Doctor of Philosophy

dissertationThe ichnology and mineralogy of selected occurrences of trace fossils and green minerals in verdine and glaucony facies were investigated, and the nature and significance of their association were evaluated. Trace fossils and green marine clays commonly occur together and are genetically related. At each site fecal pellets in marine shelf sediments were determined to be the most likely precursor of the green minerals. Fecal pellets, which are common on shelf sea floor, are organic rich, and they provide microenvironments of reduction for green mineral authigenesis, which promotes the formation of glauconitic pellets or odinite-rich pellets depending upon the paleoenvironmental conditions. Fecal pellets in intensely burrowed sediment represent a direct link between ichnology and green mineral authigenesis. Five Phanerozoic sites representing terrigenous marine shelf deposits were examined: the Middle Eocene Crockett Formation in eastern Texas; two Cambrian sites including the Reno Member, Lone Rock Formation in southern Wisconsin and the Lion Mountain Member, Upper Riley Formation in central Texas; and two Mesozoic sites including the Jurassic Curtis Formation in central Utah and the Cretaceous Shannon Sandstone in central Wyoming. All sites represent times during the geologic past when global temperature was abnormally high. The verdine facies, dominated by odinite-rich pellets, was identified in the "Main Glauconite Bed" (MGB) of the Crocket Formation. Odinite in the modern sea floor is confined to tropical latitudes, and its association with trace fossils made by shallow marine animals suggests a shallower and more tropical paleoenvironment during the Middle Eocene than was previously recognized. Glauconitic pellets were found at all the other sites, where sedimentologic characteristics, stratigraphic occurrence, ichnofabric, and trace fossil assemblages indicate a multistage, reworked depositional history. The story of sea level dynamics unfolds where glauconitic minerals indicate elevated sea level during a marine transgression. Subsequently, quartz grains and shallow-marine burrows indicate an interval of regression. Finally, shallow shifting-sand substrate occupied by burrowing organisms indicates adaptation for life in water too shallow for glauconitic mineral authigenesis. These findings document the paleoenvironment of the marine shelf during times of fluctuating sea level and warm paleoclimate

Form and formation of flares and parabolae based on new observations of the internal shell structure in lytoceratid and perisphinctid ammonoids

The ultrastructure of pristine shells of Jurassic and Cretaceous lytoceratid and perisphinctid ammonoids indicates that flares and parabolae represent homologous structures. Both mark an interruption of shell growth. We dismiss earlier interpretations of parabolae as actual aperture, relics of resorbed apophyses or superstructure of the musculature associated to a semi-internal shell. Instead we propose an episodic growth model including several growth stops at the aperture during the formation of a frill-like aperture for parabolae and flares. Such an aperture is composed of the outer prismatic layer, the nacreous layer and an apertural prismatic coating. Here, we observed the apertural prismatic coating for the first time as an integral part of flares and parabolae. The apertural prismatic coating covers only the inner surface of the frill and was secreted by a permanent mantle cover indicating a prolonged period without the production of new shell material. Parabolae differ from flares by their general shape and the presence of ventro-lateral parabolic notches and nodes. The notches were formed by folding of the frill and had the potential to form semi-open spines. The corresponding parabolic nodes are caused by an outward swelling of the shell-secreting mantle tissue producing new shell material at the position of the folding. New shell material that belongs to the conch tube is attached to the base of flares and parabolae after withdrawal of the mantle edge representing the continuation of shell growth. Usually, the frilled aperture associated with flares and parabolae were removed during lifetime. This study reports on flares in Argonauticeras for the first time. In this genus they are typically associated with varices

Taphonomy of a Mysticeti whale in the Lower Pliocene Huelva Sands Formation (Southern Spain)

This paper reports the occurrence of an incomplete fossil baleen whale skeleton in the Lower Pliocene Huelva Sands Formation (Guadalquivir basin) near the town of Bonares, southwestern Spain. The skeleton was found in the highly bioturbated glauconitic sandstone unit in association with Neopycnodonte cochlear shells. Several morphological features of the mandibles, scapula and vertebrae suggest that the specimen belongs in the suborden Mysticeti, family Balaenopteridae. Most bones show abrasion due to a long exposure on the seafloor, and some bones show shark tooth marks and both micro- and macro-bioerosion by scavengers. The position of the bones suggests that the carcass landed on the seafloor on its left side and then turned right side up. Sedimentological and paleontological features indicate that the whale was buried in shallow platform waters under low sedimentation rates

