Effect of hydrogen-diesel fuel co-combustion on exhaust emissions with verification using an in–cylinder gas sampling technique

AbstractThe paper presents an experimental investigation of hydrogen-diesel fuel co-combustion carried out on a naturally aspirated, direct injection diesel engine. The engine was supplied with a range of hydrogen-diesel fuel mixture proportions to study the effect of hydrogen addition (aspirated with the intake air) on combustion and exhaust emissions. The tests were performed at fixed diesel injection periods, with hydrogen added to vary the engine load between 0 and 6 bar IMEP. In addition, a novel in–cylinder gas sampling technique was employed to measure species concentrations in the engine cylinder at two in–cylinder locations and at various instants during the combustion process.The results showed a decrease in the particulates, CO and THC emissions and a slight increase in CO2 emissions with the addition of hydrogen, with fixed diesel fuel injection periods. NOx emissions increased steeply with hydrogen addition but only when the combined diesel and hydrogen co-combustion temperatures exceeded the threshold temperature for NOx formation. The in–cylinder gas sampling results showed higher NOx levels between adjacent spray cones, in comparison to sampling within an individual spray cone

Influence of Fuel Bound Oxygen on Soot Mass and Polyaromatic Hydrocarbons during Pyrolysis of Ethanol, Methyl Acetate, Acetone and Diethyl Ether

Air pollution has reached critical levels in many major industrial cities, endangering public health, deteriorating the environment, and causing harm to property and landscape. The particulate emissions (PM) from propulsion which contribute to air pollution vary greatly in size and composition, conveying carcinogenic polyaromatic hydrocarbons (PAHs) present on the particle surface. Although it has been found that replacing fossil fuels with renewable oxygen-bearing fuels reduces the mass of PM released, not much is known on how this change in fuel composition affects soot levels, PAH production, and toxicity during the pyrolysis processes that occur in combustion engines. Biofuels such as alcohols, esters, ethers, and ketones are considered to be potentially sustainable alternatives fuels and can be produced by various biological and thermochemical processes from a range of renewable feedstocks. The effects of these oxygenated functional groups on the soot mass and PAHs produced during pyrolysis in a laminar flow reactor were investigated quantitatively in this study. The 16 PAHs identified as priority pollutants by the US Environmental Protection Agency (EPA) were investigated in this research, with particular focus on the probable mechanisms for production of the most carcinogenic PAHs (group B). The oxygenated fuels were pyrolyzed at temperatures ranging from 1050 to 1350 0C under oxygenfree conditions with a constant carbon atom content in nitrogen of 10,000 ppm and at a consistent residence period. Both soot bound PAH collected on filter papers and gaseous PAHs collected on XAD resin were extracted using accelerated solvent extraction (ASE), with PAH identification and quantification carried out using gas chromatography combined with mass spectroscopy (GCMS). An effect of the oxygenated functional groups on soot mass was readily apparent, with consistently lower production of soot by methyl acetate, and which has a higher oxygen to carbon ratio than ethanol, acetone, and diethyl ether. At all temperatures except 1350 0C, methyl acetate pyrolysis yielded much lower GP PAH levels than acetone and diethyl ether, but somewhat higher than that from ethanol pyrolysis. The concentration of PP PAH per unit volume of gas is much lower than the corresponding GP PAH, which suggests that PP PAH that condensed onto particulate surface, subsequently experienced surface reaction and were therefore not recoverable during the extraction process. The production of pyrene via acenaphthylene was found to dominate at higher temperatures for all fuels, regardless of molecular structure. At 11500C the relative abundance of the soot particles was low, however, the toxicity of the soot particles formed was substantially higher at lower temperatures, particularly in the case of pyrolysis of methyl acetate soot

Sampling of Gas-Phase Intermediate Pyrolytic Species at Various Temperatures and Residence Times during Pyrolysis of Methane, Ethane, and Butane in a High-Temperature Flow Reactor

