Application of hyperspectral imaging combined with chemometrics for the non-destructive evaluation of the quality of fruit in postharvest

Tesis por compendio[ES] El objetivo de esta tesis doctoral es evaluar la técnica de imagen hiperespectral en el rango visible e infrarrojo cercano, en combinación con técnicas quimiométricas para la evaluación de la calidad de la fruta en poscosecha de manera eficaz y sostenible. Con este fin, se presentan diferentes estudios en los que se evalúa la calidad de algunas frutas que por su valor económico, estratégico o social, son de especial importancia en la Comunidad Valenciana como son el caqui 'Rojo Brillante', la granada 'Mollar de Elche', el níspero 'Algerie' o diferentes cultivares de nectarina. En primer lugar se llevó a cabo la monitorización de la calidad poscosecha de nectarinas 'Big Top' y 'Magique' usando imagen hiperespectral en reflectancia y transmitancia. Al mismo tiempo se evaluó la transmitancia para la detección de huesos abiertos. Se llevó a cabo también un estudio para distinguir los cultivares 'Big Top' y "Diamond Ray", los cuales poseen un aspecto muy similar pero sabor diferente. En cuanto al caqui 'Rojo Brillante', la imagen hiperespectral fue estudiada por una parte para monitorear su madurez, y por otra parte para evaluar la astringencia de esta fruta, que debe ser completamente eliminada antes de su comercialización. Las propiedades físico-químicas de la granada 'Mollar de Elche' fueron evaluadas usando imagen de color e hiperespectral durante su madurez usando la información de la fruta intacta y de los arilos. Finalmente, esta técnica se usó para caracterizar e identificar los defectos internos y externos del níspero 'Algerie'. En la predicción de los índices de calidad IQI y RPI usando imagen en reflectancia y transmitancia se obtuvieron valores de R2 alrededor de 0,90 y en la discriminación por firmeza, una precisión entorno al 95 % usando longitudes de onda seleccionadas. En cuanto a la detección de huesos abiertos, el uso de la imagen hiperespectral en transmitancia obtuvo un 93,5 % de clasificación correcta de frutas con hueso normal y 100 % con hueso abierto usando modelos PLS-DA y 7 longitudes de onda. Los resultados obtenidos en la clasificación de los cultivares 'Big Top' y 'Diamond Ray' mostraron una fiabilidad superior al 96,0 % mediante el uso de modelos PLS-DA y 14 longitudes de onda seleccionadas, superando a la imagen de color (56,9 %) y a un panel entrenado (54,5 %). Con respecto al caqui, los resultados obtenidos indicaron que es posible distinguir entre tres estados de madurez con una precisión del 96,0 % usando modelos QDA y se predijo su firmeza obteniendo un valor de R2 de 0,80 usando PLS-R. En cuanto a la astringencia, se llevaron a cabo dos estudios similares en los que en el primero se discriminó la fruta de acuerdo al tiempo de tratamiento con altas concentraciones de CO2 con una precisión entorno al 95,0 % usando QDA. En el segundo se discriminó la fruta de acuerdo a un valor de contenido en taninos (0,04 %) y se determinó qué área de la fruta era mejor para realizar esta discriminación. Así se obtuvo una precisión del 86,9 % usando la zona media y 23 longitudes de onda. Los resultados obtenidos para la granada indicaron que la imagen de color e hiperespectral poseen una precisión similar en la predicción de las propiedades fisicoquímicas usando PLS-R y la información de la fruta intacta. Sin embargo, cuando se usó la información de los arilos, la imagen hiperespectral fue más precisa. En cuanto a la discriminación del estado de madurez usando PLS-DA, la imagen hiperespectral ofreció mayor precisión, 95,0 %, usando la información de la fruta intacta y del 100 % usando la de los arilos. Finalmente, los resultados obtenidos para el níspero indicaron que la imagen hiperespectral junto con el método de clasificación XGBOOST pudo discriminar entre muestras con y sin defectos con una precisión del 97,5 % y entre muestras sin defectos o con defectos internos o externos con una precisión del 96,7 %. Además fue posible distinguir entre los dife[CA] L'objectiu de la present tesi doctoral se centra en avaluar la capacitat de la imatge hiperespectral en el rang visible i infraroig pròxim, en combinació amb mètodes quimiomètrics, per a l'avaluació de la qualitat de la fruita en post collita de manera eficaç i sostenible. A aquest efecte, es presenten diferents estudis en els quals s'avalua la qualitat d'algunes fruites que pel seu valor econòmic, estratègic o social, són d'especial importància a la Comunitat Valenciana com són el caqui 'Rojo Brillante', la magrana 'Mollar de Elche', el nispro 'Algerie' o diferents cultivares de nectarina. En primer lloc es va dur a terme la monitorització de la qualitat post collita de nectarines 'Big Top' i 'Magique' per mitjà d'imatge hiperespectral en reflectància i trasnmitancia. Així mateix es va avaluar la transmitància per a la detecció d'ossos oberts. Es va dur a terme també un estudi per distingir els cultivares 'Big Top' i 'Diamond Ray', els quals posseeixen un aspecte molt semblant però sabor diferent. Pel que fa al caqui 'Rojo Brillante', la imatge hiperespectral va ser estudiada d'una banda per a monitoritzar la seua maduresa, i per un altre costat per avaluar l'astringència, que ha de ser completament eliminada abans de la seua comercialització. Les propietats fisicoquímiques de la magrana 'Mollar de Elche' van ser avaluades per la imatge de color i hiperespectral durant la seua maduresa usant la informació de la fruita intacta i els arils. Finalment, aquesta tècnica es va fer servir per caracteritzar i identificar els defectes interns i externs del nispro 'Algerie'. En la predicció dels índexs de qualitat IQI i RPI usant imatge en reflectància com en trasnmitancia es van obtindre valors de R2 al voltant de 0,90 i en la discriminació per fermesa una precisió entorn del 95,0 % utilitzant longituds d'ona seleccionades. Pel que fa a la detecció d'ossos oberts, l'ús de la imatge hiperespectral en transmitància va obtindre un 93,5 % classificació correcta de fruites amb os normal i 