90 research outputs found
Computational Strategy for Graphene: Insight from Odd Electrons Correlation
The correlation of odd electrons in graphene turns out to be significant so
that the species should be attributed to correlated ones. This finding
profoundly influences the computational strategy addressing it to
multireference computational schemes. Owing to serious problems related to the
schemes realization, a compromise can be suggested by using single-determinant
approaches based on either Hartree-Fock or Density-Functional theory in the
form of unrestricted open-shell presentation. Both computational schemes enable
to fix the electron correlation, while only the Hartree-Fock theory suggests a
set of quantities to be calculated that can quantitatively characterize the
electron correlation and be used for a quantitative description of such
graphene properties as magnetism, chemical reactivity, and mechanical response.
The paper presents concepts and algorithms of the unrestricted Hartree-Fock
theory applied for the consideration of magnetic properties of nanographenes,
their chemical modification by the example of stepwise hydrogenation, as well
as a possible governing the electron correlation by the carbon skeleton
deformation.Comment: 17 pages, 11 figures, 3 table
Step-Wise Computational Synthesis of Fullerene C60 derivatives. 1.Fluorinated Fullerenes C60F2k
The reactions of fullerene C60 with atomic fluorine have been studied by
unrestricted broken spin-symmetry Hartree-Fock (UBS HF) approach implemented in
semiempirical codes based on AM1 technique. The calculations were focused on a
sequential addition of fluorine atom to the fullerene cage following indication
of the cage atom highest chemical susceptibility that is calculated at each
step. The effectively-non-paired-electron concept of the fullerene atoms
chemical susceptibility lays the foundation of the suggested computational
synthesis. The obtained results are analyzed from energetic, symmetry, and the
composition abundance viewpoints. A good fitting of the data to experimental
findings proves a creative role of the suggested synthesis methodology.Comment: 33 pages, 11 figures, 2 tables, 2 chart
ΠΠΏΠΈΠ΄Π΅ΠΌΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠ°Ρ ΠΈ ΡΡΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠ°Ρ Ρ Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠ° Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΠΎΠΉ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠΈ Ρ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ ΠΏΠΎ ΠΏΡΠΈΠ·ΡΠ²Ρ Π² ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΠΉ ΠΏΠ΅ΡΠΈΠΎΠ΄. Π‘ΡΠ°Π²Π½ΠΈΡΠ΅Π»ΡΠ½Π°Ρ ΠΎΡΠ΅Π½ΠΊΠ° ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΡΡ Π²Π°ΠΊΡΠΈΠ½.
