Degradasi Senyawa Paraquat dalam Pestisida Gramoxone secara Sonolisis dengan Penambahan Zno

Degradation of paraquat in gramoxone pesticide had been done by sonolysis with adding ZnO. Sonolysis method were performed using an ultrasound with frequency 50 kHz. The optimum condition of sonolysis were found at temperature 40oC. The percentage of degradation of 20 mg/L paraquat by sonolysisi method without adding ZnO during 120 minutes treatment was 20,70%, and with adding0,08 g percentage of degradation increasesd to 56,83% at the same treatment

A review: Utilization of waste materials in concrete

Concrete is the most important material in building construction. It had been used widely around the world and is made of cement, fine aggregates, coarse aggregates and water. These materials come from natural resources which had a depletion and environmental pollution issues. On the other hand, tonnes of waste are generated around the world especially in developed country which are having rapid industrialization, increasing population growth, technological developments and urbanization. Most of the waste materials from those causes are not recyclable. The methods managing of the waste materials are usually done by dumping in landfills or burning. Thus, in order to overcome both issues, alternative replacements from waste materials can massively give huge differences to the industry that will reduce the usage of natural resources and gives benefits to the industry itself and also to the environment. Studies on waste materials had been conducted by many researchers before. Hence, in this paper, some materials which are coal bottom ash, slag, ceramic waste and glass powder will be discuss as waste materials that have been used from many backgrounds of industries. This paper attempt to summarize the investigation of the following materials as substitution materials in concrete, with the following discussion. The properties such as workability, compressive strength, ductility etc. of these replacement materials are compared with the normal concrete. A lightweight concrete that is safe and eco-friendly will be produced as a construction material. This shows that some of the materials can improve the performance of concrete itself. Thus, this study is crucial in finding the other waste materials that can act as a replacement

Building a transnational biodiversity geo-database of the protected areas in the Adriatic-Ionian Macro-Region: approaches and results from the IMPRECO Project

Background The main objective of the project Common strategies and best practices to IMprove the transnational PRotection of ECOsystem integrity and services - IMPRECO is to enhance the safeguarding of ecosystems and ecosystem services. Additionally, the aim of this project is to tackle their environmental vulnerability by strengthening the potential of the Protected Areas in biodiversity, ecosystems and ecosystem services conservation. This is expected to be addressed by maintaining it through their transnational networking located in the European Adriatic-Ionian Macro-Region. New information The aim of this research is: 1) to characterise the habitats and ecosystems involved in the coastal-marine protected areas considered; 2) to set a biodiversity baseline; 3) to understand what current ecosystems' conditions are; 4) to build up a transnational biomonitoring programme of target species and habitats and 5) to assess their response to pilot actions. To do so, a transnational inventory of species, habitats, ecosystems and ecosystem services was established, starting with the seven coastal-marine protected areas involved in the project. Data collection was carried out using different sources of information: scientific literature, officially available data from NATURA 2000 Standard Data Forms, checklists from local biomonitoring programmes, personal observations and citizen science, historical maps and data from new in-field analyses. Data were filled in the transnational biodiversity geo-databases according to the NATURA 2000 standards about habitat features, species protection level and species features. The presence of alien species (non-indigenous species, NIS) was also acknowledged and references about data collection were provided in the databases according to the Darwin Core standards

Review of mechanical performance of oil palm fiber and coconut fiber as an additional material in concrete

Waste can be categorized as organic waste and chemical waste. Organic waste generated from agriculture industry had been proofed to be use in concrete production to enhance the concrete performance. The main purpose of adding the fiber in concrete structure is to control cracking due to plastic shrinkage and to drying shrinkage. Besides, it can also reduce the permeability of concrete, thus, reduce the bleeding of water. Some types of fibers produce greater impact, abrasion, and shatter resistance in concrete. Therefore, this paper reviewed the mechanical properties of concrete containing oil palm and coconut fiber as an additional material in concrete. Coconut fiber length is longer than oil palm fiber. Therefore, in comparison, by adding coconut fiber in concrete up to 5% may reduce the flexural and tensile strength of the concrete due to agglomerate effect of the fiber. In contrast, for oil palm fiber, beyond 5% of addition in concrete will improve the flexural and tensile strength of the concrete due to the length effect of the fiber. By discussing both organic fiber as an additional material to strengthen the concrete, it can contribute to the body of knowledge in term of reducing cracks in concrete. Besides, it will give a better understanding to readers regarding the function of the materials in concrete

