Application of a simplified thermal-electric model of a sodium-nickel chloride battery energy storage system to a real case residential prosumer

Recently, power system customers have changed the way they interact with public networks, playing a more and more active role. End-users first installed local small-size generating units, and now they are being equipped with storage devices to increase the self-consumption rate. By suitably managing local resources, the provision of ancillary services and aggregations among several end-users are expected evolutions in the near future. In the upcoming market of household-sized storage devices, sodium-nickel chloride technology seems to be an interesting alternative to lead-acid and lithium-ion batteries. To accurately investigate the operation of the NaNiCl2 battery system at the residential level, a suitable thermoelectric model has been developed by the authors, starting from the results of laboratory tests. The behavior of the battery internal temperature has been characterized. Then, the designed model has been used to evaluate the economic profitability in installing a storage system in the case that end-users are already equipped with a photovoltaic unit. To obtain realistic results, real field measurements of customer consumption and solar radiation have been considered. A concrete interest in adopting the sodium-nickel chloride technology at the residential level is confirmed, taking into account the achievable benefits in terms of economic income, back-up supply, and increased indifference to the evolution of the electricity market

Further Cost Reduction of Battery Manufacturing

The demand for batteries for energy storage is growing with the rapid increase in photovoltaics (PV) and wind energy installation as well as electric vehicle (EV), hybrid electric vehicle (HEV) and plug-in hybrid electric vehicle (PHEV). Electrochemical batteries have emerged as the preferred choice for most of the consumer product applications. Cost reduction of batteries will accelerate the growth in all of these sectors. Lithium-ion (Li-ion) and solid-state batteries are showing promise through their downward price and upward performance trends. We may achieve further performance improvement and cost reduction for Li-ion and solid-state batteries through reduction of the variation in physical and electrical properties. These properties can be improved and made uniform by considering the electrical model of batteries and adopting novel manufacturing approaches. Using quantum-photo effect, the incorporation of ultra-violet (UV) assisted photo-thermal processing can reduce metal surface roughness. Using in-situ measurements, advanced process control (APC) can help ensure uniformity among the constituent electrochemical cells. Industrial internet of things (IIoT) can streamline the production flow. In this article, we have examined the issue of electrochemical battery manufacturing of Li-ion and solid-state type from cell-level to battery-level process variability, and proposed potential areas where improvements in the manufacturing process can be made. By incorporating these practices in the manufacturing process we expect reduced cost of energy management system, improved reliability and yield gain with the net saving of manufacturing cost being at least 20%

An examination of thermal features' relevance in the task of battery-fault detection

Uninterruptible power supplies (UPS), represented by lead-acid batteries, play an important role in various kinds of industries. They protect industrial technologies from being damaged by dangerous interruptions of an electric power supply. Advanced UPS monitoring performed by a complex battery management system (BMS) prevents the UPS from sustaining more serious damage due to its timely and accurate battery-fault detection based on voltage metering. This technique is very advanced and precise but also very expensive on a long-term basis. This article describes an experiment applying infrared thermographic measurements during a long term monitoring and fault detection in UPS. The assumption that the battery overheat implies its damaged state is the leading factor of our experiments. They are based on real measured data on various UPS battery sets and several statistical examinations confirming the high relevancy of the thermal features with mostly over 90% detection accuracy. Such a model can be used as a supplement for lead-acid battery based UPS monitoring to ensure their higher reliability under significantly lower maintenance costs.Web of Science82art. no. 18

Techno-Economic Analysis and Optimal Control of Battery Storage for Frequency Control Services, Applied to the German Market

