Laser diagnostics and minor species detection in combustion using resonant four-wave mixing

Peer reviewedPostprin

Visible and near infrared spectroscopy in soil science

This chapter provides a review on the state of soil visible–near infrared (vis–NIR) spectroscopy. Our intention is for the review to serve as a source of up-to date information on the past and current role of vis–NIR spectroscopy in soil science. It should also provide critical discussion on issues surrounding the use of vis–NIR for soil analysis and on future directions. To this end, we describe the fundamentals of visible and infrared diffuse reflectance spectroscopy and spectroscopic multivariate calibrations. A review of the past and current role of vis–NIR spectroscopy in soil analysis is provided, focusing on important soil attributes such as soil organic matter (SOM), minerals, texture, nutrients, water, pH, and heavy metals. We then discuss the performance and generalization capacity of vis–NIR calibrations, with particular attention on sample pre-tratments, co-variations in data sets, and mathematical data preprocessing. Field analyses and strategies for the practical use of vis–NIR are considered. We conclude that the technique is useful to measure soil water and mineral composition and to derive robust calibrations for SOM and clay content. Many studies show that we also can predict properties such as pH and nutrients, although their robustness may be questioned. For future work we recommend that research should focus on: (i) moving forward with more theoretical calibrations, (ii) better understanding of the complexity of soil and the physical basis for soil reflection, and (iii) applications and the use of spectra for soil mapping and monitoring, and for making inferences about soils quality, fertility and function. To do this, research in soil spectroscopy needs to be more collaborative and strategic. The development of the Global Soil Spectral Library might be a step in the right direction

Gradient metasurfaces: a review of fundamentals and applications

In the wake of intense research on metamaterials the two-dimensional analogue, known as metasurfaces, has attracted progressively increasing attention in recent years due to the ease of fabrication and smaller insertion losses, while enabling an unprecedented control over spatial distributions of transmitted and reflected optical fields. Metasurfaces represent optically thin planar arrays of resonant subwavelength elements that can be arranged in a strictly or quasi periodic fashion, or even in an aperiodic manner, depending on targeted optical wavefronts to be molded with their help. This paper reviews a broad subclass of metasurfaces, viz. gradient metasurfaces, which are devised to exhibit spatially varying optical responses resulting in spatially varying amplitudes, phases and polarizations of scattered fields. Starting with introducing the concept of gradient metasurfaces, we present classification of different metasurfaces from the viewpoint of their responses, differentiating electrical-dipole, geometric, reflective and Huygens' metasurfaces. The fundamental building blocks essential for the realization of metasurfaces are then discussed in order to elucidate the underlying physics of various physical realizations of both plasmonic and purely dielectric metasurfaces. We then overview the main applications of gradient metasurfaces, including waveplates, flat lenses, spiral phase plates, broadband absorbers, color printing, holograms, polarimeters and surface wave couplers. The review is terminated with a short section on recently developed nonlinear metasurfaces, followed by the outlook presenting our view on possible future developments and perspectives for future applications.Comment: Accepted for publication in Reports on Progress in Physic

Mueller matrix polarimetry of plasmon resonant silver nano-rods: biomedical prospects

Fundamental understanding of the light-matter interaction in the context of nano-particles is immensely bene- fited by the study of geometry dependent tunable Localized Surface Plasmon Resonance (LSPR) and has been demonstrated to have potential applications in various areas of science. The polarization characteristics of LSPR in addition to spectroscopic tuning can be suitably exploited in such systems as contrast enhancement mech- anisms and control parameters. Such polarization characteristics like diattenuation and retardance have been studied here using a novel combination of Muller-matrix polarimetry with the T-matrix matrix approach for silver nano-rods to show unprecedented control and sensitivity to local refractive index variations. The study carried out over various aspect ratios for a constant equal volume sphere radius shows the presence of longitu- dinal (dipolar and quadrupolar) and transverse (dipolar) resonances; arising due to differential contribution of polarizabilities in two directions. The overlap regions of these resonances and the resonances themselves exhibit enhanced retardance and diattenuation respectively. The spectral and amplitude tunability of these polarimetric parameters through the aspect ratios to span from the minimum to maximum ([0, 1] in the case of diattenuation and [0, {\pi}] in the case of retardance) presents a novel result that could be used to tailor systems for study of biological media. On the other hand, the high sensitivity of diattenuation dip (caused by equal contribution of polarizabilities) could be possibly used for medium characterization and bio-sensing or bio-imaging studies.Comment: 8 pages, 6 figures, Proceedings of the Saratov Fall Meeting, 201