Strength and chloride penetration performance of concrete using coal bottom ash as coarse and fine aggregate replacement

Since 1987, Malaysia had used coal as a product to generate electricity. One of the main or the largest power plant in Malaysia is Tanjung Bin power plant at kukup, Johor. As a coal-based power plant, tonnes of coal bottom ash had been burned every day and the waste is wasted without specific economic benefit. Other than that, the waste generated are dangerous as it involved in environmental risk such as landfill ash reservoir. Therefore, this paper presents one of the alternative ways to manage the coal waste by cooperative it into concrete. This research study focuses on strength and durability performance of the concrete containing coal bottom ash as a coarse and fine aggregates replacement. The tests conducted was workability on fresh concrete, compressive strength test and chloride penetration test in 5% sodium chloride. The results show that the concrete containing coal bottom ash has low workability compare with normal concrete without coal bottom ash. Compressive strength test with coal bottom ash resulted higher than normal concrete. In chloride solution, the concrete containing coal bottom ash replacement shows better performance compare to normal concrete. Thus, it can be concluded that by using coal bottom ash in concrete as fine and coarse aggregates replacement, the performance in term of strength and chloride resistance are better compare to normal concrete. On the other hand, by using it in concrete, the waste generated dump in landfill can be reduced

Coastal sea level monitoring in the Mediterranean and Black seas

Employed for over a century, the traditional way of monitoring sea level variability by tide gauges – in combination with modern observational techniques like satellite altimetry – is an inevitable ingredient in sea level studies over the climate scales and in coastal seas. The development of the instrumentation, remote data acquisition, processing, and archiving in the last decades has allowed the extension of the applications to a variety of users and coastal hazard managers. The Mediterranean and Black seas are examples of such a transition – while having a long tradition of sea level observations with several records spanning over a century, the number of modern tide gauge stations is growing rapidly, with data available both in real time and as a research product at different time resolutions. As no comprehensive survey of the tide gauge networks has been carried out recently in these basins, the aim of this paper is to map the existing coastal sea level monitoring infrastructures and the respective data availability. The survey encompasses a description of major monitoring networks in the Mediterranean and Black seas and their characteristics, including the type of sea level sensors, measuring resolutions, data availability, and existence of ancillary measurements, altogether collecting information about 240 presently operational tide gauge stations. The availability of the Mediterranean and Black seas sea level data in the global and European sea level repositories has been also screened and classified following their sampling interval and level of quality check, pointing to the necessity of harmonization of the data available with different metadata and series in different repositories. Finally, an assessment of the networks' capabilities for their use in different sea level applications has been done, with recommendations that might mitigate the bottlenecks and ensure further development of the networks in a coordinated way, a critical need in the era of human-induced climate changes and sea level rise.En prens

Global patient outcomes after elective surgery: prospective cohort study in 27 low-, middle- and high-income countries.

BACKGROUND: As global initiatives increase patient access to surgical treatments, there remains a need to understand the adverse effects of surgery and define appropriate levels of perioperative care. METHODS: We designed a prospective international 7-day cohort study of outcomes following elective adult inpatient surgery in 27 countries. The primary outcome was in-hospital complications. Secondary outcomes were death following a complication (failure to rescue) and death in hospital. Process measures were admission to critical care immediately after surgery or to treat a complication and duration of hospital stay. A single definition of critical care was used for all countries. RESULTS: A total of 474 hospitals in 19 high-, 7 middle- and 1 low-income country were included in the primary analysis. Data included 44 814 patients with a median hospital stay of 4 (range 2-7) days. A total of 7508 patients (16.8%) developed one or more postoperative complication and 207 died (0.5%). The overall mortality among patients who developed complications was 2.8%. Mortality following complications ranged from 2.4% for pulmonary embolism to 43.9% for cardiac arrest. A total of 4360 (9.7%) patients were admitted to a critical care unit as routine immediately after surgery, of whom 2198 (50.4%) developed a complication, with 105 (2.4%) deaths. A total of 1233 patients (16.4%) were admitted to a critical care unit to treat complications, with 119 (9.7%) deaths. Despite lower baseline risk, outcomes were similar in low- and middle-income compared with high-income countries. CONCLUSIONS: Poor patient outcomes are common after inpatient surgery. Global initiatives to increase access to surgical treatments should also address the need for safe perioperative care. STUDY REGISTRATION: ISRCTN5181700