Geological notes and local details for 1:10000 sheets TQ01NW, NE, SW and SE: Pulborough and Storrington: part of 1:50000 Sheet 317 (Chichester)

This report describes the geology of 1:10 000 geological sheets TQ 01 NW, NE SW and SE, which cover the country around Pulborough and Storrington, in Sussex. The area falls within the 1:50 000 Chichester (317) Geological Sheet. It was first surveyed on the 'one-inch' scale by H.W. Bristow and F. Drew as part of Old Series One-inch Geological Sheet 9, published in 1864. The descriptive memoir covering this and adjacent sheets was compiled by W. Topley and published in 1875. The area was resurveyed on the 'six-inch scale by Clement Reid in 1890 and G.W. Lamplugh in 1899-1900~and formed part of the New Series 'One-inch' Geological Sheet 317, published in 1902. A descriptive memoir by Clement Reid appeared in 1903

Proceedings of the USDA-ARS workshop "Real world" infiltration

Compiled and edited by L.R. Ahuja and Amy Garrison.Includes bibliographical references.Proceedings of the 1996 workshop held on July 22-25, 1996 in Pingree Park, Colorado

False Bakken interval- sediment patterns and depositional architecture at the facies boundary between siliciclastic mudstones and carbonates, Lodgepole Formation, Mississippian in the Williston Basin, ND

2020 Spring.Includes bibliographical references.The lateral facies transition on deep shelves between carbonates and siliciclastic mudstones is largely enigmatic. Based on detailed facies descriptions and interpretations, this study explores which processes have shaped the sedimentary rocks on both sides of this lithological divide, and adds to our understanding of processes operating on deep shelves in general. Both siliciclastic and carbonate rocks of the 'False Bakken' and 'Scallion' intervals of the lower Lodgepole Formation in the Williston Basin, ND, can be grouped into twelve facies: these facies are graded argillaceous mudstone (F1), massive siliciclastic-argillaceous mudstone (F2a), massive calcareous-argillaceous mudstone (F2b), bioturbated pyrtitized bioclast-bearing mudstone (F3), lenticular mudstone (F4), bioclast-rich wavy mudstone (F5), siliciclastic siltstone (F6), glauconitic siltstone (F7), calcareous siltstone (F8), massive to bioturbated carbonate mudstone (F9), nodular skeletal wackestone (F10), and laminated skeletal packstone (F11). These facies are here presented in order of increasing grain size, carbonate content, and bioturbation from F1 to F11. They are arranged in three fining- and coarsening-upward units that can be identified throughout the basin within the succession. These twelve facies are interpreted to represent distinct processes on a low-inclined shelf system with carbonate occupying the proximal, and siliciclastic mudstones the distal portions of this transect. An overall decrease in energy is reflected from the proximal carbonate to distal siliciclastic facies in this sedimentary system. Nevertheless, most of the mudstone facies still reflect high energy processes operating within the distal portions of the basin; in fact, only one mudstone facies is interpreted to reflect suspension settling under tranquil conditions. Therefore, this study suggests that storm wave base is best placed within the distal siliciclastic mudstones instead of in the proximal carbonates. Carbonate mudstones, deposited above storm wave base but lacking tempestite deposition are therefore interpreted as having been subject to intense degradation of storm-derived bioclasts. A decrease in oxygen concentration is inferred from proximal carbonates to distal siliciclastics as indicated by the decrease in size and type of burrows; yet, the presence of burrows within the most distal facies belt indicates that at least dysoxic conditions prevailed throughout the Williston Basin during the deposition of the 'False Bakken'. Three transgressions and regressions are identified within this succession based on laterally correlated facies patterns and indicate an overall increase in sea level from the beginning to the end of 'False Bakken' times. Sediment starvation occurred in the northeastern and/or southwestern portions of the basin as indicated by the presence of glauconitic siltstones and/or lenticular mudstones at various locations within the succession. However, a source of sediment input is interpreted to be located in the northwestern part of the basin based on a high abundance of detrital silt. In addition, a shift in the basin depocenter southwards from Bakken to lower Lodgepole times is reflected in this succession most likely mirroring an increase in subsidence south of Mountrail County during 'False Bakken' deposition

