989 research outputs found
Long-term trapping of Stark-decelerated molecules
Trapped cold molecules represent attractive systems for precision-spectroscopic studies and for investigations of cold collisions and chemical reactions. However, achieving their confinement for sufficiently long timescales remains a challenge. Here, we report the long-term trapping of Stark-decelerated OH radicals in their X (2)Pi(3/2) (nu = 0, J = 3/2, M-J = 3/2, f) state in a permanent magnetic trap. The trap environment is cryogenically cooled to a temperature of 17 K to suppress black-body-radiation-induced pumping of the molecules out of trappable quantum states and collisions with residual background gas molecules which usually limit the trap lifetime. The cold molecules are thus confined on timescales approaching minutes, an improvement of up to two orders of magnitude compared with room temperature experiments, at translational temperatures of similar to 25 mK. The present results pave the way for new experiments using trapped cold molecules in precision spectroscopy, in studies of slow chemical processes at low energies and in the quantum technologies
Laser Cooling of Optically Trapped Molecules
Calcium monofluoride (CaF) molecules are loaded into an optical dipole trap
(ODT) and subsequently laser cooled within the trap. Starting with
magneto-optical trapping, we sub-Doppler cool CaF and then load CaF
molecules into an ODT. Enhanced loading by a factor of five is obtained when
sub-Doppler cooling light and trapping light are on simultaneously. For trapped
molecules, we directly observe efficient sub-Doppler cooling to a temperature
of . The trapped molecular density of
cm is an order of magnitude greater than in the initial sub-Doppler
cooled sample. The trap lifetime of 750(40) ms is dominated by background gas
collisions.Comment: 5 pages, 5 figure
Cold and Ultracold Molecules: Science, Technology, and Applications
This article presents a review of the current state of the art in the
research field of cold and ultracold molecules. It serves as an introduction to
the Special Issue of the New Journal of Physics on Cold and Ultracold Molecules
and describes new prospects for fundamental research and technological
development. Cold and ultracold molecules may revolutionize physical chemistry
and few body physics, provide techniques for probing new states of quantum
matter, allow for precision measurements of both fundamental and applied
interest, and enable quantum simulations of condensed-matter phenomena.
Ultracold molecules offer promising applications such as new platforms for
quantum computing, precise control of molecular dynamics, nanolithography, and
Bose-enhanced chemistry. The discussion is based on recent experimental and
theoretical work and concludes with a summary of anticipated future directions
and open questions in this rapidly expanding research field.Comment: 82 pages, 9 figures, review article to appear in New Journal of
Physics Special Issue on Cold and Ultracold Molecule
Formation and interactions of cold and ultracold molecules: new challenges for interdisciplinary physics
Progress on researches in the field of molecules at cold and ultracold
temperatures is reported in this review. It covers extensively the experimental
methods to produce, detect and characterize cold and ultracold molecules
including association of ultracold atoms, deceleration by external fields and
kinematic cooling. Confinement of molecules in different kinds of traps is also
discussed. The basic theoretical issues related to the knowledge of the
molecular structure, the atom-molecule and molecule-molecule mutual
interactions, and to their possible manipulation and control with external
fields, are reviewed. A short discussion on the broad area of applications
completes the review.Comment: to appear in Reports on Progress in Physic
Rydberg Molecules and Circular Rydberg states in Cold Atom Clouds.
