A Simple, Automatic Means of Designing a Conversion Table for Expressing Laboratory Results in the International System of Units (SI)

Peer Reviewe

Diurnal to interannual variability of low‐level cloud cover over western equatorial Africa in May–October

This study examines the diurnal to interannual variations of the stratiform cloud cover in May–October (1971–2019) from a 3-hourly station database and from ERA5 reanalyses over western equatorial Africa (WEA). The main diurnal variations of the local-scale fraction and genus of stratiform clouds are synthesized into three canonical diurnal types (i.e., “clear,” “clear afternoon,” “cloudy” days). The interannual variations of frequencies of the three diurnal types during the cloudiest months (JJAS) are mostly associated with two main mechanisms: a meridional shallow overturning cell associating more “cloudy” and less “clear” and “clear afternoon” days to anomalous southerlies below 900 hPa over and around WEA, anomalous ascent around 5°–7°N, anomalous northerlies between 875 and 700 hPa, and anomalous subsidence over the equatorial Atlantic. This circulation is strongly related to interannual variations of the equatorial Atlantic upwelling (i.e., more clouds when the upwelling is strong) associated with a meridional shift of the Intertropical Convergence Zone over the Tropical Atlantic and adjacent continents. The second mechanism operates mostly in the zonal direction and involves again the coupled ocean–atmosphere system over the equatorial Atlantic, but also the remote El Niño–Southern Oscillation (ENSO). An anomalously cold equatorial Atlantic drives increased low-level westerlies toward the Congo Basin. Warm ENSO events promote broad warm and easterly anomalies in the middle and upper troposphere, which increase the local static stability, and thus the local stratiform cloud cover over WEA. The present study suggests new mechanisms responsible for interannual variations of stratiform clouds in WEA, thus providing avenues of future research regarding the stability of the stratiform cloud deck under the ongoing differential warming of tropical ocean and land masses

Isotopic Composition of Solar Wind Calcium: First in Situ Measurement by CELIAS/MTOF on Board SOHO

We present first results on the Ca isotopic abundances derived from the high resolution Mass Time-of-Flight (MTOF) spectrometer of the charge, element, and isotope analysis system (CELIAS) experiment on board the Solar and Heliospheric Observatory (SOHO). We obtain isotopic ratios 40Ca/42Ca = (128+-47) and 40Ca/44Ca = (50+-8), consistent with terrestrial values. This is the first in situ determination of the solar wind calcium isotopic composition and is important for studies of stellar modeling and solar system formation since the present-day solar Ca isotopic abundances are unchanged from their original isotopic composition in the solar nebula.Comment: 14 pages, 3 figure

Halogen activation and radical cycling initiated by imidazole-2-carboxaldehyde photochemistry

Atmospheric aerosol particles can contain light-absorbing organic compounds, also referred to as brown carbon (BrC). The ocean surface and sea spray aerosol particles can also contain light-absorbing organic species referred to as chromophoric dissolved organic matter (CDOM). Many BrC and CDOM species can contain carbonyls, dicarbonyls or aromatic carbonyls such as imidazole-2-carboxaldehyde (IC), which may act as photosensitizers because they form triplet excited states upon UV&ndash;VIS light absorption. These triplet excited states are strong oxidants and may initiate catalytic radical reaction cycles within and at the surface of atmospheric aerosol particles, thereby increasing the production of condensed-phase reactive oxygen species (ROS). Triplet states or ROS can also react with halides, generating halogen radicals and molecular halogen compounds. In particular, molecular halogens can be released into the gas phase, which is one halogen activation pathway. In this work, we studied the influence of bromide and iodide on the photosensitized production and release of hydroperoxy radicals (HO2) upon UV irradiation of films in a coated wall flow tube (CWFT) containing IC in a matrix of citric acid (CA) irradiated with UV light. In addition, we measured the iodine release upon irradiation of IC ∕ CA films in the CWFT. We developed a kinetic model coupling photosensitized CA oxidation with condensed-phase halogen chemistry to support data analysis and assessment of atmospheric implications in terms of HO2 production and halogen release in sea spray particles. As indicated by the experimental results and confirmed by the model, significant recycling of halogen species occurred via scavenging reactions with HO2. These prevented the full and immediate release of the molecular halogen (bromine and iodine) produced. Recycling was stronger at low relative humidity, attributed to diffusion limitations. Our findings also show that the HO2 production from BrC or CDOM photosensitized reactions can increase due to the presence of halides, leading to high HO2 turnover, in spite of low release due to the scavenging reactions. We estimated the iodine production within sea salt aerosol particles due to iodide oxidation by ozone (O3) at 5.0&times;10-6 M s&minus;1 assuming O3 was in Henry's law equilibrium with the particle. However, using an O3 diffusion coefficient of 1&times;10-12 cm2 s&minus;1, iodine activation in an aged, organic-rich sea spray is estimated to be 5.5&times;10-8 M s&minus;1. The estimated iodine production from BrC photochemistry based on the results reported here amounts to 4.1&times;10-7 M s&minus;1 and indicates that BrC photochemistry can exceed O3 reactive uptake in controlling the rates of iodine activation from sea spray particles under dry or cold conditions where diffusion is slow within particles.</p

