg clusters. However, our first principle calculations show that while an infinite linear chain can be insulating, Mg wires with larger atomic coordinations, as in realistic atomic contacts, are alwaysmetallic. Finally, at liquid helium temperature our measurements show that the conductance histogram is dominated by a pronounced peak at the quantum of conductance. This is in good agreement with our calculations based on a tight-binding model that indicate that the conductance of a Mg one-atom contact is dominated by a single fully open conduction channel.Comment: 14 pages, 5 figure

Electronic and atomic shell structure in aluminum nanowires

We report experiments on aluminum nanowires in ultra-high vacuum at room temperature that reveal a periodic spectrum of exceptionally stable structures. Two "magic" series of stable structures are observed: At low conductance, the formation of stable nanowires is governed by electronic shell effects whereas for larger contacts atomic packing dominates. The crossover between the two regimes is found to be smooth. A detailed comparison of the experimental results to a theoretical stability analysis indicates that while the main features of the observed electron-shell structure are similar to those of alkali and noble metals, a sequence of extremely stable wires plays a unique role in Aluminum. This series appears isolated in conductance histograms and can be attributed to "superdeformed" non-axisymmetric nanowires.Comment: 15 pages, 9 figure

The mass-metallicity gradient relation of early-type galaxies

We present a newly observed relation between galaxy mass and radial metallicity gradients of early-type galaxies. Our sample of 51 early-type galaxies encompasses a comprehensive mass range from dwarf to brightest cluster galaxies. The metallicity gradients are measured out to one effective radius by comparing nearly all of the Lick absorption-line indices to recent models of single stellar populations. The relation shows very different behaviour at low and high masses, with a sharp transition being seen at a mass of ~ 3.5 x 10^10 M_sun (velocity dispersion of ~140 km/s, M_B ~ -19). Low-mass galaxies form a tight relation with mass, such that metallicity gradients become shallower with decreasing mass and positive at the very low-mass end. Above the mass transition point several massive galaxies have steeper gradients, but a clear downturn is visible marked by a broad scatter. The results are interpreted in comparison with competing model predictions. We find that an early star-forming collapse could have acted as the main mechanism for the formation of low-mass galaxies, with star formation efficiency increasing with galactic mass. The high-mass downturn could be a consequence of merging and the observed larger scatter a natural result of different merger properties. These results suggest that galaxies above the mass threshold of ~ 3.5 x 10^10 M_sun might have formed initially by mergers of gas-rich disc galaxies and then subsequently evolved via dry merger events. The varying efficiency of the dissipative merger-induced starburst and feedback processes have shaped the radial metallicity gradients in these high-mass systems.Comment: 5 pageg, 3 figures, accepted by ApJ Lette

Optimización de uniones y estructuras de autobuses

El objetivo principal del proyecto de investigación presentado es el de obtener una mejorar en el comportamiento y la predictibilidad de las tensiones de los modelos FEM de vehículos de grandes dimensiones para el transporte de pasajeros (autobuses y autocares). Dadas las dimensiones de estos vehículos y el tipo de estructura de los mismos (tubular de sección rectangular hueca) los modelos más adecuados desde el punto de vista técnico, económico y de coste de modelización computacional son los generados con elementos de tipo viga. Dichos elementos debido a la simplicidad de su formulación presentan una serie de limitaciones en la caracterización del comportamiento de las uniones (infinitamente rígidas), debido a esto los modelos de autobuses realizados con este tipo de elementos presentan mayores rigideces estructurales. Teniendo en cuenta lo anteriormente mencionado las estimaciones de vida a fatiga o la estimación de las tensiones se ven afectadas. Para resolveré este problema se han realizando una serie de investigaciones mediante modelización y experimentación para diferentes modelos de uniones que se encuentran de manera frecuenta en las estructuras de autobuses urbanos. Por otra parte fue ideada una metodología y se realizo un programa mediante el cual se pueden realizar de manera rápida simulaciones para una serie entera de configuraciones de los parámetros del modelo con elementos finitos: tipos de elementos utilizados, tipo de mallado, dimensión del mallado características de las constantes reales. Conjuntamente fueron realizadas una serie de análisis modales para diferentes uniones en las cuales se intento aislar y evidenciar las diferencias de comportamiento vibracional influenciado exclusivamente por la configuración de la unión. Los resultados obtenidos serán utilizados para poder realizar un modelo con elementos finitos que reproduzca de manera más real el comportamiento de las uniones rígidas que se utilizan en los autobuses y autocares (uniones soldadas

