Coherent Heteroepitaxy of Bi2Se3 on GaAs (111)B

We report the heteroepitaxy of single crystal thin films of Bi2Se3 on the (111)B surface of GaAs by molecular beam epitaxy. We find that Bi2Se3 grows highly c-axis oriented, with an atomically sharp interface with the GaAs substrate. By optimizing the growth of a very thin GaAs buffer layer before growing the Bi2Se3, we demonstrate the growth of thin films with atomically flat terraces over hundreds of nanometers. Initial time-resolved Kerr rotation measurements herald opportunities for probing coherent spin dynamics at the interface between a candidate topological insulator and a large class of GaAs-based heterostructures.Comment: To appear in Applied Physics Letter

Interplay between ferromagnetism, surface states, and quantum corrections in a magnetically doped topological insulator

The breaking of time-reversal symmetry by ferromagnetism is predicted to yield profound changes to the electronic surface states of a topological insulator. Here, we report on a concerted set of structural, magnetic, electrical and spectroscopic measurements of \MBS thin films wherein photoemission and x-ray magnetic circular dichroism studies have recently shown surface ferromagnetism in the temperature range 15 K $\leq T \leq 100$ K, accompanied by a suppressed density of surface states at the Dirac point. Secondary ion mass spectroscopy and scanning tunneling microscopy reveal an inhomogeneous distribution of Mn atoms, with a tendency to segregate towards the sample surface. Magnetometry and anisotropic magnetoresistance measurements are insensitive to the high temperature ferromagnetism seen in surface studies, revealing instead a low temperature ferromagnetic phase at $T \lesssim 5$ K. The absence of both a magneto-optical Kerr effect and anomalous Hall effect suggests that this low temperature ferromagnetism is unlikely to be a homogeneous bulk phase but likely originates in nanoscale near-surface regions of the bulk where magnetic atoms segregate during sample growth. Although the samples are not ideal, with both bulk and surface contributions to electron transport, we measure a magnetoconductance whose behavior is qualitatively consistent with predictions that the opening of a gap in the Dirac spectrum drives quantum corrections to the conductance in topological insulators from the symplectic to the orthogonal class.Comment: To appear in Phys. Rev.

Mooring systems for marine energy converters

This is the author accepted manuscript. The final version is available from IEEE via the DOI in this record.This paper discusses several new technologies for mooring floating marine energy converter (MEC) devices, such as wave energy generators, tidal current turbines and floating wind turbines. The principal mooring component is a special nylon fiber rope which provides cyclic tension fatigue endurance much superior to that of conventional nylon ropes. The nylon fiber is treated with a new proprietary coating which has excellent wet yarn abrasion properties. The parallel-subrope type rope construction further reduces internal abrasion. Extensive laboratory testing was carried out on this new nylon rope design. Cyclic tension fatigue tests were conducted at mean loads and load amplitudes typical of actual service conditions and at higher mean loads and amplitudes. These tests demonstrate that the special nylon rope has essentially the same, desirable stretch characteristics as conventional nylon rope and has much better endurance performance. The mooring connection to the floating MEC device consists of a high-modulus fiber rope pendant which passes through a low-friction bell-mouth nylon fairlead on the MEC device. This eliminates the use of heavy, unreliable chain in this critical connection. A unique bag anchor system would be used on sand, clay, rock and other sea beds in which conventional drag embedment anchors and driven piles are impractical. The bag anchor consists of a large abrasion resistant carcass with lifting straps and top closure. The bag is transported to site in a collapsed form and is filled with local sand or aggregate to provide ballast weight. Several or many such bags are enclosed within a fiber rope net for deployment and are grouped together for connection to the mooring line. The paper will be of particular interest to designers of moorings for MEC systems in shallow water and severe wave environments. It will also be of interest for other mooring applications.This work would not have been possible without the funding and support of the Scottish Government, the Carbon Trust and Innovate UK.   The project was funded under the Marine Renewables Commercialization Fund (MRCF) and Marine Energy Supporting Array Technologies (MESAT).   Other partners who contributed to this project include Lloyd’s Register, DNV‐GL, TenCate, Orion Energy Centre, Nylacast, and offshore wind developer IDEOL.    Input and encouragement was provided by tidal power developer partner Bluewater, and wave energy developers AWS Ocean Energy and Pelamis.

The occupation of a box as a toy model for the seismic cycle of a fault

We illustrate how a simple statistical model can describe the quasiperiodic occurrence of large earthquakes. The model idealizes the loading of elastic energy in a seismic fault by the stochastic filling of a box. The emptying of the box after it is full is analogous to the generation of a large earthquake in which the fault relaxes after having been loaded to its failure threshold. The duration of the filling process is analogous to the seismic cycle, the time interval between two successive large earthquakes in a particular fault. The simplicity of the model enables us to derive the statistical distribution of its seismic cycle. We use this distribution to fit the series of earthquakes with magnitude around 6 that occurred at the Parkfield segment of the San Andreas fault in California. Using this fit, we estimate the probability of the next large earthquake at Parkfield and devise a simple forecasting strategy.Comment: Final version of the published paper, with an erratum and an unpublished appendix with some proof