The purpose of the study is to analyze morbidity and to determine etiology of community-acquired pneumonia of conscripts, to examine the epidemiological effectiveness of pneumococcal conjugate and non-conjugate polysaccharide vaccines for the prevention of community-acquired pneumonia in soldiers.Materials and methods. The incidence of communityacquired pneumonia of conscripts in the period from 2008 to 2017 was examined. PCR diagnosis of samples sputum and smears from the pharynx of 694 patients with pneumonia of conscripts was carried out to detect fragments of DNA/RNA of 14 different pathogens. Epidemiologic efficacy of conjugated and non-conjugated pneumococcal vaccine was studied in groups from a total population of 1727 soldiers.Results. It is established that over the past 8 years, the incidence of community-acquired pneumonia of military conscripts decreased by 2.7 times. However, the level of morbidity achieved in 2017 (25.7 β°) is still very high compared to the incidence of contract soldiers (5.3 β°) and the population (4.2 β°).When determining the etiology of pneumonias in military conscripts by means of PCR diagnosis, the prevalence of S. pneumoniae and adenoviruses was established, the genetic material of which was detected in 56.3% and 35.9% of the examined samples, respectively. 56.1% of pneumonia had mixed, mainly viral-bacterial etiology.Among those who were vaccinated with pneumococcal conjugate vaccine, the incidence of community-acquired pneumonia was 4.5 times lower in the 5 β month follow β up period than in the comparison group (p < 0.001) (effectiveness was 77.7%), and among those who were vaccinated with non-conjugate polysaccharide vaccines it was 2.8 times lower (p < 0.001) (effectiveness was 64.3%).It was found that the use of pneumococcal conjugate vaccine in military teams formed a collective immunity that prevents the circulation of pneumococci and the development of diseases not only in vaccinated persons, but also in unvaccinated persons.Conclusion. Both types of pneumococcal vaccines β conjugate, first used in the military, and usually used non-conjugate polysaccharide vaccine, have shown high epidemiological effectiveness in the prevention of community-acquired pneumonia and can equally be recommended for vaccination of recruits a month before the call to military service and of young soldiers, not vaccinated before the call.Π¦Π΅Π»Ρ: Π°Π½Π°Π»ΠΈΠ· Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π΅ΠΌΠΎΡΡΠΈ ΠΈ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΠ΅ ΡΡΠΈΠΎΠ»ΠΎΠ³ΠΈΠΈ Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΠΎΠΉ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠΈ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΏΠΎ ΠΏΡΠΈΠ·ΡΠ²Ρ Π² ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΠΉ ΠΏΠ΅ΡΠΈΠΎΠ΄, ΠΎΡΠ΅Π½ΠΊΠ° ΡΠΏΠΈΠ΄Π΅ΠΌΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ 13-Π²Π°Π»Π΅Π½ΡΠ½ΠΎΠΉ ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΠΎΠΉ ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ Π²Π°ΠΊΡΠΈΠ½Ρ Π΄Π»Ρ ΠΏΡΠΎΡΠΈΠ»Π°ΠΊΡΠΈΠΊΠΈ Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΠΎΠΉ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠΈ Π² Π²ΠΎΠΈΠ½ΡΠΊΠΈΡ
ΠΊΠΎΠ»Π»Π΅ΠΊΡΠΈΠ²Π°Ρ
Π² ΡΡΠ°Π²Π½Π΅Π½ΠΈΠΈ Ρ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΡΡ Π½Π΅ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ
ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΡΡ
ΠΏΠΎΠ»ΠΈΡΠ°Ρ
Π°ΡΠΈΠ΄Π½ΡΡ
