3,304 research outputs found

    Ozone and Other Air Pollutants and the Risk of Oral Clefts

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    Plasmon-phonon coupling in large-area graphene dot and antidot arrays

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    Nanostructured graphene on SiO2 substrates pave the way for enhanced light-matter interactions and explorations of strong plasmon-phonon hybridization in the mid-infrared regime. Unprecedented large-area graphene nanodot and antidot optical arrays are fabricated by nanosphere lithography, with structural control down to the sub-100 nanometer regime. The interaction between graphene plasmon modes and the substrate phonons is experimentally demonstrated and structural control is used to map out the hybridization of plasmons and phonons, showing coupling energies of the order 20 meV. Our findings are further supported by theoretical calculations and numerical simulations.Comment: 7 pages including 6 figures. Supporting information is available upon request to author

    Study of the auto-ignition phenomenon of PRFs under HCCI conditions in a RCEM by means of spectroscopy

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    An investigation of the effects of contour conditions and fuel properties on the auto-ignition and combustion process under HCCI conditions is presented in this study. A parametric variation of initial temperature, intake pressure, compression ratio, oxygen concentration and equivalence ratio has been carried out for Primary Reference Fuels in a Rapid Compression Expansion Machine while applying spectroscopy. The results have also been contrasted with natural chemiluminescence measurements. Additionally, the experiments have been simulated in CHEMKIN and the results derived from the optical techniques have been compared with the results from the chemical kinetics of the process, validating the chemical kinetic mechanism and an additional sub-model of excited OH . Two different scenarios can be seen according to the results from the spectrograph. For very lean or very low-temperature combustions no peak of OH is seen at 310 nm of wavelength, proving that the luminosity came from the CO continuum rather than from the OH . However, for more intense combustions (richer equivalence ratios, higher temperatures or lower EGR rates) spectrography shows a clear peak of OH that has much longer time of life than the corresponding to the CO continuum. The main chemical reaction that causes this two scenarios has been identified as H þ HO2 ) 2OH. The increase of relevance of this reaction at high combustion temperatures causes a higher OH accumulation, which leads to a brighter OH emission. Finally, for low temperature combustions the CO continuum out-shines the OH radiation so the light emitted by this radical cannot be detected by means of natural chemiluminescence. 201The authors would like to thank different members of the LAV team of the ETH-Zurich for their contribution to this work. The authors are grateful to the Universitat Politecnica de Valencia for financing the Ph.D. studies of W. Vera-Tudela (FPI SP1 grant 30/05/2012) and his stay at ETH-Zurich (grant 30/12/2014). Finally, the authors would like to thank the Spanish Ministry of Education for financing the Ph.D. studies of Dario Lopez-Pintor (grant FPU13/02329) and his stay at ETH-Zurich (grant EST14/00626).Desantes Fernández, JM.; García Oliver, JM.; Vera-Tudela-Fajardo, WM.; López Pintor, D.; Schneider, B.; Boulouchos, K. (2016). Study of the auto-ignition phenomenon of PRFs under HCCI conditions in a RCEM by means of spectroscopy. Applied Energy. 179:389-400. https://doi.org/10.1016/j.apenergy.2016.06.134S38940017

    Bulk-sensitive photoemission spectroscopy of A_2FeMoO_6 double perovskites (A=Sr, Ba)

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    Electronic structures of Sr_2FeMoO_6 (SFMO) and Ba_2FeMoO_6 (BFMO) double perovskites have been investigated using the Fe 2p->3d resonant photoemission spectroscopy (PES) and the Cooper minimum in the Mo 4d photoionization cross section. The states close to the Fermi level are found to have strongly mixed Mo-Fe t_{2g} character, suggesting that the Fe valence is far from pure 3+. The Fe 2p_{3/2} XAS spectra indicate the mixed-valent Fe^{3+}-Fe^{2+} configurations, and the larger Fe^{2+} component for BFMO than for SFMO, suggesting a kind of double exchange interaction. The valence-band PES spectra reveal good agreement with the LSDA+U calculation.Comment: 4 pages, 3 figure

    High spatial resolution X-ray spectroscopy of SNR Cassiopeia A with {\sl Chandra}