Optimal investment in battery energy storage systems, taking into account degradation, sizing and control, is crucial for the deployment of battery storage, of which providing frequency control is one of the major applications. In this paper, we present a holistic, data-driven framework to determine the optimal investment, size and controller of a battery storage system providing frequency control. We optimised the controller towards minimum degradation and electricity costs over its lifetime, while ensuring the delivery of frequency control services compliant with regulatory requirements. We adopted a detailed battery model, considering the dynamics and degradation when exposed to actual frequency data. Further, we used a stochastic optimisation objective while constraining the probability on unavailability to deliver the frequency control service. Through a thorough analysis, we were able to decrease the amount of data needed and thereby decrease the execution time while keeping the approximation error within limits. Using the proposed framework, we performed a techno-economic analysis of a battery providing 1 MW capacity in the German primary frequency control market. Results showed that a battery rated at 1.6 MW, 1.6 MWh has the highest net present value, yet this configuration is only profitable if costs are low enough or in case future frequency control prices do not decline too much. It transpires that calendar ageing drives battery degradation, whereas cycle ageing has less impact.Comment: Submitted to Applied Energ

Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V

LiCoO2 is a dominant cathode material for lithium-ion (Li-ion) batteries due to its high volumetric energy density, which could potentially be further improved by charging to high voltages. However, practical adoption of high-voltage charging is hindered by LiCoO2’s structural instability at the deeply delithiated state and the associated safety concerns. Here, we achieve stable cycling of LiCoO2 at 4.6 V (versus Li/Li+) through trace Ti–Mg–Al co-doping. Using state-of-the-art synchrotron X-ray imaging and spectroscopic techniques, we report the incorporation of Mg and Al into the LiCoO2 lattice, which inhibits the undesired phase transition at voltages above 4.5 V. We also show that, even in trace amounts, Ti segregates significantly at grain boundaries and on the surface, modifying the microstructure of the particles while stabilizing the surface oxygen at high voltages. These dopants contribute through different mechanisms and synergistically promote the cycle stability of LiCoO2 at 4.6 V

Systematic approach for the test data generation and validation of ISC/ ESC detection methods

Various methods published in recent years for reliable detection of battery faults (mainly internal short circuit (ISC)) raise the question of comparability and cross-method evaluation, which cannot yet be answered due to significant differences in training data and boundary conditions. This paper provides a Monte Carlo-like simulation approach to generate a reproducible, comprehensible and large dataset based on an extensive literature background on common assumptions and simulation parameters. In some cases, these assumptions are quite different from field data, as shown by comparison with experimentally determined values. Two relatively simple ISC detection methods are tested on the generated dataset and their performance is evaluated to illustrate the proposed approach. The evaluation of the detection performance by quantitative measures such as the Youden-index shows a high divergence with respect to internal and external parameters such as threshold level and cell-to-cell variations (CtCV), respectively. These results underline the importance of quantitative evaluations based on identical test data. The proposed approach is able to support this task by providing cost-effective test data generation with incorporation of known factors affecting detection quality

Data-driven nonparametric Li-ion battery ageing model aiming at learning from real operation data - Part B : cycling operation

Conventional Li-ion battery ageing models, such as electrochemical, semi-empirical and empirical models, require a significant amount of time and experimental resources to provide accurate predictions under realistic operating conditions. At the same time, there is significant interest from industry in the introduction of new data collection telemetry technology. This implies the forthcoming availability of a significant amount of real-world battery operation data. In this context, the development of ageing models able to learn from in-field battery operation data is an interesting solution to mitigate the need for exhaustive laboratory testing. In a series of two papers, a data-driven ageing model is developed for Li-ion batteries under the Gaussian Process framework. A special emphasis is placed on illustrating the ability of the Gaussian Process model to learn from new data observations, providing more accurate and confident predictions, and extending the operating window of the model. The first paper of the series focussed on the systematic modelling and experimental verification of cell degradation through calendar ageing. Conversantly, this second paper addresses the same research challenge when the cell is electrically cycled. A specific covariance function is composed, tailored for use in a battery ageing application. Over an extensive dataset involving 124 cells tested during more than three years, different training possibilities are contemplated in order to quantify the minimal number of laboratory tests required for the design of an accurate ageing model. A model trained with only 26 tested cells achieves an overall mean-absolute-error of 1.04% in the capacity curve prediction, after being validated under a broad window of both dynamic and static cycling temperatures, Depth-of-Discharge, middle-SOC, charging and discharging C-rates