Nature, Distribution, Origin and Economics of Glauconite in Carbonate-Phosphate-Glauconite Surficial Deposits on Central Chatham Rise, Southwest Pacific

Chatham Rise is a broad, elongated submarine platform that extends 1100 km out into the Southwest Pacific off eastern South Island. The surficial sediments on the central portion of the Rise at depths of 200-500 m include significant concentrations of the mineral glauconite (10-80 wt%) associated with skeletal carbonate, fine terrigenous material and locally abundant phosphatic nodules. This is the first study to fully analyse the nature, origin and economic potential of the glauconite component. Sub-bottom 3.5 kHz profiles have established the distribution, geometry and thickness (10-200 cm) of the surficial deposits, which overlie partially indurated Oligocene chalk of probable Whaingaroan age (~34-27 Ma). 137 grab, dredge or piston core samples have been analysed for their texture, mineralogy and geochemistry, which has produced a new surficial sediment map for the central Chatham Rise. Glauconite most commonly occurs as dark green to black, very fine to fine sand-sized (0.2 mm), polished ovoidal and lobate pellets, and less commonly as infills within foraminiferal tests or as variably replaced rock fragments and phosphatic clasts. Full physical analysis reveals seven morphological types of glauconite including, in order of decreasing abundance, ovoidal, lobate, composite, internal molds, fossil casts, pigmentary, tabular and pellets within rock fragments. Their internal fabrics are dominated by random microcrystalline varieties with some oriented fibroradiating rim and skeletal infill types. Other notable features of some glauconite pellets include their expansion cracks, opaque inclusions and variable degrees of limonitisation. XRF/XRD analyses reveal mainly diagenetically mature varieties having elevated K2O (7-9 wt%) and Fe2O3 (19-23 wt%) values, and a dominant 10Å glauconitic mica structure involving from 10-20% expandable smectite layers. K-Ar dates on pellets indicate a Late Miocene age (av. 5.75 Ma). This “old” age, as well as the clear evidence of reworking shown by the dominance of smooth polished ovoidal grains, mean that the central Chatham Rise glauconites are predominantly allogenic (i.e. derived/reworked), and neither strictly authigenic nor in situ, despite occurring in “modern” seafloor deposits. The formation of glauconite is linked to prominent upwelling within the Subtropical Front (STF) zone over the Rise in the Late Miocene, and the attendant heightened primary productivity, bacterial activity and nutrients associated with widespread biogenic blooms at that time. The source of the smectite required for glauconite formation could have been from the devitrification of volcanic ash from diverse eruptive centres, or through “neoformation”/authigenic precipitation within pore water solutions of carbonate-rich waters in the Oligocene/Miocene chalk substrate. Glauconite formation largely ceased after the Late Miocene due to an increase in terrigenous input, a reduced smectite source, and a major period of lowered sea level associated with Antarctic ice sheet growth. The “modern” Chatham glauconite pellets were sourced from submarine erosion of the former Late Miocene sediments and have been dispersed by intensified bottom current circulation at times of lowered sea level within the complex STF over Chatham Rise, and possibly ice scouring. Effectively there exists a widespread “Chatham unconformity” (mid-Oligocene to Recent) which cuts out most of the last 30 myr of the sedimentary record on central Chatham Rise, except for the highly condensed surficial deposits whose glauconite grains formed 5-6 Ma, in the Late Miocene. This long-lasting “Chatham unconformity” is a greatly extended version of the well documented Oligocene Marshall Paraconformity. The thickness of the surficial sediment cover on central Chatham Rise ranges from 0.06-1.35 m. By using a conservative estimate of 0.5 m thick, and the wt% of glauconite within the sediment cover, a resource estimate of the glauconite has been made for various areas. In the most glauconite-rich area (>50 wt% glauconite) in the vicinity of Reserve Bank in 200-300 m water depths, which has an aerial extend of 4,500 km2, the glauconite resource amounts to about 2 Bt. The Chatham Rise glauconites have substantial economic potential as a potash fertiliser in support of the strong agricultural-based economy of New Zealand. Glauconite is widespread in many Late Cretaceous-Cenozoic sedimentary deposits in the New Zealand rock record and the Chatham Rise occurrences provide a useful uniformitarian analogue for at least some of these