Π²Π°ΠΊΡΠΈΠ½.ΠΠ°ΡΠ΅ΡΠΈΠ°Π»Ρ ΠΈ ΠΌΠ΅ΡΠΎΠ΄Ρ: ΠΏΡΠΎΠ°Π½Π°Π»ΠΈΠ·ΠΈΡΠΎΠ²Π°Π½Ρ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π΅ΠΌΠΎΡΡΡ Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΠΎΠΉ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠ΅ΠΉ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΏΠΎ ΠΏΡΠΈΠ·ΡΠ²Ρ Π² ΠΏΠ΅ΡΠΈΠΎΠ΄ Ρ 2008 ΠΏΠΎ 2017 Π³. ΠΈ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΡ ΠΠ¦Π Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΠΈ ΠΏΡΠΎΠ± ΠΌΠΎΠΊΡΠΎΡΡ ΠΈ ΠΌΠ°Π·ΠΊΠΎΠ² ΠΈΠ· Π·Π΅Π²Π° 694 Π±ΠΎΠ»ΡΠ½ΡΡ
ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠ΅ΠΉ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΏΠΎ ΠΎΠ±Π½Π°ΡΡΠΆΠ΅Π½ΠΈΡ ΡΡΠ°Π³ΠΌΠ΅Π½ΡΠΎΠ² ΠΠΠ/Π ΠΠ 14 ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ
Π²ΠΎΠ·Π±ΡΠ΄ΠΈΡΠ΅Π»Π΅ΠΉ. ΠΡΠΎΠ²Π΅Π΄Π΅Π½Π° ΠΎΡΠ΅Π½ΠΊΠ° ΡΠΏΠΈΠ΄Π΅ΠΌΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΡΡ
ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΈ Π½Π΅ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ
ΠΏΠΎΠ»ΠΈΡΠ°Ρ
Π°ΡΠΈΠ΄Π½ΡΡ
Π²Π°ΠΊΡΠΈΠ½ Π² Π³ΡΡΠΏΠΏΠ°Ρ
Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΎΠ±ΡΠ΅ΠΉ ΡΠΈΡΠ»Π΅Π½Π½ΠΎΡΡΡΡ 1727 ΡΠ΅Π»ΠΎΠ²Π΅ΠΊ.Π Π΅Π·ΡΠ»ΡΡΠ°ΡΡ: ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ Π·Π° ΠΏΠΎΡΠ»Π΅Π΄Π½ΠΈΠ΅ Π²ΠΎΡΠ΅ΠΌΡ Π»Π΅Ρ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π΅ΠΌΠΎΡΡΡ Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΡΠΌΠΈ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΡΠΌΠΈ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΏΠΎ ΠΏΡΠΈΠ·ΡΠ²Ρ ΡΠ½ΠΈΠ·ΠΈΠ»Π°ΡΡ Π² 2,7 ΡΠ°Π·Π°. ΠΠ΄Π½Π°ΠΊΠΎ Π΄ΠΎΡΡΠΈΠ³Π½ΡΡΡΠΉ Π² 2017 Π³. ΡΡΠΎΠ²Π΅Π½Ρ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π΅ΠΌΠΎΡΡΠΈ (25,7 β°) Π²ΡΠ΅ Π΅ΡΠ΅ ΠΎΡΠ΅Π½Ρ Π²ΡΡΠΎΠΊ Π² ΡΡΠ°Π²Π½Π΅Π½ΠΈΠΈ Ρ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π΅ΠΌΠΎΡΡΡΡ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΏΠΎ ΠΊΠΎΠ½ΡΡΠ°ΠΊΡΡ (5,3 β°) ΠΈ Π½Π°ΡΠ΅Π»Π΅Π½ΠΈΡ (4,2 β°).ΠΡΠΈ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΠΈ ΡΡΠΈΠΎΠ»ΠΎΠ³ΠΈΠΈ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠΉ Ρ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΠΏΠΎ ΠΏΡΠΈΠ·ΡΠ²Ρ Ρ ΠΏΠΎΠΌΠΎΡΡΡ ΠΠ¦Π -Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΠΈ ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ ΠΏΡΠ΅Π²Π°Π»ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ S. pneumoniae ΠΈ Π°Π΄Π΅Π½ΠΎΠ²ΠΈΡΡΡΠΎΠ², Π³Π΅Π½Π΅ΡΠΈΡΠ΅ΡΠΊΠΈΠΉ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π» ΠΊΠΎΡΠΎΡΡΡ
Π±ΡΠ» ΠΎΠ±Π½Π°ΡΡΠΆΠ΅Π½ Π² 56,3% ΠΈ 35,9% ΠΎΠ±ΡΠ»Π΅Π΄ΠΎΠ²Π°Π½Π½ΡΡ
ΠΏΡΠΎΠ± ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²Π΅Π½Π½ΠΎ. 56,1% ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠΉ ΠΈΠΌΠ΅Π»ΠΈ ΡΠΌΠ΅ΡΠ°Π½Π½ΡΡ, Π² ΠΎΡΠ½ΠΎΠ²Π½ΠΎΠΌ Π²ΠΈΡΡΡΠ½ΠΎ-Π±Π°ΠΊΡΠ΅ΡΠΈΠ°Π»ΡΠ½ΡΡ ΡΡΠΈΠΎΠ»ΠΎΠ³ΠΈΡ.Π‘ΡΠ΅Π΄ΠΈ Π²Π°ΠΊΡΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ
ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΠΎΠΉ ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ Π²Π°ΠΊΡΠΈΠ½ΠΎΠΉ Π·Π° 5-ΠΌΠ΅ΡΡΡΠ½ΡΠΉ ΠΏΠ΅ΡΠΈΠΎΠ΄ Π½Π°Π±Π»ΡΠ΄Π΅Π½ΠΈΡ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π΅ΠΌΠΎΡΡΡ Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΠΎΠΉ ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠ΅ΠΉ Π±ΡΠ»Π° Π² 4,5 ΡΠ°Π·Π° ΠΌΠ΅Π½ΡΡΠ΅, ΡΠ΅ΠΌ Π² Π³ΡΡΠΏΠΏΠ΅ ΡΡΠ°Π²Π½Π΅Π½ΠΈΡ (Ρ < 0,001) (ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»Ρ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΡΠΎΡΡΠ°Π²ΠΈΠ» 77,7%), Π° ΡΡΠ΅Π΄ΠΈ Π²Π°ΠΊΡΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ
Π½Π΅ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΡΠΌΠΈ ΠΏΠΎΠ»ΠΈΡΠ°Ρ
Π°ΡΠΈΠ΄Π½ΡΠΌΠΈ Π²Π°ΠΊΡΠΈΠ½Π°ΠΌΠΈ β Π² 2,8 ΡΠ°Π·Π° ΠΌΠ΅Π½ΡΡΠ΅ (Ρ < 0,001) (ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»Ρ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ β 64,3%). Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ ΠΏΡΠΈ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠΈ ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΠΎΠΉ ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ Π²Π°ΠΊΡΠΈΠ½Ρ Π² ΠΊΠΎΠ»Π»Π΅ΠΊΡΠΈΠ²Π°Ρ
Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
ΡΠΎΡΠΌΠΈΡΡΠ΅ΡΡΡ ΠΊΠΎΠ»Π»Π΅ΠΊΡΠΈΠ²Π½ΡΠΉ ΠΈΠΌΠΌΡΠ½ΠΈΡΠ΅Ρ, ΠΏΡΠ΅ΠΏΡΡΡΡΠ²ΡΡΡΠΈΠΉ ΡΠΈΡΠΊΡΠ»ΡΡΠΈΠΈ ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ² ΠΈ ΡΠ°Π·Π²ΠΈΡΠΈΡ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΠΉ Π½Π΅ ΡΠΎΠ»ΡΠΊΠΎ Ρ ΠΏΡΠΈΠ²ΠΈΡΡΡ
, Π½ΠΎ ΠΈ Ρ Π½Π΅ΠΏΡΠΈΠ²ΠΈΡΡΡ
.ΠΠ°ΠΊΠ»ΡΡΠ΅Π½ΠΈΠ΅: ΠΎΠ±Π° ΡΠΈΠΏΠ° ΠΏΠ½Π΅Π²ΠΌΠΎΠΊΠΎΠΊΠΊΠΎΠ²ΡΡ
Π²Π°ΠΊΡΠΈΠ½ β ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½Π°Ρ, Π²ΠΏΠ΅ΡΠ²ΡΠ΅ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½Π½Π°Ρ Ρ Π²ΠΎΠ΅Π½Π½ΠΎΡΠ»ΡΠΆΠ°ΡΠΈΡ
, ΠΈ ΠΎΠ±ΡΡΠ½ΠΎ ΠΏΡΠΈΠΌΠ΅Π½ΡΠ΅ΠΌΠ°Ρ Π½Π΅ΠΊΠΎΠ½ΡΡΠ³ΠΈΡΠΎΠ²Π°Π½Π½Π°Ρ ΠΏΠΎΠ»ΠΈΡΠ°Ρ
Π°ΡΠΈΠ΄Π½Π°Ρ Π²Π°ΠΊΡΠΈΠ½Π° β ΠΏΠΎΠΊΠ°Π·Π°Π»ΠΈ Π²ΡΡΠΎΠΊΡΡ ΡΠΏΠΈΠ΄Π΅ΠΌΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΡΡ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ Π² ΠΎΡΠ½ΠΎΡΠ΅Π½ΠΈΠΈ ΠΏΡΠΎΡΠΈΠ»Π°ΠΊΡΠΈΠΊΠΈ Π²Π½Π΅Π±ΠΎΠ»ΡΠ½ΠΈΡΠ½ΡΡ
ΠΏΠ½Π΅Π²ΠΌΠΎΠ½ΠΈΠΉ ΠΈ Π² ΡΠ°Π²Π½ΠΎΠΉ ΡΡΠ΅ΠΏΠ΅Π½ΠΈ ΠΌΠΎΠ³ΡΡ Π±ΡΡΡ ΡΠ΅ΠΊΠΎΠΌΠ΅Π½Π΄ΠΎΠ²Π°Π½Ρ Π΄Π»Ρ Π²Π°ΠΊΡΠΈΠ½Π°ΡΠΈΠΈ ΠΏΡΠΈΠ·ΡΠ²Π½ΠΈΠΊΠΎΠ² Π·Π° ΠΌΠ΅ΡΡΡ Π΄ΠΎ ΠΏΡΠΈΠ·ΡΠ²Π° ΠΈ Π½ΠΎΠ²ΠΎΠ±ΡΠ°Π½ΡΠ΅Π², Π½Π΅ ΠΏΡΠΈΠ²ΠΈΡΡΡ
ΠΏΠ΅ΡΠ΅Π΄ ΠΏΡΠΈΠ·ΡΠ²ΠΎΠΌ Π½Π° Π²ΠΎΠ΅Π½Π½ΡΡ ΡΠ»ΡΠΆΠ±Ρ
First Observation of Self-Amplified Spontaneous Emission in a Free-Electron Laser at 109 nm Wavelength
We present the first observation of Self-Amplified Spontaneous Emission
(SASE) in a free-electron laser (FEL) in the Vacuum Ultraviolet regime at 109
nm wavelength (11 eV). The observed free-electron laser gain (approx. 3000) and
the radiation characteristics, such as dependency on bunch charge, angular
distribution, spectral width and intensity fluctuations all corroborate the
existing models for SASE FELs.Comment: 6 pages including 6 figures; e-mail: [email protected]
Stretching and breaking of chemical bonds, correlation of electrons, and radical properties of covalent species
Chemical bonds are considered in light of correlation of valence electrons
that is strengthened when the bond is dissociated. In the framework of the
unrestricted Hartree-Fock single-reference version of the configuration
interaction theory, effectively unpaired electrons lay the foundation of the
electron correlation measure in terms of total number of the electrons
(molecular chemical susceptibility). graphs and their singularities with
respect to the interatomic distance allow presenting a quantitative description
of stretching and breaking of chemical bonds. The approach validity is
demonstrated on a large number of bonds of different order and chemical
composition.Comment: 24 pages, 17 figures, 4 tables, Advances in Quantum Chemistry, vol.
