HD 174005: another binary classified as lambda Boo

We demonstrate that HD 174005, a star recently classified as belonging to the lambda Boo group, is in reality a double lined spectroscopic binary; at some phases, the observed composite spectrum may be similar to that of a single star with weak metal lines.Comment: Accepted by A&

Lode a Maria SS. Addolorata

Italian hymn to Our Lady of Sorrows, composed by Carlo Gerbaldi with lyrics by Father Antonio Fontana. This sheet music was published by the Church of San Carlo in Torino.https://ecommons.udayton.edu/imri_sheetmusic/1058/thumbnail.jp

The Latin Leaflet, Number 29

Polymer electrolytes represent the ultimate in terms of desirable properties of energy storage/conversion devices, as they can offer an all-solid-state construction, a wide variety of shapes and sizes, light-weight, low costs, high energy density and safety. Here we present our recent results concerning a novel strategy for preparing efficient polymer membranes which are successfully demonstrated as suitable electrolytes for several energy conversion and storage devices (i.e., Li- and Na-based batteries and DSSCs). Highly ionic conducting polymer electrolytes containing PEO-based functionalities and different components (e.g., Li/Na salts, RTILs, natural biosourced and cellulosic fillers) are successfully prepared via a rapid process and, directly or subsequently, cross-linked via UV irradiation (patent pending, PCT/IT2014/000008). All the prepared materials are thoroughly characterised in terms of their physical, chemical and morphological properties and tested for their electrochemical performances and durability. The UV-curing process on such materials led to the production of elastic and resistant amorphous macromolecular networks. Noticeably increased ionic conductivities are registered (10-3 S cm-1 at RT), along with very stable interfacial and storage stability and wide electrochemical stability windows. The different lab-scale solid-state devices show remarkable performances even at ambient temperature, at the level of those using liquid electrolytes, respect to which demonstrate much greater durability and safety. The obtained findings demonstrate a new, easy and low cost approach to fabricate and tailor-make polymer electrolytes with highly promising prospects for the next generation of advanced flexible energy production and storage devices

Sustainable electrochemistry - Functional applied materials and techniques for energy devices and sensing (GEI 2018): Foreword

In this Virtual Special Issue of Electrochimica Acta, we gather a selection of scientific research articles corresponding to contributions presented at the Italian Electrochemistry Days (Giornate dell'Elettrochimica Italiana) Edition 2018 – GEI 2018, the yearly event that gathers the national electrochemical community, which was held at the Olympic Village Hotel in Sestriere (Torino), built for the 2006 Winter Games, with panoramic views toward one of the most famous Europe's skiing resorts on the mountains of the north-west side of Italy

Rotational velocities of A-type stars I. Measurement of vsini in the southern hemisphere

Within the scope of a Key Programme determining fundamental parameters of stars observed by HIPPARCOS, spectra of 525 B8 to F2-type stars brighter than V=8 have been collected at ESO. Fourier transforms of several line profiles in the range 4200-4500 A are used to derive vsini from the frequency of the first zero. Statistical analysis of the sample indicates that measurement error is a function of vsini and this relative error of the rotational velocity is found to be about 6% on average. The results obtained are compared with data from the literature. There is a systematic shift from standard values from Slettebak et al. (1975), which are 10 to 12% lower than our findings. Comparisons with other independent vsini values tend to prove that those from Slettebak et al. are underestimated. This effect is attributed to the presence of binaries in the standard sample of Slettebak et al., and to the model atmosphere they used.Comment: 17 pages, includes 18 figures, accepted in A&

Lambda Boo stars with composite spectra

We examine the large sample of lambda Boo candidates collected in Table 1 of Gerbaldi et al. (2003) to see how many of them show composite spectra. Of the 132 lambda Boo candidates we identify 22 which definitely show composite spectra and 15 more for which there are good reasons to suspect a composite spectrum. The percentage of lambda Boo candidates with composite spectra is therefore > 17 and possibly considerably higher. For such stars the lambda Boo classification should be reconsidered taking into account the fact that their spectra are composite. We argue that some of the underabundances reported in the literature may simply be the result of the failure to consider the composite nature of the spectra. This leads to the legitimate suspicion that some, if not all, the lambda Boo candidates are not chemically peculiar at all. A thorough analysis of even a single one of the lambda Boo candidates with composite spectra, in which the composite nature of the spectrum is duly considered, which would demonstrate that the chemical peculiarities persist, would clear the doubt we presently have that the stars with composite spectra may not be lambda Boo at all.Comment: Accepted for publication by A&A on June 3rd 200

Structure–Performance Correlation of Nanocellulose‐Based Polymer Electrolytes for Efficient Quasi‐solid DSSCs

Nanoscale microfibrillated cellulose (NMFC) was introduced into a light-cured polymeric matrix to result in a green, cheap, and highly efficient quasi-solid electrolyte for the next-generation of bio-based dye-sensitized solar cells. The effect of NMFC on the photovoltaic parameters and performance of the resulting photo-electrochemical cells was thoroughly investigated, and a noticeable increase in both the photocurrent (due to optical phenomena) and the photovoltage (through a shielding effect on the recombination reactions) was demonstrated. Upon thorough optimization of the amount of NMFC introduced into the polymeric network, sunlight conversion efficiencies as high as 7.03 and 8.25 % were achieved at simulated light intensities of 1.0 and 0.4 sun, respectively. Furthermore and outstandingly, the addition of NMFC positively affected the long-term stability of the device, which was able to retain >95 % of its initial efficiency after 500 h of extreme aging condition

Evolution of magnetic fields in stars across the upper main sequence: I. Catalogue of magnetic field measurements with FORS1 at the VLT

To properly understand the physics of Ap and Bp stars it is particularly important to identify the origin of their magnetic fields. For that, an accurate knowledge of the evolutionary state of stars that have a measured magnetic field is an important diagnostic. Previous results based on a small and possibly biased sample suggest that the distribution of magnetic stars with mass below 3 M_sun in the H-R diagram differs from that of normal stars in the same mass range (Hubrig et al. 2000). In contrast, higher mass magnetic Bp stars may well occupy the whole main-sequence width (Hubrig, Schoeller & North 2005). In order to rediscuss the evolutionary state of upper main sequence magnetic stars, we define a larger and bias-free sample of Ap and Bp stars with accurate Hipparcos parallaxes and reliably determined longitudinal magnetic fields. We used FORS1 at the VLT in its spectropolarimetric mode to measure the magnetic field in chemically peculiar stars where it was unknown or poorly known as yet. In this first paper we present our results of the mean longitudinal magnetic field measurements in 136 stars. Our sample consists of 105 Ap and Bp stars, two PGa stars, 17 HgMn stars, three normal stars, and nine SPB stars. A magnetic field was for the first time detected in 57 Ap and Bp stars, in four HgMn stars, one PGa star, one normal B-type star and four SPB stars.Comment: 9 pages, 2 figures, 2 tables, to appear in AN 327, 28

Carrier mobility and scattering lifetime in electric double-layer gated few-layer graphene

We fabricate electric double-layer field-effect transistor (EDL-FET) devices on mechanically exfoliated few-layer graphene. We exploit the large capacitance of a polymeric electrolyte to study the transport properties of three, four and five-layer samples under a large induced surface charge density both above and below the glass transition temperature of the polymer. We find that the carrier mobility shows a strong asymmetry between the hole and electron doping regime. We then employ ab-initio density functional theory (DFT) calculations to determine the average scattering lifetime from the experimental data. We explain its peculiar dependence on the carrier density in terms of the specific properties of the electrolyte we used in our experiments.Comment: 6 pages, 3 figure