100 % amb os obert usant models PLS-DA i 7 longituds d'ona. Els resultats obtinguts en la classificació dels cultivares 'Big Top' i 'Diamond Ray' van mostrar una fiabilitat superior al 96,0 % per mitjà de l'ús de models PLS-DA i 14 longituds d'ona, superant a la imatge de color (56,9 %) i a un panell sensorial entrenat (54,5 %). Quant al caqui, els resultats obtinguts van indicar que és possible distingir entre tres estats de maduresa amb una precisió del 96,0 % usant models QDA i es va predir la seua fermesa obtenint un valor de R2 de 0,80 usant PLS-R. Pel que fa a l'astringència, es van dur a terme dos estudis similars en què el primer es va discriminar la fruita d'acord al temps de tractament amb altes concentracions de CO2 amb una precisió al voltant del 95,0 % usant QDA. En el segon, es va discriminar la fruita d'acord a un valor de contingut en tanins (0,04 %) i es va determinar quina part de la fruita era millor per a realitzar aquesta discriminació. Així es va obtindre una precisió del 86,9 % usant la zona mitjana i 23 longituds d'ona. Els resultats obtinguts per la magrana van indicar que la imatge de color i hiperespectral posseïxen una precisió semblant a la predicció de les propietats fisicoquímiques usant PLS-R i la informació de la fruita intacta. No obstant això, quan es va usar la informació dels arils, la imatge hiperespectral va ser més precisa. Quant a la discriminació de l'estat de maduresa usant PLS-DA, la imatge hiperespectral va oferir major precisió (95,0 %) usant la informació de la fruita intacta i del 100 % usant la dels arils. Finalment, els resultats obtinguts pel nispro indiquen que la imatge hiperespectral juntament amb el mètode de classificació XGBOOST va poder discriminar entre mostres amb i sense defectes amb una precisió del 97,5 % i entre mostres sense defectes o amb defectes interns o externs amb una precisió del 96,7 %. A més, va ser possible distingir entre[EN] The objective of this doctoral thesis is to evaluate the potential of the hyperspectral imaging in the visible and near infrared range in combination with chemometrics for the assessment of the postharvest quality of fruit in a non-destructive, efficient and sustainable manner. To this end, different studies are presented in which the quality of some fruits is evaluated. Due to their economic, strategic or social value, the selected fruits are of special importance in the Valencian Community, such as Persimmon 'Rojo Brillante', the pomegranate 'Mollar de Elche', the loquat 'Algerie' or different nectarine cultivars. First, the quality monitoring of 'Big Top' and 'Magique' nectarines was carried out using reflectance and transmittance images. At the same time, transmittance was evaluated for the detection of split pit. In addition, a classification was performed to distinguish the 'Big Top' and 'Diamond Ray' cultivars, which look very similar but have different flavour. Whereas that for the 'Rojo Brillante' persimmon, the hyperspectral imaging was studied on the one hand to monitor its maturity, and on the other hand to evaluate the astringency of this fruit, which must be completely eliminated before its commercialization. The physicochemical properties of the 'Mollar de Elche' pomegranate were evaluated by means of hyperspectral and colour imaging during its maturity using the information from the intact fruit and arils. Finally, this technique was used to characterise and identify the internal and external defects of the 'Algerie' loquat. In the prediction of the IQI and RPI quality indexes using reflectance and transmittance images, R2 values around 0.90 were obtained and in the discrimination according to firmness, accuracy around 95.0 % using selected wavelengths was obtained. Regarding the split pit detection, the use of the hyperspectral image in transmittance mode obtained a 93.5 % of fruits with normal bone correctly classified and 100% with split pit using PLS-DA models and 7 wavelengths. The results obtained in the classification of 'Big Top' and 'Diamond Ray' fruits show accuracy higher than 96.0 % by using PLS-DA models and 14 selected wavelengths, higher than the obtained with colour image (56.9 %) and a trained panel (54.5 %). According to persimmon, the results obtained indicated that it is possible to distinguish between three states of maturity with an accuracy of 96.0 % using QDA models and its firmness was predicted obtaining a R2 value of 0.80 using PLS-R. Regarding astringency, two similar studies were carried out. In the first study, the fruit was classified according to the time of treatment with high concentrations of CO2 with a precision of around 95.0 % using QDA. In the second, the fruit was discriminated according to a threshold value of soluble tannins (0.04 %) and was determined what fruit area was better to perform this discrimination. Thus, an accuracy of 86.9 % was obtained using the middle area and 23 wavelengths. The results obtained for the pomegranate indicated that the use of colour and hyperspectral images have a similar precision in the prediction of physicochemical properties using PLS-R and the intact fruit information. However, when the information from the arils was used, the hyperspectral image was more accurate. Regarding the discrimination by the state of maturity using PLS-DA, the hyperspectral image offered greater precision, of 95.0 % using the information from the intact fruit and 100 % using that from the arils. Finally, the results obtained for the 'Algerie' loquat indicated that the hyperspectral image with the XGBOOST classification method could discriminate between sound samples and samples with defects with accuracy of 97.5 % and between sound samples or samples with internal or external defects with an accuracy of 96.7 %. It was also possible to distinguish between the different defects with an accuracy of 95.9 %.Munera Picazo, SM. (2019). Application of hyperspectral imaging combined with chemometrics for the non-destructive evaluation of the quality of fruit in postharvest [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/125954TESISCompendi

