42 research outputs found
Molecular and Electronic Structure of Electroactive Self-Assembled Monolayers
Self-assembled monolayers (SAMs) containing electroactive functional groups are excellent model systems for the formation of electronic devices by self-assembly. In particular ferrocene-terminated alkanethiol SAMs have been extensively studied in the past. However, there are still open questions related with their electronic structure including the influence of the ferrocene group in the SAM-induced work function changes of the underlying metal. We have thus carried out a thorough experimental and theoretical investigation in order to determine the molecular and electronic structure of ferrocene-terminated alkanethiol SAMs on Au surfaces. In agreement with previous studies we found that the Fc-containing alkanethiol molecules adsorb forming a thiolate bond with the Au surface with a molecular geometry 30 degrees tilted with respect to the surface normal. Measured surface coverages indicate the formation of a compact monolayer. On the other hand, contrary with previous observations, we found that the ferrocene group has little influence on the observed work function decrease which is largely determined by the alkanethiol. Furthermore, the ferrocene moiety lies 14 Å above the metal surface covalently bonded to the alkanethiol SAM and its HOMO is located at -1.6 eV below the Fermi level. Our results provide new valuable insight into the molecular and electronic structure of electroactive SAMs which are of fundamental importance in the field of molecular electronics.Fil: Méndez de Leo, Lucila Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: de la Llave, Ezequiel Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Scherlis Perel, Damian Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Williams, Federico Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentin
Estimation of necessity of performance and choice of optimum terms tracheostomy at carrying out ALV at patients with abdominal sepsis
For the purpose of a substantiation of necessity and optimum terms of performance tracheostomy at 96 patients with a abdominal sepsis, demanding carrying out long ALV the analysis of a clinical current of disease is made. From them to 59 patients (61,5 %) it is executed surgical top median tracheostomy in different terms ALV. At 37 patients (38,5 %) long ventilation of lungs was carried out through an endotracheal tube throughout all period of artificial respiratory support. It is established that tracheostomy performance at carrying out long ALV within 25 days in the general population of patients the abdominal sepsis has no conclusive clinical advantages before ventilation of lungs through a endotracheal tube tube. Early the tracheostomy does not reduce risk VAP, does not reduce duration ALV and stay time in DRIT. Term of carrying out of artificial respiratory support is not the main defining factor for decision-making. Indications to tracheostomy should be individualised proceeding from a concrete clinical situation.С целью обоснования необходимости и оптимальных сроков выполнения трахеостомии у 96 пациентов с абдоминальным сепсисом, требующих проведения длительной ИВЛ выполнен анализ клинического течения заболевания. Из них 59 пациентам (61,5%) выполнена хирургическая верхняя срединная трахеостомия в разные сроки ИВЛ. У 37 пациентов (38,5%) длительная вентиляция лёгких осуществлялась через эндотрахеальную трубку на протяжении всего периода искусственной респираторной поддержки. Установлено, что выполнение ТС при проведении длительной ИВЛ в пределах 25 дней в общей популяции пациентов АС не имеет неоспоримых клинических преимуществ перед вентиляцией лёгких через эндотрахеальную трубку. Ранняя ТС не снижает риск ВАП, не сокращает длительность ИВЛ и время пребывания в ОРИТ. Срок проведения искусственной респираторной поддержки не является главным определяющим фактором для принятия решения. Показания к трахеостомии должны быть индивидуализированы исходя из конкретной клинической ситуации
Gravitating discs around black holes
Fluid discs and tori around black holes are discussed within different
approaches and with the emphasis on the role of disc gravity. First reviewed
are the prospects of investigating the gravitational field of a black
hole--disc system by analytical solutions of stationary, axially symmetric
Einstein's equations. Then, more detailed considerations are focused to middle
and outer parts of extended disc-like configurations where relativistic effects
are small and the Newtonian description is adequate.
Within general relativity, only a static case has been analysed in detail.