Air pollution in many major cities is endangering public health and is causing deterioration of the environment. Particulate emissions (PM) contribute to air pollution as they carry toxic polyaromatic hydrocarbons (PAHs) on their surface. Abatement of PM requires continuous strict emission regulation and, in parallel, the development of fuels with reduced formation of PM. Key processes in the formation of PM are the decomposition of hydrocarbon fuels and the synthesis of potential precursors that lead to the formation of benzene rings and thereafter growth to PAHs and eventually PM. Methane, ethane and butane are important components of natural gas and liquefied petroleum gas, and are also widely used in transportation, industrial processes and power generation. This paper reports on a quantitative investigation of the intermediate gaseous species present during pyrolysis of methane, ethane and butane in a laminar flow reactor. The investigation aimed to further the understanding of the decomposition process of these fuels and the subsequent formation of aromatic rings. The pyrolysis of methane, ethane and butane were carried out in a tube reactor under laminar flow conditions and within a temperature range of 869–1213 °C. The fuels were premixed in nitrogen carrier gas at a fixed carbon atom concentration of 10,000 ppm, and were pyrolysed under oxygen-free conditions. Intermediate gaseous species were collected from within the tube reactor at different residence times using a specially designed high-temperature ceramic sampling probe with arrangements to quench and freeze the reactions at entry to the probe. Identification and quantification of intermediate species were carried out using a gas chromatography-flame ionization detector (GC-FID). During methane pyrolysis, it was observed that as the concentration of acetylene increased, the concentration of benzene also increased, suggesting that the benzene ring is formed via the cyclo trimerisation of acetylene. With all three fuels, all intermediate species disappeared at higher temperatures and residence times, suggesting that those species converted into species higher than benzene, for example naphthalene. It was observed that increasing carbon chain length lowered the temperature at which fuel breakdown occurred and also affected the relative abundance of intermediate species

Hydrogen-diesel fuel co-combustion strategies in light duty and heavy duty CI engines

The co-combustion of diesel fuel with H 2 presents a promising route to reduce the adverse effects of diesel engine exhaust pollutants on the environment and human health. This paper presents the results of H 2 -diesel co-combustion experiments carried out on two different research facilities, a light duty and a heavy duty diesel engine. For both engines, H 2 was supplied to the engine intake manifold and aspirated with the intake air. H 2 concentrations of up to 20% vol/vol and 8% vol/vol were tested in the light duty and heavy duty engines respectively. Exhaust gas circulation (EGR) was also utilised for some of the tests to control exhaust NO x emissions. The results showed NO x emissions increase with increasing H 2 in the case of the light duty engine, however, in contrast, for the heavy duty engine NO x emissions were stable/reduced slightly with H 2 , attributable to lower in-cylinder gas temperatures during diffusion-controlled combustion. CO and particulate emissions were observed to reduce as the intake H 2 was increased. For the light duty, H 2 was observed to auto-ignite intermittently before diesel fuel injection had started, when the intake H 2 concentration was 20% vol/vol. A similar effect was observed in the heavy duty engine at just over 8% H 2 concentration

The influence of straight vegetable oil fatty acid composition on compression ignition combustion and emissions

This paper presents experimental studies carried out on a modern direct injection compression ignition engine supplied with a range of straight vegetable oils to investigate the effect of oil fatty acid composition on combustion and emissions. Seven oils, those of corn, groundnut, palm, rapeseed, soybean, sunflower and the micro-algae species Chlorella protothecoides were tested, with all of the fuels heated to 60°C, at constant injection timing and constant ignition timing at a constant engine speed of 1200 rpm. All of the vegetable oils exhibited a duration of ignition delay within ±0.6 CAD of that displayed by a reference fossil diesel, but displayed much reduced rates of peak heat release rate. The duration of ignition delay was found to increase with an increasing carbon to hydrogen ratio of the vegetable oils, implicating the fatty acid alkyl chain as the primary driver of low temperature reactivity. Peak heat release rates decreased with decreasing vegetable oil viscosity, suggesting a significant degree of fuel cylinder wall and piston bowl impingement. At both injection timings, emissions of NOx were lower for all of the vegetable oils relative to the reference fossil diesel, while those of CO, THC and particulate matter were higher and sensitive to the injection timing

A High Stellar Obliquity in the WASP-7 Exoplanetary System

We measure a tilt of 86+-6 deg between the sky projections of the rotation axis of the WASP-7 star, and the orbital axis of its close-in giant planet. This measurement is based on observations of the Rossiter-McLaughlin (RM) effect with the Planet Finder Spectrograph on the Magellan II telescope. The result conforms with the previously noted pattern among hot-Jupiter hosts, namely, that the hosts lacking thick convective envelopes have high obliquities. Because the planet's trajectory crosses a wide range of stellar latitudes, observations of the RM effect can in principle reveal the stellar differential rotation profile; however, with the present data the signal of differential rotation could not be detected. The host star is found to exhibit radial-velocity noise (``stellar jitter') with an amplitude of ~30m/s over a timescale of days.Comment: ApJ accepted, 9 pages, 9 figure

Image guidance in neurosurgical procedures, the "Visages" point of view.