Computer Vision System for Non-Destructive and Contactless Evaluation of Quality Traits in Fresh Rocket Leaves (Diplotaxis Tenuifolia L.)

La tesi di dottorato è incentrata sull'analisi di tecnologie non distruttive per il controllo della qualità dei prodotti agroalimentari, lungo l'intera filiera agroalimentare. In particolare, la tesi riguarda l'applicazione del sistema di visione artificiale per valutare la qualità delle foglie di rucola fresh-cut. La tesi è strutturata in tre parti (introduzione, applicazioni sperimentali e conclusioni) e in cinque capitoli, rispettivamente il primo e il secondo incentrati sulle tecnologie non distruttive e in particolare sui sistemi di computer vision per il monitoraggio della qualità dei prodotti agroalimentari. Il terzo, quarto e quinto capitolo mirano a valutare le foglie di rucola sulla base della stima di parametri qualitativi, considerando diversi aspetti: (i) la variabilità dovuta alle diverse pratiche agricole, (ii) la senescenza dei prodotti confezionati e non, e (iii) lo sviluppo e sfruttamento dei vantaggi di nuovi modelli più semplici rispetto al machine learning utilizzato negli esperimenti precedenti. Il lavoro di ricerca di questa tesi di dottorato è stato svolto dall'Università di Foggia, dall'Istituto di Scienze delle Produzioni Alimentari (ISPA) e dall'Istituto di Tecnologie e Sistemi Industriali Intelligenti per le Manifatture Avanzate (STIIMA) del Consiglio Nazionale delle Ricerche (CNR). L’attività di ricerca è stata condotta nell'ambito del Progetto SUS&LOW (Sustaining Low-impact Practices in Horticulture through Non-destructive Approach to Provide More Information on Fresh Produce History & Quality), finanziato dal MUR-PRIN 2017, e volto a sostenere la qualità della produzione e dell'ambiente utilizzando pratiche agricole a basso input e la valutazione non distruttiva della qualità di prodotti ortofrutticoli.The doctoral thesis focused on the analysis of non-destructive technologies available for the control quality of agri-food products, along the whole supply chain. In particular, the thesis concerns the application of computer vision system to evaluate the quality of fresh rocket leaves. The thesis is structured in three parts (introduction, experimental applications and conclusions) and in 5 chapters, the first and second focused on non-destructive technologies and in particular on computer vision systems for monitoring the quality of agri-food products, respectively. The third, quarter, and fifth chapters aim to assess the rocket leaves based on the estimation of quality aspects, considering different aspects: (i) the variability due to the different agricultural practices, (ii) the senescence of packed and unpacked products, and (iii) development and exploitation of the advantages of new models simpler than the machine learning used in the previous experiments. The research work of this doctoral thesis was carried out by the University of Foggia, the Institute of Science of Food Production (ISPA) and the Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing (STIIMA) of National Research Council (CNR). It was conducted within the Project SUS&LOW (Sustaining Low-impact Practices in Horticulture through Non-destructive Approach to Provide More Information on Fresh Produce History & Quality), funded by MUR- PRIN 2017, and aimed at sustaining quality of production and of the environment using low input agricultural practices and non-destructive quality evaluation