Results are often very inspiring, however, simplifying assumptions must be
imposed: ad hoc profiles of the disc density are commonly assumed and the
effects of frame-dragging and completely lacking. Astrophysical discs (e.g.
accretion discs in active galactic nuclei) typically extend far beyond the
relativistic domain and are fairly diluted. However, self-gravity is still
essential for their structure and evolution, as well as for their radiation
emission and the impact on the environment around. For example, a nuclear star
cluster in a galactic centre may bear various imprints of mutual star--disc
interactions, which can be recognised in observational properties, such as the
relation between the central mass and stellar velocity dispersion.Comment: Accepted for publication in CQG; high-resolution figures will be
available from http://www.iop.org/EJ/journal/CQ
Supersymmetric QCD corrections to and the Bernstein-Tkachov method of loop integration
The discovery of charged Higgs bosons is of particular importance, since
their existence is predicted by supersymmetry and they are absent in the
Standard Model (SM). If the charged Higgs bosons are too heavy to be produced
in pairs at future linear colliders, single production associated with a top
and a bottom quark is enhanced in parts of the parameter space. We present the
next-to-leading-order calculation in supersymmetric QCD within the minimal
supersymmetric SM (MSSM), completing a previous calculation of the SM-QCD
corrections. In addition to the usual approach to perform the loop integration
analytically, we apply a numerical approach based on the Bernstein-Tkachov
theorem. In this framework, we avoid some of the generic problems connected
with the analytical method.Comment: 14 pages, 6 figures, accepted for publication in Phys. Rev.
Quantum field theory and Hopf algebra cohomology
We exhibit a Hopf superalgebra structure of the algebra of field operators of
quantum field theory (QFT) with the normal product. Based on this we construct
the operator product and the time-ordered product as a twist deformation in the
sense of Drinfeld. Our approach yields formulas for (perturbative) products and
expectation values that allow for a significant enhancement in computational
efficiency as compared to traditional methods. Employing Hopf algebra
cohomology sheds new light on the structure of QFT and allows the extension to
interacting (not necessarily perturbative) QFT. We give a reconstruction
theorem for time-ordered products in the spirit of Streater and Wightman and
recover the distinction between free and interacting theory from a property of
the underlying cocycle. We also demonstrate how non-trivial vacua are described
in our approach solving a problem in quantum chemistry.Comment: 39 pages, no figures, LaTeX + AMS macros; title changed, minor
corrections, references update
Fluids and barriers of the CNS: a historical viewpoint
Tracing the exact origins of modern science can be a difficult but rewarding pursuit. It is possible for the astute reader to follow the background of any subject through the many important surviving texts from the classical and ancient world. While empirical investigations have been described by many since the time of Aristotle and scientific methods have been employed since the Middle Ages, the beginnings of modern science are generally accepted to have originated during the 'scientific revolution' of the 16th and 17th centuries in Europe. The scientific method is so fundamental to modern science that some philosophers consider earlier investigations as 'pre-science'. Notwithstanding this, the insight that can be gained from the study of the beginnings of a subject can prove important in the understanding of work more recently completed. As this journal undergoes an expansion in focus and nomenclature from cerebrospinal fluid (CSF) into all barriers of the central nervous system (CNS), this review traces the history of both the blood-CSF and blood-brain barriers from as early as it was possible to find references, to the time when modern concepts were established at the beginning of the 20th century
Branch Retinal Vein Occlusion: Pathogenesis, Visual Prognosis, and Treatment Modalities
In branch retinal vein occlusion (BRVO), abnormal arteriovenous crossing with vein compression, degenerative changes of the vessel wall and abnormal hematological factors constitute the primary mechanism of vessel occlusion. In general, BRVO has a good prognosis: 50–60% of eyes are reported to have a final visual acuity (VA) of 20/40 or better even without treatment. One important prognostic factor for final VA appears to be the initial VA. Grid laser photocoagulation is an established treatment for macular edema in a particular group of patients with BRVO, while promising results for this condition are shown by intravitreal application of steroids or new vascular endothelial growth factor inhibitors. Vitrectomy with or without arteriovenous sheathotomy combined with removal of the internal limiting membrane may improve vision in eyes with macular edema which are unresponsive to or ineligible for laser treatment
Erratum to: 36th International Symposium on Intensive Care and Emergency Medicine
[This corrects the article DOI: 10.1186/s13054-016-1208-6.]