Influence of bacterial dynamics upon the final characteristics

The microbiological profile in raw milk cheeses is typically characterized by a multitude of microbial groups, with interactions among them throughout ripening that are not fully understood to date. Incidence of undesired microorganisms in raw cheesemaking milk, as is the case of either spoilage or even pathogenic ones, is a common trait in Portuguese traditional cheeses. Hence, they will likely contribute to the physicochemical changes occurring therein and, consequently, to the characteristics of the final product. In order to gain insight into their role, model cheese systems, manufactured as far as possible according to artisanal practices (except that the initial microbial load and biodiversity were controlled), were experimentally tested. Single contaminants, or a consortium thereof, were inoculated at two levels in sterilized raw ewe's milk, and duly combined with inocula containing one or two lactic acid bacteria normally found in those traditional cheeses. The physicochemical composition, organic acid profile, and evolution of both protein breakdown and rheology were monitored throughout a 60 d-ripening period. Modifications brought about within the cheese matrix as a result of microbial metabolism, especially those arising from the interaction between lactic acid bacteria and unwanted microorganisms, included the enhanced release of peptides and free amino acids, which in turn led to higher viscoelastic moduli. The final model cheeses could be well discriminated, based on the impact of the various inocula considered upon the levels of organic acids. Conversely, proteolysis and viscoelastic properties appeared to be essentially independent of the initial microflora.info:eu-repo/semantics/publishedVersio

R125H, W240S, C386R, and V507I SLC4A11 mutations associated with corneal endothelial dystrophy affect the transporter function but not trafficking in PS120 cells

SLC4A11 mutations are associated with Fuchs’ endothelial corneal dystrophy (FECD), congenital hereditary endothelial dystrophy (CHED) and Harboyan syndrome (endothelial dystrophy with auditory deficiency). Mice with genetically ablated Slc4a11 recapitulate CHED, exhibiting significant corneal edema and altered endothelial morphology. We recently demonstrated that SLC4A11 functions as an NH3 sensitive, electrogenic H+ transporter. Here, we investigated the properties of five clinically relevant SLC4A11 mutants: R125H, W240S, C386R, V507I and N693A, relative to wild type, expressed in a PS120 fibroblast cell line. The effect of these mutations on the NH4Cl-dependent transporter activity was investigated by intracellular pH and electrophysiology measurements. Relative to plasma membrane expression of NaK ATPase, there were no significant differences in plasma membrane SLC4A11 expression among each mutant and wild type. All mutants revealed a marked decrease in acidification in response to NH4Cl when compared to wild type, indicating a decreased H+ permeability in mutants. All mutants exhibited significantly reduced H+ currents at negative holding potentials as compared to wild type. Uniquely, the C386R and W240S mutants exhibited a different inward current profile upon NH4Cl challenges, suggesting an altered transport mode. Thus, our data suggest that these SLC4A11 mutants, rather than having impaired protein trafficking, show altered H+ flux properties

Quantum size effects in Pb islands on Cu(111): Electronic-structure calculations

The appearance of "magic" heights of Pb islands grown on Cu(111) is studied by self-consistent electronic structure calculations. The Cu(111) substrate is modeled with a one-dimensional pseudopotential reproducing the essential features, i.e. the band gap and the work function, of the Cu band structure in the [111] direction. Pb islands are presented as stabilized jellium overlayers. The experimental eigenenergies of the quantum well states confined in the Pb overlayer are well reproduced. The total energy oscillates as a continuous function of the overlayer thickness reflecting the electronic shell structure. The energies for completed Pb monolayers show a modulated oscillatory pattern reminiscent of the super-shell structure of clusters and nanowires. The energy minima correlate remarkably well with the measured most probable heights of Pb islands. The proper modeling of the substrate is crucial to set the quantitative agreement.Comment: 4 pages, 4 figures. Submitte