This paper gives an overview of the evolution of clinical neuroinformatics in the domain of neurosurgery. It shows how image guided neurosurgery (IGNS) is evolving according to the integration of new imaging modalities before, during and after the surgical procedure and how this acts as the premise of the Operative Room of the future. These different issues, as addressed by the VisAGeS INRIA/INSERM U746 research team (http://www.irisa.fr/visages), are presented and discussed in order to exhibit the benefits of an integrated work between physicians (radiologists, neurologists and neurosurgeons) and computer scientists to give adequate answers toward a more effective use of images in IGNS

Algal biomass and diesel emulsions: An alternative approach for utilizing the energy content of microalgal biomass in diesel engines

The use of algal biomass for the production of sustainable biofuels has attracted significant interest due to the fast reproduction rates and high lipid content of many microalgal species. However, existing methods of extracting algal cellular lipids are complex and expensive, with regards to both energy input and economic costs. This work explores an alternative method of utilizing the energy content of microalgae through the preparation of wet algal biomass slurry/fossil diesel emulsions containing up to 6.6% wt/wt algae biomass, using a specific surfactant combination, for direct injection diesel engine combustion of microalgae without prior biomass drying or lipid extraction. A high lipid containing green microalgae, Chlorella sorokiniana, was used to produce algal biomass for the study. The preparation of wet algal slurry/diesel emulsions from algae grown under standard conditions, and also those under conditions intended to increase cellular lipid content or growth rates was investigated, and in all cases a surfactant pack of Span80, CTAB and butanol was found to produce a stable emulsion. A correlation between the engine work produced during combustion of the emulsions in a modern direct injection compression ignition and the lower heating value of the wet slurry emulsions was found, with no evidence of individual algae cells persisting to the engine exhaust. Engine exhaust emissions of nitrogen oxides (NOx) and particulate matter were lower for all of the wet algal slurry/diesel emulsions relative to a reference fossil diesel tested under similar conditions, while in the case of the emulsion prepared from algal biomass to which a flocculating agent had been added, emissions of carbon monoxide (CO) were found to increase significantly

The long-term evolution of the spin, pulse shape, and orbit of the accretion-powered millisecond pulsar SAX J1808.4-3658

We present a 7 yr timing study of the 2.5 ms X-ray pulsar SAX J1808.4-3658, an X-ray transient with a recurrence time of ~2 yr, using data from the Rossi X-ray Timing Explorer covering 4 transient outbursts (1998-2005). We verify that the 401 Hz pulsation traces the spin frequency fundamental and not a harmonic. Substantial pulse shape variability, both stochastic and systematic, was observed during each outburst. Analysis of the systematic pulse shape changes suggests that, as an outburst dims, the X-ray "hot spot" on the pulsar surface drifts longitudinally and a second hot spot may appear. The overall pulse shape variability limits the ability to measure spin frequency evolution within a given X-ray outburst (and calls previous nudot measurements of this source into question), with typical upper limits of |nudot| < 2.5x10^{-14} Hz/s (2 sigma). However, combining data from all the outbursts shows with high (6 sigma) significance that the pulsar is undergoing long-term spin down at a rate nudot = (-5.6+/-2.0)x10^{-16} Hz/s, with most of the spin evolution occurring during X-ray quiescence. We discuss the possible contributions of magnetic propeller torques, magnetic dipole radiation, and gravitational radiation to the measured spin down, setting an upper limit of B < 1.5x10^8 G for the pulsar's surface dipole magnetic field and and Q/I < 5x10^{-9} for the fractional mass quadrupole moment. We also measured an orbital period derivative of Pdot = (3.5+/-0.2)x10^{-12} s/s. This surprising large Pdot is reminiscent of the large and quasi-cyclic orbital period variation observed in the so-called "black widow" millisecond radio pulsars, supporting speculation that SAX J1808.4-3658 may turn on as a radio pulsar during quiescence. In an appendix we derive an improved (0.15 arcsec) source position from optical data.Comment: 22 pages, 10 figures; accepted for publication in Ap

New Measurements of Orbital Period Change in Cygnus X-3

A nonlinear nature of the binary ephemeris of Cygnus X-3 indicates either a change in the orbital period or an apsidal motion of the orbit. We have made extended observations of Cygnus X-3 with the Pointed Proportional Counters (PPCs) of the Indian X-ray Astronomy Experiment (IXAE) during 1999 July 3-13 and October 11-14. Using the data from these observations and the archival data from ROSAT, ASCA, BeppoSAX and RXTE, we have extended the data base for this source. Adding these new arrival time measurements to the published results, we make a comparison between the various possibilities, (a) orbital decay due to mass loss from the system, (b) mass transfer between the stars, and (c) apsidal motion of the orbit due to gravitational interaction between the two components. Orbital decay due to mass loss from the companion star seems to be the most probable scenario.Comment: 7 pages, 4 figures, accepted for publication in A&