A new form of Saturn's magnetopause using a dynamic pressure balance model, based on in situ, multi‐instrument Cassini measurements

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95429/1/jgra19967.pd

The Solar Origin of Corotating Interaction Regions and Their Formation in the Inner Heliosphere

Corotating Interaction Regions (CIRs) form as a consequence of the compression of the solar wind at the interface between fast speed streams and slow streams. Dynamic interaction of solar wind streams is a general feature of the heliospheric medium; when the sources of the solar wind streams are relatively stable, the interaction regions form a pattern which corotates with the Sun. The regions of origin of the high speed solar wind streams have been clearly identified as the coronal holes with their open magnetic field structures. The origin of the slow speed solar wind is less clear; slow streams may well originate from a range of coronal configurations adjacent to, or above magnetically closed structures. This article addresses the coronal origin of the stable pattern of solar wind streams which leads to the formation of CIRs. In particular, coronal models based on photospheric measurements are reviewed; we also examine the observations of kinematic and compositional solar wind features at 1 AU, their appearance in the stream interfaces (SIs) of CIRs, and their relationship to the structure of the solar surface and the inner corona; finally we summarise the Helios observations in the inner heliosphere of CIRs and their precursors to give a link between the optical observations on their solar origin and the in-situ plasma observations at 1 AU after their formation. The most important question that remains to be answered concerning the solar origin of CIRs is related to the origin and morphology of the slow solar wind.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43796/1/11214_2004_Article_248206.pd

The Solar Orbiter Science Activity Plan: translating solar and heliospheric physics questions into action

Solar Orbiter is the first space mission observing the solar plasma both in situ and remotely, from a close distance, in and out of the ecliptic. The ultimate goal is to understand how the Sun produces and controls the heliosphere, filling the Solar System and driving the planetary environments. With six remote-sensing and four in-situ instrument suites, the coordination and planning of the operations are essential to address the following four top-level science questions: (1) What drives the solar wind and where does the coronal magnetic field originate?; (2) How do solar transients drive heliospheric variability?; (3) How do solar eruptions produce energetic particle radiation that fills the heliosphere?; (4) How does the solar dynamo work and drive connections between the Sun and the heliosphere? Maximising the mission’s science return requires considering the characteristics of each orbit, including the relative position of the spacecraft to Earth (affecting downlink rates), trajectory events (such as gravitational assist manoeuvres), and the phase of the solar activity cycle. Furthermore, since each orbit’s science telemetry will be downloaded over the course of the following orbit, science operations must be planned at mission level, rather than at the level of individual orbits. It is important to explore the way in which those science questions are translated into an actual plan of observations that fits into the mission, thus ensuring that no opportunities are missed. First, the overarching goals are broken down into specific, answerable questions along with the required observations and the so-called Science Activity Plan (SAP) is developed to achieve this. The SAP groups objectives that require similar observations into Solar Orbiter Observing Plans, resulting in a strategic, top-level view of the optimal opportunities for science observations during the mission lifetime. This allows for all four mission goals to be addressed. In this paper, we introduce Solar Orbiter’s SAP through a series of examples and the strategy being followed

Treatment of gout in a renal transplant patient leading to severe thrombocytopenia

What is known and objective: Allopurinol (AP) inhibits the xanthine oxidase, which may indirectly lead to myelotoxicity when used in combination with azathioprine (AZA). Case summary: A 79-year-old female developed symptomatic thrombocytopenia after combination therapy with AZA (75 mg/day) and AP (100 mg/day) – after AP had been stopped. Concentrations of the myelotoxic 6-thioguanine-nucleotides metabolite of AZA were increased. Thrombocyte counts normalized within 8 days of discontinuation of AZA. What is new and conclusion: The effect of a drug interaction in a patient with decreased elimination capacity may take several weeks to become apparent and may in fact do so even after the drug has been stopped. Concurrent AZA and AP therapy demands cautious use