Validation of data analysis routines for a thermal probe apparatus using numerical data sets

Most thermal properties of construction materials used in the analysis of building performance have been measured under laboratory conditions, using a guarded hot box or hot plate apparatus. As a consequence, these properties seldom reflect the impact of actual conditions (especially moisture content) on the values of conductivity and diffusivity. Hence there is a need to develop techniques that allow to take into account local conditions, and measure building material properties in situ. One option available is the use of a thermal probe. The thermal probe technique is based on creating a line source in a material sample, and measuring the temperature rise in the sample in reaction to heat being applied. Obviously the data analysis routines used to calculate thermal conductivity and thermal diffusivity based on the temperature rise observed are crucial to the success of the technique. Transient thermal simulation of a of a model representing a line source in an infinite material sample has been used to generate a set of numerical data sets to validate analysis routines in conjunction with an experimental thermal probe apparatus. Findings show that by careful application of these routines, a close agreement with simulation input values can be achieved, with errors of less than one percent. This validates the analysis routines and provides a deeper appreciation of the theoretical behaviour of a thermal probe

Thermal probe technology for buildings: the transition from laboratory to field measurements

This article reports the results of an investigation into the transfer of thermal probe measurement technology from laboratory use to actual buildings in order to undertake the in situ determination of thermal material properties. The imperative for using in situ measurements is 1) the impact of moisture content on thermal properties, 2) the possible wide range of variation of properties across most materials used in construction, and 3) the lack of data for new and innovative materials. Thermal probe technology offers the prospect of taking building specific data, addressing these issues. Based on commercially available thermal probes a portable measurement kit and accompanying measurement procedure have been developed. Three case study buildings, each having different materials, have been studied to ascertain whether or not the technique can be transferred to relatively uncontrolled environments while remaining capable of achieving a precision that is similar to an ASTM standard that can be related to thermal conductivity measurements of building materials. The results show that this is indeed the case, and that the use of thermal probe technology may yield thermal properties that vary significantly from the laboratory values currently used in building thermal engineering calculations

Positronium collisions with rare-gas atoms

We calculate elastic scattering of positronium (Ps) by the Xe atom using the recently developed pseudopotential method [I. I. Fabrikant and G. F. Gribakin, Phys. Rev. A 90, 052717 (2014)] and review general features of Ps scattering from heavier rare-gas atoms: Ar, Kr, and Xe. The total scattering cross section is dominated by two contributions: elastic scattering and Ps ionization (breakup). To calculate the Ps ionization cross sections we use the binary-encounter method for Ps collisions with an atomic target. Our results for the ionization cross section agree well with previous calculations carried out in the impulse approximation. Our total Ps-Xe cross section, when plotted as a function of the projectile velocity, exhibits similarity with the electron-Xe cross section for the collision velocities higher than 0.8 a.u., and agrees very well with the measurements at Ps velocities above 0.5 a.u.Comment: 7 pages, 7 figures, submitted to J. Phys.

Joint source-channel coding for a quantum multiple access channel

Suppose that two senders each obtain one share of the output of a classical, bivariate, correlated information source. They would like to transmit the correlated source to a receiver using a quantum multiple access channel. In prior work, Cover, El Gamal, and Salehi provided a combined source-channel coding strategy for a classical multiple access channel which outperforms the simpler "separation" strategy where separate codebooks are used for the source coding and the channel coding tasks. In the present paper, we prove that a coding strategy similar to the Cover-El Gamal-Salehi strategy and a corresponding quantum simultaneous decoder allow for the reliable transmission of a source over a quantum multiple access channel, as long as a set of information inequalities involving the Holevo quantity hold.Comment: 21 pages, v2: minor changes, accepted into Journal of Physics

Positronium collisions with rare-gas atoms: Free-electron gas plus orthogonalizing pseudopotential model

Positronium collisions with rare-gas atoms are treated using the free-electron-gas approximation for exchange and correlation potential. The results confirm the absence of the Ramsauer-Townsend minimum in elastic scattering cross sections, but show lower cross sections in the lower-energy region when compared to previous pseudopotential calculations. This is explained by a more attractive ab initio correlation potential as compared to the previously used empirical potential. The results in the thermal-energy region agree very well with most swarm measurements for all rare-gas atoms. At higher energies, the results are compared with beam experiments and agreement for heavier rare-gas atoms Ar, Kr, and Xe is found to be very good. For He and Ne, some discrepancies with beam measurements are observed. This is explained by a poorer performance of the free-electron-gas potentials, based on the statistical Thomas-Fermi model, for systems with fewer electrons

Extending the UK's green deal with the consideration of occupant behaviour

This paper introduces a study, which extends the current UK’s Green Deal through a consideration of modifying occupant behaviour in buildings to save building energy consumption. A case study was carried out in a typical mid-terraced residential building located in the Southwest of the UK. In the study, dynamic building performance simulation was used to predict the energy saving potential of various behaviour change options so as to help occupants use the building more energy efficiently. Feedback from building occupants reveals that this approach is helpful in reducing energy demand in a real building application, but also points out the need for future work

Quantum correlations in the temporal CHSH scenario

We consider a temporal version of the CHSH scenario using projective measurements on a single quantum system. It is known that quantum correlations in this scenario are fundamentally more general than correlations obtainable with the assumptions of macroscopic realism and non-invasive measurements. In this work, we also educe some fundamental limitations of these quantum correlations. One result is that a set of correlators can appear in the temporal CHSH scenario if and only if it can appear in the usual spatial CHSH scenario. In particular, we derive the validity of the Tsirelson bound and the impossibility of PR-box behavior. The strength of possible signaling also turns out to be surprisingly limited, giving a maximal communication capacity of approximately 0.32 bits. We also find a temporal version of Hardy's nonlocality paradox with a maximal quantum value of 1/4.Comment: corrected versio

Semiempirical \u3ci\u3eR\u3c/i\u3e-matrix theory of low energy electron–CF\u3csub\u3e3\u3c/sub\u3eCl inelastic scattering

We apply a semiempirical R-matrix theory to calculations of vibrational excitation and dissociative attachment in the CF3Cl molecule for electron energies below about 3 eV. We employ two sets of model parameters corresponding to two different forms of the CF3Cl− potential curve. We find that our present, ab initio calculated anion curve gives vibrational excitation and dissociative attachment cross sections in good agreement with experimental measurements. We also compare the results of our theory with those of a recently published classical theory

Positronium collisions with polar molecules

We calculate elastic and positronium (Ps) break-up cross sections for collisions of Ps with the polar molecules CO, HCl, and LiF in the fixed-nuclei approximation. We incorporate electron exchange and correlation for these processes by using the free-electron-gas model developed earlier for Ps scattering by rare-gas atoms, N2, O2, and CO2 molecules. The present target molecules provide a range of dipole moments from the weakly polar CO to the strongly polar LiF. We find that Ps scattering is similar to electron scattering when the cross sections are plotted as a function of projectile velocity for the targets with smaller dipole moments (CO, HCl). However, we do not see such a similarity for LiF which has a large dipole moment. Below the Ps break-up threshold we observe resonance structures similar to those obtained earlier for the other molecular targets that we have studied

Development of integrated thermionic circuits for high-temperature applications

Integrated thermionic circuits (ITC) capable of extended operation in ambient temperatures up to 500 C are studied. A set of practical design and performance equations is demonstrated. Experimental results are discussed in which both devices and simple circuits were successfully operated in 5000 C environments for extended periods. It is suggested that ITC's may become an important technology for high temperature instrumentation and control systems in geothermal and other high temperature environments