Las personas y su identidad.

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Viabilidad de la implantación de sistemas de cerramiento total para reducir las emisiones difusas de partículas

Tras la entrada en vigor de la Directiva de Prevención y Control Integrados de la Contaminación (Directiva IPPC) las actividades afectadas por la misma, incluidas las del sector cerámico, se han visto obligadas a controlar la emisión de partículas difusas mediante la implantación de medidas correctoras, que en muchos casos suponen un impacto económico significativo. En los casos más exigentes, las Autorizaciones Ambientales Integradas (AAIs) otorgadas a empresas del sector cerámico requieren el cerramiento total de las operaciones de gestión de materias primas. En el presente trabajo se evalúa la viabilidad técnica, económica y ambiental de la implantación de un sistema de cerramiento o confinamiento total como medida de reducción de emisiones difusas al considerarse una de las Mejores Técnicas Disponibles (MTDs). El estudio se ha realizado sobre una instalación de fabricación de gránulo atomizado considerando las operaciones de recepción, gestión y almacenamiento de materias primas.Peer reviewe

Prevalence of vertebral fractures in women and men in the population-based Tromsø Study

<p>Abstract</p> <p>Background</p> <p>Osteoporotic vertebral fractures are, as the hip fractures, associated with increased morbidity and mortality. Norway has one of the highest reported incidences of hip fractures in the world. Because of methodological challenges, vertebral fractures are not extensively studied. The aim of this population based study was to describe, for the first time, the age- and sex specific occurrence of osteoporotic vertebral fractures in Norway.</p> <p>Methods</p> <p>Data was collected in the Tromso Study, 2007/8 survey. By the use of dual x-ray absorptiometry (GE Lunar Prodigy) vertebral fracture assessments were performed in 2887 women and men aged from 38 to 87 years, in addition to measurements of bone mineral density at the femoral sites. Information on lifestyle was collected through questionnaires. Comparisons between fractures and non-fractures were done sex stratified, by univariate analyses, adjusting for age when relevant.</p> <p>Results</p> <p>The prevalence of vertebral fractures varied from about 3% in the age group below 60 to about 19% in the 70+ group in women, and from 7.5% to about 20% in men, with an overall prevalence of 11.8% in women and 13.8% in men (<it>p </it>= 0.07). Among those with fractures, only one fracture was the most common; two and more fractures were present in approximately 30% of the cases. Fractures were seen from the fourth lumbar to the fifth thoracic vertebrae, most common between first lumbar and sixth thoracic vertebrae. The most common type of fracture was the wedge type in both sexes. Bone mineral density at the hip differed significantly according to type of fracture, being highest in those with wedge fractures and lowest in those with compression fractures.</p> <p>Conclusions</p> <p>The prevalence of vertebral fractures increased by age in women and men, but the overall prevalence was lower than expected, considering the high prevalence of hip and forearm fractures in Norway. In both sexes, the wedge type was the fracture type most frequently observed and most common in the thoracic region.</p

Reductio ad vacuum

Cartesianism was always a subject to Wittgenstein's criticism. In his case against it, he employed a general strategy that I have called "Reductio ad vacuum". There is something right in Cartesianism but without a hidden confusing premise, the truth of Cartesianism is empty. According to the early Wittgenstein, Cartesianism was right be-cause Solipsism is true: the Self is the center of the world. But without confusing this metaphysical Self with the psychological one, Solipsism becomes empty and no different from Realism

Reductio ad vacuum

Cartesianism was always a subject to Wittgenstein's criticism. In his case against it, he employed a general strategy that I have called "Reductio ad vacuum". There is something right in Cartesianism but without a hidden confusing premise, the truth of Cartesianism is empty. According to the early Wittgenstein, Cartesianism was right be-cause Solipsism is true: the Self is the center of the world. But without confusing this metaphysical Self with the psychological one, Solipsism becomes empty and no different from Realism

Substrate-induced cooperative effects in water adsorption from density functional calculations

9 páginas, 6 figuras, 2 tablas.-- PACS number(S): 33.15.Fm, 68.43.-h, 33.15.KrDensity functional theory calculations are used to investigate the role of substrate-induced cooperative effects on the adsorption of water on a partially oxidized transition-metal surface, O(2×2)/Ru(0001). Focusing particularly on the dimer configuration, we analyze the different contributions to its binding energy. A significant reinforcement of the intermolecular hydrogen bond (H bond), also supported by the observed frequency shifts of the vibration modes, is attributed to the polarization of the donor molecule when bonded to the Ru atoms in the substrate. This result is further confirmed by our calculations for a water dimer interacting with a small Ru cluster, which clearly show that the observed effect does not depend critically on fine structural details and/or the presence of coadsorbates. Interestingly, the cooperative reinforcement of the H bond is suppressed when the acceptor molecule, instead of the donor, is bonded to the surface. This simple observation can be used to rationalize the relative stability of different condensed structures of water on metallic substrates.We acknowledge support from Basque Departamento de Educación, UPV/EHU (Grant No. IT-366-07), the Spanish Ministerio Innovación y Ciencia (Grant No. FIS2007-66711- C02-00), and the ETORTEK research program funded by the Basque Departamento de Industria and the Diputación Foral de Guipúzcoa. M.V.F.-S. acknowledges support from DOE under Grant No. DE-FG02-09ER16052.Peer reviewe

Effectiveness of nanoparticle exposure mitigation measures in industrial settings

International audienc

Workplace Exposure to Nanoparticles during Thermal Spraying of Ceramic Coatings

Thermal spraying is widely used for industrial-scale application of ceramic coatings onto metallic surfaces. The particular process has implications for occupational health, as the high energy process generates high emissions of metal-bearing nanoparticles. Emissions and their impact on exposure were characterized during thermal spraying in a work environment, by monitoring size-resolved number and mass concentrations, lung-deposited surface area, particle morphology, and chemical composition. Along with exposure quantification, the modal analysis of the emissions assisted in distinguishing particles from different sources, while an inhalation model provided evidence regarding the potential deposition of particulate matter on human respiratory system. High particle number (>106 cm-3; 30-40 nm) and mass (60-600 µgPM1 m-3) concentrations were recorded inside the spraying booths, which impacted exposure in the worker area (104-105 cm-3, 40-65 nm; 44-87 µgPM1 m-3). Irregularly-shaped, metal-containing particles (Ni, Cr, W) were sampled from the worker area, as single particles and aggregates (5-200 nm). Energy dispersive X-ray analysis confirmed the presence of particles originated from the coating material, establishing a direct link between the spraying activity and exposure. In particle number count, 90% of the particles were between 26-90 nm. Inhaled dose rates, calculated from the exposure levels, resulted in particle number rates (n˙) between 353 × 106-1024 × 106 min-1, with 70% of deposition occurring in the alveolar region. The effectiveness of personal protective equipment (FPP3 masks) was tested under real working conditions. The proper sealing of the spraying booths was identified as a key element for exposure reduction. This study provides high time-resolved aerosol data which may be valuable for validating indoor aerosol models applied to risk assessment