New Methods for ferrous raw materials characterization in electric steelmaking

425 p.In the siderurgical sector, the steel scrap is the most important raw material in electric steelmaking,contributing between 70% of the total production costs. It is well-known how the degree of which thescrap mix can be optimized, and also the degree of which the melting operation can be controlled andautomated, is limited by the knowledge of the properties of the scrap and other raw-materials in thecharge mix.Therefore, it is of strategic importance having accurate information about the scrap composition of thedifferent steel scrap types. In other words, knowing scrap characteristics is a key point in order to managethe steel-shop resources, optimize the scrap charge mix/composition at the electric arc furnace (EAF),increase the plant productivity, minimize the environmental footprint of steelmaking activities and tohave the lowest total cost of ownership of the plant.As a main objective of present doctoral thesis, the doctorate will provide new tools and methods of scrapcharacterization to increase the current recycling ration, through better knowledge of the quality of thescrap, and thus go in the direction of a 100% recycling ratio. In order to achieve it, two main workinglines were developed in present research. Firstly, it was analysed not only the different existingmethodologies for scrap characterization and EAF process optimization, but also to develop new methodsor combination of existing, Secondly, it was defined a general recommendations guide for implementingthese methods based on the specifics of each plant

Application of mixed and virtual reality in geoscience and engineering geology

Visual learning and efficient communication in mining and geotechnical practices is crucial, yet often challenging. With the advancement of Virtual Reality (VR) and Mixed Reality (MR) a new era of geovisualization has emerged. This thesis demonstrates the capabilities of a virtual continuum approach using varying scales of geoscience applications. An application that aids analyses of small-scale geological investigation was constructed using a 3D holographic drill core model. A virtual core logger was also developed to assist logging in the field and subsequent communication by visualizing the core in a complementary holographic environment. Enriched logging practices enhance interpretation with potential economic and safety benefits to mining and geotechnical infrastructure projects. A mine-scale model of the LKAB mine in Sweden was developed to improve communication on mining induced subsidence between geologists, engineers and the public. GPS, InSAR and micro-seismicity data were hosted in a single database, which was geovisualized through Virtual and Mixed Reality. The wide array of applications presented in this thesis illustrate the potential of Mixed and Virtual Reality and improvements gained on current conventional geological and geotechnical data collection, interpretation and communication at all scales from the micro- (e.g. thin section) to the macro- scale (e.g. mine)

