9 research outputs found
Shifting Winds: Using Ancestry DNA to Explore Multiracial Individuals\u27 Patterns of Articulating Racial Identity
This study explored how genotype information affects identification narratives of multiracial individuals. Twenty-one multiracial individuals completed individual interviews before and after receiving a DNA analysis to clarify their genetically based racial ancestry. Based on results, this article proposes patterns of articulating racial identity by multiracial individuals. Four patterns extend evolving research in multiracial identification, namely (1) the individual articulates a monoracial identity; (2) the individual articulates one identity, but this can shift in response to various conditions; (3) the individual articulates an extraracial identity, opting out of traditional categories applied to race; and (4) the person distinguishes traditional categories of race from culture and owns the two identities in different ways. Implications of these findings are discussed. First, adding new ancestry DNA information further muddles the neat categories of race, consistent with the view of race as socially constructed. Second, results emphasize the fluidity of identification for multiracial individuals. Third, DNA information challenges the neat percentages people tend to associate with their backgrounds. Particularly for younger multiracial individuals, there was less of a sense that race was a real thing and more that culture played a big part in how they saw themselves
N-Aryl stilbazolium dyes as sensitizers for solar cells
Eight new N-arylstilbazolium chromophores with electron donating –NR2 (R = Me or Ph) substituents have been synthesized via Knoevenagel condensations and isolated as their PF6− salts. These compounds have been characterized by using various techniques including 1H NMR and IR spectroscopies and electrospray mass spectrometry. UV–vis absorption spectra recorded in acetonitrile are dominated by intense, low energy π → π* intramolecular charge-transfer (ICT) bands, and replacing Me with Ph increases the ICT energies. Cyclic voltammetric studies show irreversible reduction processes, together with oxidation waves that are irreversible for R = Me, but reversible for R = Ph. Single crystal X-ray structures have been determined for three of the methyl ester-substituted stilbazolium salts and for the Cl− salts of their picolinium precursors. Time-dependent density functional theory calculations afford reasonable predictions of ICT energies, but greater rigour is necessary for –NPh2 derivatives. The four new acid-functionalized dyes give moderate sensitization efficiencies (ca. 0.2%) when using TiO2-based photoanodes, with relatively higher values for R = Ph vs Me, while larger efficiencies (up to 0.8%) are achieved with ZnO substrates
Properties of adhesive films used in cultural assets
The hygroscopic nature of wood leads to large moisture fluctuations in the material that may influence the mechanical performance of glued wood products. Adhesives based on bone, fish and hide have a long tradition for the gluing of wood and can be found in wooden structures in our cultural heritage. In this study, selected sorptive and mechanical properties of animal adhesives have been compiled and compared to those of synthetic polyurethane adhesives. Bone, fish and hide adhesives show a high moisture uptake at high relative humidity, which confirms the low moisture resistance of such adhesives. The modulus of elasticity and ultimate tensile strength of the films based on animal adhesives are considerably reduced when the moisture content is increased.Validerad;2022;Nivå 2;2022-03-24 (hanlid);Funder: OP RDE (CZ.02.1.01/0.0/0.0/16_019/0000803); Swiss National Science Foundation (SNF CRSI22_125184/1)CT WOO