Gradient Optics of subwavelength nanofilms

Propagation and tunneling of light through subwavelength photonic barriers, formed by dielectric layers with continuous spatial variations of dielectric susceptibility across the film are considered. Effects of giant heterogeneity-induced non-local dispersion, both normal and anomalous, are examined by means of a series of exact analytical solutions of Maxwell equations for gradient media. Generalized Fresnel formulae, visualizing a profound influence of gradient and curvature of dielectric susceptibility profiles on reflectance/transmittance of periodical photonic heterostructures are presented. Depending on the cutoff frequency of the barrier, governed by technologically managed spatial profile of its refractive index, propagation or tunneling of light through these barriers are examined. Nonattenuative transfer of EM energy by evanescent waves, tunneling through dielectric gradient barriers, characterized by real values of refractive index, decreasing in the depth of medium, is shown. Scaling of the obtained results for different spectral ranges of visible, IR and THz waves is illustrated. Potential of gradient optical structures for design of miniaturized filters, polarizers and frequency-selective interfaces of subwavelength thickness is considered

Digital Color Imaging

This paper surveys current technology and research in the area of digital color imaging. In order to establish the background and lay down terminology, fundamental concepts of color perception and measurement are first presented us-ing vector-space notation and terminology. Present-day color recording and reproduction systems are reviewed along with the common mathematical models used for representing these devices. Algorithms for processing color images for display and communication are surveyed, and a forecast of research trends is attempted. An extensive bibliography is provided

A Non-Local Structure Tensor Based Approach for Multicomponent Image Recovery Problems

Non-Local Total Variation (NLTV) has emerged as a useful tool in variational methods for image recovery problems. In this paper, we extend the NLTV-based regularization to multicomponent images by taking advantage of the Structure Tensor (ST) resulting from the gradient of a multicomponent image. The proposed approach allows us to penalize the non-local variations, jointly for the different components, through various $\ell_{1,p}$ matrix norms with $p \ge 1$. To facilitate the choice of the hyper-parameters, we adopt a constrained convex optimization approach in which we minimize the data fidelity term subject to a constraint involving the ST-NLTV regularization. The resulting convex optimization problem is solved with a novel epigraphical projection method. This formulation can be efficiently implemented thanks to the flexibility offered by recent primal-dual proximal algorithms. Experiments are carried out for multispectral and hyperspectral images. The results demonstrate the interest of introducing a non-local structure tensor regularization and show that the proposed approach leads to significant improvements in terms of convergence speed over current state-of-the-art methods

Origin of the spin reorientation transitions in (Fe1−x_{1-x}Cox_{x})2_{2}B alloys

Low-temperature measurements of the magnetocrystalline anisotropy energy $K$ in (Fe$_{1-x}$Co$_{x}$)$_{2}$B alloys are reported, and the origin of this anisotropy is elucidated using a first-principles electronic structure analysis. The calculated concentration dependence $K(x)$ with a maximum near $x=0.3$ and a minimum near $x=0.8$ is in excellent agreement with experiment. This dependence is traced down to spin-orbital selection rules and the filling of electronic bands with increasing electronic concentration. At the optimal Co concentration, $K$ depends strongly on the tetragonality and doubles under a modest 3% increase of the $c/a$ ratio, suggesting that the magnetocrystalline anisotropy can be further enhanced using epitaxial or chemical strain.Comment: 4 pages + supplementary material, 6 figures. Accepted in Applied Physics Letter

Understanding the dynamics of photoionization-induced solitons in gas-filled hollow-core photonic crystal fibers

We present in detail our developed model [Saleh et al., Phys. Rev. Lett. 107] that governs pulse propagation in hollow-core photonic crystal fibers filled by an ionizing gas. By using perturbative methods, we find that the photoionization process induces the opposite phenomenon of the well-known Raman self-frequency red-shift of solitons in solid-core glass fibers, as was recently experimentally demonstrated [Hoelzer et al., Phys. Rev. Lett. 107]. This process is only limited by ionization losses, and leads to a constant acceleration of solitons in the time domain with a continuous blue-shift in the frequency domain. By applying the Gagnon-B\'{e}langer gauge transformation, multi-peak `inverted gravity-like' solitary waves are predicted. We also demonstrate that the pulse dynamics shows the ejection of solitons during propagation in such fibers, analogous to what happens in conventional solid-core fibers. Moreover, unconventional long-range non-local interactions between temporally distant solitons, unique of gas plasma systems, are predicted and studied. Finally, the effects of higher-order dispersion coefficients and the shock operator on the pulse dynamics are investigated, showing that the resonant radiation in the UV [Joly et al., Phys. Rev. Lett. 106] can be improved via plasma formation.Comment: 9 pages, 10 figure