Real-time classification of coffee fruits using FPGA

The goal in this work was to design a circuit that could classify objects by color in real-time that can be used for quality improvement. A circuit that performs color analysis of an image and, according to that analysis, classifies the object was designed. A histogram of the Spherical Coordinate Transform of the image is computed and compared to histogram patterns to make a classification decision. The circuit was tested on the classification of coffee fruits in four maturity stages: immature, under-mature, mature and over-mature. The results showed that it is possible to build a system for color object classification that works in real-time and that can be affordable and portable. The designed circuit is implemented on a Field Programmable Gate Array (FPGA), acquires video at 64 frames per second, classifies the coffee fruits at a rate of 25 fruits per second and achieved an average efficacy of 75.7%Abstract : El objetivo de este trabajo fue diseñar un circuito que lograra clasificar objetos basado en su color funcionando en tiempo real y que pueda ser usado en aplicaciones de control de calidad. Se diseñó un circuito que toma una imagen, analiza sus características de color y, de acuerdo a este análisis, asigna el objeto a una categoría. La imagen se transforma del espacio RGB a coordenadas esféricas, se calcula el histograma de la imagen transformada y se compara con los patrones de cada categoría para realizar la asignación. El circuito fue usado para clasificar frutos de café en cuatro estados de maduración: inmaduro, pintón, maduro y sobremaduro. Los resultados mostraron que es posible construir un sistema que clasifique objetos basado en su color, que funcione en tiempo real y que además sea económico y portátil. El circuito diseñado adquiere video a una velocidad de 64 cuadros por segundo, clasifica frutos de café a una tasa de 25 frutos por segundo y obtuvo una eficacia promedio de 75.7%Doctorad

Applications and Experiences of Quality Control

The rich palette of topics set out in this book provides a sufficiently broad overview of the developments in the field of quality control. By providing detailed information on various aspects of quality control, this book can serve as a basis for starting interdisciplinary cooperation, which has increasingly become an integral part of scientific and applied research

Investigation of a 'Field Factory' to harvest and grade tree stock in a forestry nursery

Primary industries are facing an ever increasing labour problem. Major concerns with labour include lack of staff training, high costs, poor efficiency, non-optimal quality control and health and safety issues. While automation is commonplace in factory environments, such technologies have not yet migrated to an outdoor, agricultural environment. Forestry nurseries are no exception, where the most problematic and labour intensive task is lifting and grading tree stock. Mechanical lifting of tree stock is already performed commercially; however, these machines are incapable of performing the additional steps required by this research, particularly root trimming, coupled with a machine vision system that can replicate the human decision making process for selecting ’good’ and ’bad’ tree stock. In particular, there are strict criteria for root structure which must be assessed. Currently, human graders are proving to be poor assessors of this, to such an extent that tree stock is graded up to three times before being shipped to the customer. Additionally, there is the need to remove expensive pack houses. This research investigates a field factory capable of processing forestry tree stock in the field, from lifting through to grading and boxing. The machine vision component of the field factory was tested in controlled conditions, on a sample of 200 trees. There was good agreement between machine vision measurements and manually measured tree features. There is much ambiguity in the grading process, with three experts only reaching a consensus 75% of the time when grading a sample of trees. The machine vision grading system performed very well, showing less bias than human graders. The machine agreed with the specification 96% of the time, significantly higher than the experts’ agreements of between 86 and 90%. While classification systems such as fuzzy logic and artificial neural networks seem to be a good match for this research, they did not outperform the ’crisp’ grading system. A field factory for harvesting and grading forestry tree stock proved to be feasible; however, further development, particularly on mechanical systems, is required to produce a machine reliable enough to be implemented commercially

Feature Selection and Classifier Development for Radio Frequency Device Identification

The proliferation of simple and low-cost devices, such as IEEE 802.15.4 ZigBee and Z-Wave, in Critical Infrastructure (CI) increases security concerns. Radio Frequency Distinct Native Attribute (RF-DNA) Fingerprinting facilitates biometric-like identification of electronic devices emissions from variances in device hardware. Developing reliable classifier models using RF-DNA fingerprints is thus important for device discrimination to enable reliable Device Classification (a one-to-many looks most like assessment) and Device ID Verification (a one-to-one looks how much like assessment). AFITs prior RF-DNA work focused on Multiple Discriminant Analysis/Maximum Likelihood (MDA/ML) and Generalized Relevance Learning Vector Quantized Improved (GRLVQI) classifiers. This work 1) introduces a new GRLVQI-Distance (GRLVQI-D) classifier that extends prior GRLVQI work by supporting alternative distance measures, 2) formalizes a framework for selecting competing distance measures for GRLVQI-D, 3) introducing response surface methods for optimizing GRLVQI and GRLVQI-D algorithm settings, 4) develops an MDA-based Loadings Fusion (MLF) Dimensional Reduction Analysis (DRA) method for improved classifier-based feature selection, 5) introduces the F-test as a DRA method for RF-DNA fingerprints, 6) provides a phenomenological understanding of test statistics and p-values, with KS-test and F-test statistic values being superior to p-values for DRA, and 7) introduces quantitative dimensionality assessment methods for DRA subset selection