In this dissertation I investigate cold Rydberg atoms and molecules in which the angular-momentum character of the quantum states involved strongly influences their properties and dynamics. In the first part I focus on long-range diatomic Rydberg molecules formed by a rubidium D-state Rydberg atom and a second rubidium atom in its ground state. Spectroscopic measurements of molecular binding energies are presented showing the effect of the Rydberg atom size and fine-structure coupling on the molecular potentials. A theoretical model is introduced that takes into account all relevant angular-momentum couplings between the molecular constituents, successfully reproducing experimental observations. Calculations of adiabatic potentials and binding energies, molecular-state lifetimes, electric and magnetic dipole moments are also presented. In the second part, I describe the production and magnetic trapping of cold circular Rydberg atoms. The circular Rydberg atoms are generated out of a cold gas of rubidium using the crossed-fields method and magnetically trapped. The trapping force is employed to induce center-of-mass oscillations of the trapped atom sample. Trap parameters and observed oscillation frequencies are used to measure the magnetic moments of the circular Rydberg atoms. Trap losses and the atomic internal-state evolution in the 300 Kelvin thermal background are also investigated.PHDApplied PhysicsUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib.umich.edu/bitstream/2027.42/111347/1/anderda_1.pd
Molecular regimes in ultracold Fermi gases
The use of Feshbach resonances for tuning the interparticle interaction in
ultracold Fermi gases has led to remarkable developments, in particular to the
creation and Bose-Einstein condensation of weakly bound diatomic molecules of
fermionic atoms. These are the largest diatomic molecules obtained so far, with
a size of the order of thousands of angstroms. They represent novel composite
bosons, which exhibit features of Fermi statistics at short intermolecular
distances. Being highly excited, these molecules are remarkably stable with
respect to collisional relaxation, which is a consequence of the Pauli
exclusion principle for identical fermionic atoms. The purpose of this review
is to introduce theoretical approaches and describe the physics of molecular
regimes in two-component Fermi gases and Fermi-Fermi mixtures, focusing
attention on quantum statistical effects.Comment: Chapter of the book: "Cold Molecules: Theory, Experiment,
Applications" edited by R. V. Krems, B. Friedrich and W. C. Stwalley
(publication expected in March 2009
Quo vadis, cold molecules? - Editorial review
We give a snapshot of the rapidly developing field of ultracold polar
molecules abd walk the reader through the papers appearing in this topical
issue
A molecular line study of NGC 1333/IRAS 4
Molecular line surveys and fully sampled spectral line maps at 1.3 and 0.87 mm are used to examine the
physical and chemical characteristics of the extreme Class I sources IRAS 4A and 4B in the L1450/NGC 1333
molecular cloud complex. A very well collimated, jetlike molecular outflow emanates from IRAS 4A, with a
dynamical age of a few thousand years. Symmetric, clumpy structure along the outflow lobes suggests that
there is considerable variability in the mass-loss rate or wind velocity even at this young age. Molecular emission
lines toward IRAS 4A and 4B are observed to be weak in the velocity range corresponding to quiescent
material surrounding the young stellar objects (YSOs). Depletion factors of 10-20 are observed for αll molecules,
including CO, even for very conservative mass estimates from the measured millimeter and submillimeter
dust continuum. However, abundances scaled with respect to CO are similar to other dark
molecular cloud cores. Such depletions could be mimicked by high dust optical depths or increased grain
emissivities at the observing frequencies of 230 and 345 GHz, but the millimeter and submillimeter spectral
energy distributions suggest that this is unlikely over the single-dish size scales of 5000-10,000 AU.
Dense, outflowing gas is found to be kinematically, but not spatially, distinct from the quiescent material on
these size scales. If CO is used as a chemical standard for the high-velocity gas, we find substantial enhancements
in the abundances of several molecules in outflowing material, most notably CS, SiO, and CH_30H. The
SiO emission is kinematically well displaced from the bulk cloud velocity and likely arises from directly
shocked material. As is the case for CO, however, the outflow features from more volatile species are centered
near the cloud velocity and are often characterized by quite low rotational temperatures. We suggest that
grain-grain collisions induced by velocity shear zones surrounding the outflow axes transiently desorb the
grain mantles, resulting in large abundance enhancements of selected species. Similar results have recently
been obtained in several other low-mass YSOs, where the outflowing gas is often both kinematically and spatially
distinct, and are illustrative of the ability of accretion and outflow processes to simultaneously modify
the composition of the gas and dust surrounding young stars
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