Characterization of the near-surface nanocrystalline microstructure of ultrasonically treated Ti-6Al-4V using ASTAR™/precession electron diffraction technique

The surface of Ti-6Al-4V was treated mechanically by applying ultrasonic nanocrystal surface modification. The effect of this treatment on the hardness, compressive residual stresses and fatigue performance were investigated. It is shown that in terms of the measured nanoindentation hardness values and the presence of compressive residual stresses, the treated sample only differed from the as-received sample in the first 200–300 µm area far from the surface. Also, the microstructure very close to the treated surface (\u3c5 µm) was characterized using a relatively new transmission orientation microscopy technique named ASTAR™/precession electron diffraction. Based on different types of results (e.g., index map and virtual bright field image) acquired by this technique, it is concluded that titanium grains smaller than 10 nm exist within the distance of less than 1 µm from the treated surface. Difficulties associated with ASTAR™/precession electron diffraction technique to characterize this challenging near-surface area are discussed

Observation of Precipitation Evolution in Fe-Ni-Mn-Ti-Al Maraging Steel by Atom Probe Tomography

We describe the full decomposition sequence in an Fe-Ni-Mn-Ti-Al maraging steel during isothermal annealing at 550 °C. Following significant pre-precipitation clustering reactions within the supersaturated martensitic solid solution, (Ni,Fe)3Ti and (Ni,Fe)3(Al,Mn) precipitates eventually form after isothermal aging for ~60 seconds. The morphology of the (Ni,Fe)3Ti particles changes gradually during aging from predominantly plate-like to rod-like, and, importantly, Mn and Al were observed to segregate to these precipitate/matrix interfaces. The (Ni,Fe)3(Al,Mn) precipitates occurred at two main locations: uniformly within the matrix and at the periphery of the (Ni,Fe)3Ti particles. We relate this latter mode of precipitation to the Mn-Al segregation

Doing synthetic biology with photosynthetic microorganisms

The use of photosynthetic microbes as synthetic biology hosts for the sustainable production of commodity chemicals and even fuels has received increasing attention over the last decade. The number of studies published, tools implemented, and resources made available for microalgae have increased beyond expectations during the last few years. However, the tools available for genetic engineering in these organisms still lag those available for the more commonly used heterotrophic host organisms. In this mini-review, we provide an overview of the photosynthetic microbes most commonly used in synthetic biology studies, namely cyanobacteria, chlorophytes, eustigmatophytes and diatoms. We provide basic information on the techniques and tools available for each model group of organisms, we outline the state-of-the-art, and we list the synthetic biology tools that have been successfully used. We specifically focus on the latest CRISPR developments, as we believe that precision editing and advanced genetic engineering tools will be pivotal to the advancement of the field. Finally, we discuss the relative strengths and weaknesses of each group of organisms and examine the challenges that need to be overcome to achieve their synthetic biology potential.Peer reviewe

Solution–Membrane Equilibrium at Metal-Deposited Cation-Exchange Membranes: Chronopotentiometric Characterization of Metal-Modified Membranes

Copper- and lead-deposited interpolymer cationic membranes have been prepared by electroless plating by an ion-exchange method and characterized by chronopotentiometry and cyclic voltammetry. The parameters such as transition time (t), It1/2, the potential drop (E0) across these membranes immediately after the application of constant current (I), and the height of the potential jump (DE) across the membrane at t have been measured by chronopotentiometry and compared with those of plain membranes. The approximate percentage of metal coverage and the number of ionic sites masked by the deposited metal in terms of NaCl concentration have been estimated from the differences in It1/2 values of plain and metal-deposited membranes. The quantity of metal deposited in a unit area of the membrane surface was measured by differential pulse polarography. The oxidation and reduction peak potentials corresponding to Cu(0)/Cu(II) and Pb(0)/Pb(II) couples were identified by cyclic voltammetry at pH 2.8 and 4.5 of 0.2 M CH3COONa–H2SO4

Dislocation-solute atom interactions in alloys. Technical progress report, February 1, 1973--January 31, 1974

Research is reported in: alloy hardening and softening in bcc metals, effects of solute gradients on strengthening in bcc materials 10 in Nb), mechanical behavior of hydrogenated bcc metals, carbon-vacancy interactions in austenitic alloys, and Snoek anisotrophy in bcc metals. (10 figures, 40 references) (DJC

Characterization of the near-surface nanocrystalline microstructure of ultrasonically treated Ti-6Al-4V using ASTAR™/precession electron diffraction technique

The surface of Ti-6Al-4V was treated mechanically by applying ultrasonic nanocrystal surface modification. The effect of this treatment on the hardness, compressive residual stresses and fatigue performance were investigated. It is shown that in terms of the measured nanoindentation hardness values and the presence of compressive residual stresses, the treated sample only differed from the as-received sample in the first 200–300 µm area far from the surface. Also, the microstructure very close to the treated surface (This is a manuscript of an article published as Ghamarian, I., P. Samimi, A. Telang, V. K. Vasudevan, and P. C. Collins. "Characterization of the near-surface nanocrystalline microstructure of ultrasonically treated Ti-6Al-4V using ASTAR™/precession electron diffraction technique." Materials Science and Engineering: A 688 (2017): 524-531. doi: 10.1016/j.msea.2017.02.029. Posted with permission.</p