70, 201
Development and Validation of a Tokamak Skin Effect Transformer model
A control oriented, lumped parameter model for the tokamak transformer
including the slow flux penetration in the plasma (skin effect transformer
model) is presented. The model does not require detailed or explicit
information about plasma profiles or geometry. Instead, this information is
lumped in system variables, parameters and inputs. The model has an exact
mathematical structure built from energy and flux conservation theorems,
predicting the evolution and non linear interaction of the plasma current and
internal inductance as functions of the primary coil currents, plasma
resistance, non-inductive current drive and the loop voltage at a specific
location inside the plasma (equilibrium loop voltage). Loop voltage profile in
the plasma is substituted by a three-point discretization, and ordinary
differential equations are used to predict the equilibrium loop voltage as
function of the boundary and resistive loop voltages. This provides a model for
equilibrium loop voltage evolution, which is reminiscent of the skin effect.
The order and parameters of this differential equation are determined
empirically using system identification techniques. Fast plasma current
modulation experiments with Random Binary Signals (RBS) have been conducted in
the TCV tokamak to generate the required data for the analysis. Plasma current
was modulated in Ohmic conditions between 200kA and 300kA with 30ms rise time,
several times faster than its time constant L/R\approx200ms. The model explains
the most salient features of the plasma current transients without requiring
detailed or explicit information about resistivity profiles. This proves that
lumped parameter modeling approach can be used to predict the time evolution of
bulk plasma properties such as plasma inductance or current with reasonable
accuracy; at least in Ohmic conditions without external heating and current
drive sources
Nuclear Magnetic Resonance Investigation of the Metal-to-Semiconductor Transition in Crystalline CdO
Current ramps in tokamaks: from present experiments to ITER scenarios
In order to prepare adequate current ramp-up and ramp-down scenarios for ITER, present experiments from various tokamaks have been analysed by means of integrated modelling in view of determining relevant heat transport models for these operation phases. A set of empirical heat transport models for L-mode (namely, the Bohm-gyroBohm model and scaling based models with a specific fixed radial shape and energy confinement time factors of H(96-L) = 0.6 or H(IPB98) = 0.4) has been validated on a multi-machine experimental dataset for predicting the l(i) dynamics within +/- 0.15 accuracy during current ramp-up and ramp-down phases. Simulations using the Coppi-Tang or GLF23 models (applied up to the LCFS) overestimate or underestimate the internal inductance beyond this accuracy (more than +/- 0.2 discrepancy in some cases). The most accurate heat transport models are then applied to projections to ITER current ramp-up, focusing on the baseline inductive scenario (main heating plateau current of I(p) = 15 MA). These projections include a sensitivity study to various assumptions of the simulation. While the heat transport model is at the heart of such simulations (because of the intrinsic dependence of the plasma resistivity on electron temperature, among other parameters), more comprehensive simulations are required to test all operational aspects of the current ramp-up and ramp-down phases of ITER scenarios. Recent examples of such simulations, involving coupled core transport codes, free-boundary equilibrium solvers and a poloidal field (PF) systems controller are also described, focusing on ITER current ramp-down.</p
THE METHOD OF THE CAPPAMETER OF SOILS AND ITS APPLICATION TO THE SEARCH OF THE SULPHIDE ORES IN KARELIA
Developed and delivered to the industrial production the field cappameter IPK-2, the methods of the field works and the processing of the soil cappametry results have been justified, the efficiency of method in complex with the magnetic and litogeochemical photographies with the search of the sulphide ores in Karelia has been shown. The developed cappameter has been delivered to the Joint-Stock Company "Uralchermetautomatics", where it is manufactured under the grade IPK-2; the methodical guides by the cappemetry of soils have been developedAvailable from VNTIC / VNTIC - Scientific & Technical Information Centre of RussiaSIGLERURussian Federatio
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