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    We present high spatial resolution X-ray spectroscopy of supernova remnant Cassiopeia A with the {\sl Chandra} observations. The X-ray emitting region of this remnant was divided into 38 ×\times 34 pixels with a scale of 10\arcsec ×\times 10\arcsec each. Spectra of 960 pixels were created and fitted with an absorbed two component non-equilibrium ionization model. With the spectral analysis results we obtained maps of absorbing column density, temperatures, ionization ages, and the abundances for Ne, Mg, Si, S, Ca and Fe. The Si, S and possibly Ca abundance maps show obviously jet structures, while Fe doesn't follow the jet but seems to be distributed perpendicular to it. In the range of about two orders of magnitude, the abundances of Si, S and Ca show tight correlations between each other, suggesting them to be ejecta from explosive O-burning and incomplete Si-burning. Meanwhile, Ne abundance is well correlated with that of Mg, indicating them to be the ashes of explosive C/Ne burning. The Fe abundance is positively correlated with that of Si when Si abundance is lower than 3 solar abundances, but a negative correlation appears when the Si abundance is higher. We suggest that such a two phase correlation is the results of different ways in which Fe is synthesized.Comment: accepted by ChJA

    Resonant Visible Light Modulation with Graphene

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    Fast modulation and switching of light at visible and near-infrared (vis-NIR) frequencies is of utmost importance for optical signal processing and sensing technologies. No fundamental limit appears to prevent us from designing wavelength-sized devices capable of controlling the light phase and intensity at gigaherts (and even terahertz) speeds in those spectral ranges. However, this problem remains largely unsolved, despite recent advances in the use of quantum wells and phase-change materials for that purpose. Here, we explore an alternative solution based upon the remarkable electro-optical properties of graphene. In particular, we predict unity-order changes in the transmission and absorption of vis-NIR light produced upon electrical doping of graphene sheets coupled to realistically engineered optical cavities. The light intensity is enhanced at the graphene plane, and so is its absorption, which can be switched and modulated via Pauli blocking through varying the level of doping. Specifically, we explore dielectric planar cavities operating under either tunneling or Fabry-Perot resonant transmission conditions, as well as Mie modes in silicon nanospheres and lattice resonances in metal particle arrays. Our simulations reveal absolute variations in transmission exceeding 90% as well as an extinction ratio >15 dB with small insertion losses using feasible material parameters, thus supporting the application of graphene in fast electro-optics at vis-NIR frequencies.Comment: 17 pages, 13 figures, 54 reference

    Phenotypic and functional analyses show stem cell-derived hepatocyte-like cells better mimic fetal rather than adult hepatocytes

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    Background & Aims: Hepatocyte-like cells (HLCs), differentiated from pluripotent stem cells by the use of soluble factors, can model human liver function and toxicity. However, at present HLC maturity and whether any deficit represents a true fetal state or aberrant differentiation is unclear and compounded by comparison to potentially deteriorated adult hepatocytes. Therefore, we generated HLCs from multiple lineages, using two different protocols, for direct comparison with fresh fetal and adult hepatocytes. Methods: Protocols were developed for robust differentiation. Multiple transcript, protein and functional analyses compared HLCs to fresh human fetal and adult hepatocytes. Results: HLCs were comparable to those of other laboratories by multiple parameters. Transcriptional changes during differentiation mimicked human embryogenesis and showed more similarity to pericentral than periportal hepatocytes. Unbiased proteomics demonstrated greater proximity to liver than 30 other human organs or tissues. However, by comparison to fresh material, HLC maturity was proven by transcript, protein and function to be fetal-like and short of the adult phenotype. The expression of 81% phase 1 enzymes in HLCs was significantly upregulated and half were statistically not different from fetal hepatocytes. HLCs secreted albumin and metabolized testosterone (CYP3A) and dextrorphan (CYP2D6) like fetal hepatocytes. In seven bespoke tests, devised by principal components analysis to distinguish fetal from adult hepatocytes, HLCs from two different source laboratories consistently demonstrated fetal characteristics. Conclusions: HLCs from different sources are broadly comparable with unbiased proteomic evidence for faithful differentiation down the liver lineage. This current phenotype mimics human fetal rather than adult hepatocytes

    Modelling of strain effects in manganite films

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    Thickness dependence and strain effects in films of La1xAxMnO3La_{1-x}A_xMnO_3 perovskites are analyzed in the colossal magnetoresistance regime. The calculations are based on a generalization of a variational approach previously proposed for the study of manganite bulk. It is found that a reduction in the thickness of the film causes a decrease of critical temperature and magnetization, and an increase of resistivity at low temperatures. The strain is introduced through the modifications of in-plane and out-of-plane electron hopping amplitudes due to substrate-induced distortions of the film unit cell. The strain effects on the transition temperature and transport properties are in good agreement with experimental data only if the dependence of the hopping matrix elements on the MnOMnMn-O-Mn bond angle is properly taken into account. Finally variations of the electron-phonon coupling linked to the presence of strain turn out important in influencing the balance of coexisting phases in the filmComment: 7 figures. To be published on Physical Review
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