Density functional theory of superconductivity in doped tungsten oxides

We apply density functional theory for superconductors (SCDFT) to doped tungsten oxide in three forms: electrostatically doped WO3, perovskite WO3−xFx, and hexagonal CsxWO3. We achieve a consistent picture in which the experimental superconducting transition temperature Tc is reproduced, and superconductivity is understood as a weak-coupling state sustained by soft vibrational modes of the WO6 octahedra. SCDFT simulations of CsxWO3 allow us to explain the anomalous Tc behavior observed in most tungsten bronzes, where Tc decreases with increasing carrier density. Here, the opening of structural channels to host Cs atoms induces a softening of strongly coupled W-O modes. By increasing the Cs content, these modes are screened and Tc is strongly reduced

Enthalpy and stagnation temperature determination of a high temperature laminar flow gas stream Patent

Measuring conductive heat flow and thermal conductivity of laminar gas stream in cylindrical plug to simulate atmospheric reentr

Mussel adhesive protein inspired coatings: a versatile method to fabricate silica films on various surfaces

A simple and versatile biomimetic strategy for the fabrication of silica films on a variety of substrates including gold, polystyrene and silicon wafers was developed using nanogram amounts per cm 2 of silicatein. The strategy exploits the adhesive property of 3,4-dihydroxyphenylalanine (DOPA) and a decapeptide (Ala-Lys-Pro-Ser-Tyr-DHP-Hyp-Thr-DOPA-Lys), important components of mussel adhesive proteins, to modify the surface of substrates. DOPA molecules polymerize to poly(DOPA) and the decapeptide forms thin films on gold substrates at pH 8.5, rendering the substrate compatible for silicatein immobilization. Nearly 50 ng cm 2 of silicatein is immobilized on poly(DOPA) and decapeptide coated surfaces where these polymer films act as "cushion" to protect the active structure and maintain the activity of the largely chemically adsorbed silicatein at ca. 95% of that experienced in solution. Uniform silica films of thickness 130-140 nm and roughness 12-14.5 nm were fabricated on coated gold surfaces. Evidence to show that this method is also applicable for the fabrication of uniform silica films on polystyrene and silicon substrates over multiple length scales in an economical way is also presented

Low energy spin dynamics in the antiferromagnetic phase of CaFe2As2

We present 75As nuclear magnetic resonance data in the paramagnetic and magnetic states of single crystal CaFe2As2. The electric field gradient and the internal magnetic field at the As sites change discontinuously below the first order structural transition at T0 = 169 K. In the magnetic state, we find a single value of the internal hyperfine field consistent with commensurate antiferromagnetic order of Fe moments pointing in the ab plane. The spin lattice relaxation rate shows Korringa behavior for T<T0/3, reflecting the metallic nature of the ordered state. Surprisingly, 1/T1 exhibits a small peak at 10 K, revealing the presence of slow spin fluctuations that may be associated with domain wall motion.Comment: 11 pages, 8 figure

Role of Coulomb interaction in the superconducting properties of CaC6 and H under pressure

Superconductivity in intercalated graphite CaC6 and H under extreme pressure, in the framework of superconducting density functional theory, is discussed. A detailed analysis on how the electron-phonon and electron-electron interactions combine together to determine the superconducting gap and critical temperature of these systems is presented. In particular, we discuss the effect on the calculated Tc of the anisotropy of the electron-phonon interaction and of the different approximations for screening the Coulomb repulsion. These results contribute to the understanding of multigap and anisotropic superconductivity, which has received a lot of attention since the discovery of MgB2, and show how it is possible to describe the superconducting properties of real materials on a fully ab-initio basis.Comment: 13 pages, 5 figure

A genome-wide identification and comparative analysis of the lentil MLO genes

Revista electrónica on linePowdery mildew is a widespread fungal plant disease that can cause significant losses in many crops. Some MLO genes (Mildew resistance locus O) have proved to confer a durable resistance to powdery mildew in several species. Resistance granted by the MLO gene family members has prompted an increasing interest in characterizing these genes and implementing their use in plant breeding. Lentil (Lens culinaris Medik.) is a widely grown food legume almost exclusively consumed as dry seed with an average world production of 4.5 million tons. Powdery mildew causes severe losses on certain lentil cultivars under particular environmental conditions. Data mining of the lentil CDC Redberry draft genome allowed to identify up to 15 gene sequences with homology to known MLO genes, designated as LcMLOs. Further characterization of these gene sequences and their deduced protein sequences demonstrated conformity with key MLO protein characteristics such as the presence of transmembrane and calmodulin binding domains, as well as that of other conserved motifs. Phylogenetic and other comparative analyses revealed that LcMLO1 and LcMLO3 are the most likely gene orthologs related to powdery mildew response in other species, sharing a high similarity with other known resistance genes of dicot species, such as pea PsMLO1 and Medicago truncatula MtMLO1 and MtMLO3. Sets of primers were designed as tools to PCR amplify the genomic sequences of LcMLO1 and LcMLO3, also to screen lentil germplasm in search of resistance mutants. Primers were used to obtain the complete sequences of these two genes in all of the six wild lentil relatives. Respective to each gene, all Lens sequences shared a high similarity. Likewise, we used these primers to screen a working collection of 58 cultivated and 23 wild lentil accessions in search of length polymorphisms present in these two genes. All these data widen the insights on this gene family and can be useful for breeding programs in lentil and close related species.S

A review of the phytochemical support for the shifting defence hypothesis

Several theories have been developed to explain why invasive species are very successful and develop into pest species in their new area. The shifting defence hypothesis (SDH) argues that invasive plant species quickly evolve towards new defence levels in the invaded area because they lack their specialist herbivores but are still under attack by local (new) generalist herbivores. The SDH predicts that plants should increase their cheap, toxic defence compounds and lower their expensive digestibility reducing compounds. As a net result resources are saved that can be allocated to growth and reproduction giving these plants a competitive edge over the local plant species. We conducted a literature study to test whether toxic defence compounds in general are increased in the invaded area and if digestibility reducing compounds are lowered. We specifically studied the levels of pyrrolizidine alkaloids, a toxin which is known for its beneficial and detrimental impact against specialists and generalists, respectively. Digestibility reducers did not show a clear trend which might be due to the small number of studies and traits measured. The meta analysis showed that toxic compounds in general and pyrrolizidine alkaloid levels specifically, increased significantly in the invaded area, supporting the predictions of the SDH that a fast evolution takes place in the allocation towards defence