A comprehensive assessment of the applicability of available and proposed offshore mooring and foundation technologies and design tools for array applications

PublishedThe function and type of mooring and/or foundation system are determined by a number of factors including: cost, site characteristics, expected environmental loading and environmental or legislative constraints. The design of the device and its mode of operation will also influence the decision making process. It is the role of DTOcean Work Package 4 to produce a decision making tool which has the capability to assess a range of technologies for the design and selection of mooring and foundation systems for marine renewable energy (MRE) device arrays. In this first deliverable report, criteria are introduced which can be used to appraise technologies and approaches relevant to MRE devices. Existing mooring and foundation technologies used in the offshore industry are summarised with examples given of MRE device deployments. A general overview of the design tools which are currently used for mooring and foundation design in the offshore and MRE industries is provided, along with a list of the capabilities of several commercially available software packages.European Commission’s 7th Framework; Grant agreement number: 60859

MoKCa database - mutations of kinases in cancer

Members of the protein kinase family are amongst the most commonly mutated genes in human cancer, and both mutated and activated protein kinases have proved to be tractable targets for the development of new anticancer therapies The MoKCa database (Mutations of Kinases in Cancer, http://strubiol.icr.ac.uk/extra/mokca) has been developed to structurally and functionally annotate, and where possible predict, the phenotypic consequences of mutations in protein kinases implicated in cancer. Somatic mutation data from tumours and tumour cell lines have been mapped onto the crystal structures of the affected protein domains. Positions of the mutated amino-acids are highlighted on a sequence-based domain pictogram, as well as a 3D-image of the protein structure, and in a molecular graphics package, integrated for interactive viewing. The data associated with each mutation is presented in the Web interface, along with expert annotation of the detailed molecular functional implications of the mutation. Proteins are linked to functional annotation resources and are annotated with structural and functional features such as domains and phosphorylation sites. MoKCa aims to provide assessments available from multiple sources and algorithms for each potential cancer-associated mutation, and present these together in a consistent and coherent fashion to facilitate authoritative annotation by cancer biologists and structural biologists, directly involved in the generation and analysis of new mutational data

Estimation of the solubility parameters of model plant surfaces and agrochemicals: a valuable tool for understanding plant surface interactions

Background Most aerial plant parts are covered with a hydrophobic lipid-rich cuticle, which is the interface between the plant organs and the surrounding environment. Plant surfaces may have a high degree of hydrophobicity because of the combined effects of surface chemistry and roughness. The physical and chemical complexity of the plant cuticle limits the development of models that explain its internal structure and interactions with surface-applied agrochemicals. In this article we introduce a thermodynamic method for estimating the solubilities of model plant surface constituents and relating them to the effects of agrochemicals. Results Following the van Krevelen and Hoftyzer method, we calculated the solubility parameters of three model plant species and eight compounds that differ in hydrophobicity and polarity. In addition, intact tissues were examined by scanning electron microscopy and the surface free energy, polarity, solubility parameter and work of adhesion of each were calculated from contact angle measurements of three liquids with different polarities. By comparing the affinities between plant surface constituents and agrochemicals derived from (a) theoretical calculations and (b) contact angle measurements we were able to distinguish the physical effect of surface roughness from the effect of the chemical nature of the epicuticular waxes. A solubility parameter model for plant surfaces is proposed on the basis of an increasing gradient from the cuticular surface towards the underlying cell wall. Conclusions The procedure enabled us to predict the interactions among agrochemicals, plant surfaces, and cuticular and cell wall components, and promises to be a useful tool for improving our understanding of biological surface interactions

Performing innocence: violence and the nation in Ian McEwan’s Saturday and Sunjeev Sahota’s Ours Are the Streets

British normative society and post-9/11 fiction borrow from the discourse of American exceptionalism (including the fall from innocence to experience, the desire to create or preserve a better world, a ‘Messianic consciousness’ reflecting the arrogance of virtue, the development of narratives of heroism and goodness tied to nation-building, and the use of the above to justify ‘exemptionalism’) to expose and query the entitlement of those within the narrative home of Britishness and the outsider-status of those used to define its borders. This article discusses Ian McEwan’s Saturday and Sunjeev Sahota’s Ours Are the Streets, arguing that they illustrate a turning point in Britain’s imagination of itself as a nation in a struggle over Britishness which is predicated on notions of violence and innocence. Since 9/11 the debate about Britishness has used innocence as a constitutive inside of the nation and direct violence as an exclusionary characteristic. McEwan satirizes this rhetoric of innocence whereas Sahota challenges it. Both novels illustrate how post-9/11 British fiction deals with politics as war, placing violence at the heart of society. McEwan parodies the point of view of British normative society by allowing his main character to justify his privileged position under the guise of arguing for the current social and international status quo. Sahota charts the journey of those who are caught between the rejection of unjust social structures and the desire to fit within them, depicting his protagonist’s misguided attempt to redefine the British nation through terrorism. Violence and exceptionalism are central to both novels, which portray a turn in the imagining of Britain. The events of 9/11 can therefore be seen not just as a historical turning point but as a turn in Britain’s imagination of itself