Inorganic Chemistry in the Mountain Critical Zone : Are the mountain water towers of contemporary society under threat by trace contaminants ?

Potentially harmful trace elements (PHTEs) do not accumulate homogeneously over mountainous area. Generally, highland areas receive more wet deposition, aerosols, and ions than surrounding lowlands ones, mainly due to orographic enhancement. Within mountainous areas, however, the accumulation of PHTEs is much more complex. Direct cloud deposition of contaminants could act as an important pathway of deposition either from a regional low-altitude, cloud level, orographic clouds, or haze whose frequency of occurrence is much higher than surrounding lowlands areas. The accumulation legacy of PHTEs from local human activities should also be considered when investigating PHTE distribution in mountainous areas. Combined with other phenomena, the PHTE accumulation patterns could be highly variable depending on local topography, dominant winds, and vegetation cover, as well as present and past local practices. Despite their remoteness, mountain ecosystems are highly sensitive to PHTEs loadings

Numerical model validation for mooring systems: Method and application for wave energy converters

PublishedArticleMooring systems are key sub-systems of wave energy devices. The design of mooring systems is challenging because overdesign of the mooring system incurs a significant cost penalty, while underdesign may lead to a premature failure. Incorrect design could also reduce the power production. It is therefore important to develop mooring systems which are specific for wave energy applications. In particular, very compliant mooring systems which allow the system to be highly dynamic are being developed. The validation of numerical models with data from physical experiments would facilitate the development of appropriate mooring solutions. This paper presents tank test results for a scale model of the buoy and mooring used at the South West Mooring Test Facility (SWMTF), an offshore facility developed to conduct long-term sea trials for wave energy device moorings. The mooring system investigated is a compliant 3 leg catenary mooring system using Nylon ropes in the water column. Preliminary static, quasi-static, decay, regular and irregular wave tests were conducted on the 1:5 scale model, using the Ifremer basin in Brest. A corresponding numerical model was developed with a time-domain mooring modelling tool, inputting hydrodynamic data from a radiation/diffraction potential modelling program. After the calibration of several hydrodynamic parameters (added mass, damping and mean drift), the numerical model demonstrated good agreement with the experiment, providing an accurate prediction of the maximum mooring loads in irregular waves. However, results show large differences with the field test results, mainly because of the anchor position. The methods and procedures presented will allow the effective validation of numerical models to enable the development of appropriate mooring systems in wave energy applications.The authors acknowledge the support of the MERiFIC (4122) project partners (Marine Energy in Far Peripheral and Island Communities, http://www.merific.eu) and of MARINET, a European Community Research Infrastructure Action under the FP7 Capacities Specific Programme (262552) (www.fp7-marinet.eu). The authors would like to acknowledge the support of the South West Regional Development Agency for its support through the PRIMaRE institution and the support towards the FabTest through the Regional Growth Fund. The authors are grateful for the valuable support of the Ifremer team: Emmanuel Mansuy, Aurélien Tancray, Christophe Maisondieu and Peter Davies. The authors also want to thank Orcina for their technical support

A Novel ARX-Based Approach for the Steady-State Identification Analysis of Industrial Depropanizer Column Datasets

This paper introduces a novel steady-state identification (SSI) method based on the auto-regressive model with exogenous inputs (ARX). This method allows the SSI with reduced tuning by analyzing the identifiability properties of the system. In particular, the singularity of the model matrices is used as an index for steady-state determination. In this contribution, the novel SSI method is compared to other available techniques, namely the F-like test, wavelet transform and a polynomial-based approach. These methods are implemented for SSI of three different case studies. In the first case, a simulated dataset is used for calibrating the output-based SSI methods. The second case corresponds to a literature nonlinear continuous stirred-tank reactor (CSTR) example running at different steady states in which the ARX-based approach is tuned with the available input-output data. Finally, an industrial case with real data of a depropanizer column from PETROBRAS S.A. considering different pieces of equipment is analyzed. The results for a reflux drum case indicate that the wavelet and the F-like test can satisfactorily detect the steady-state periods after careful tuning and when respecting their hypothesis, i.e., smooth data for the wavelet method and the presence of variance in the data for the F-like test. Through a heat exchanger case with different measurement frequencies, we demonstrate the advantages of using the ARX-based method over the other techniques, which include the aspect of online implementation

Weblab France-Brésil en génie des procédés

A Weblab is an experiment remotely operated via internet. A Weblab between the Chemical Engineering Department of the University of São Paulo Polytechnic School (EPUSP) and the Process Engineering Department of the Ecole Nationale Supérieurs d’Ingénieurs en Arts Chimiques et Technologiques (ENSIACET) is developed. The experiment consists of a tank level control. The main objective is to propose and test tunings for the system control loop. For this purpose, the students must work in synergy and propose models for the system in order to find the tuning parameters. Weblab is a showcase for new technologies and original experiences because it allows to perform a control action from anywhere in a supervision environment which is spreading out in the industry. The objectives and interests are mainly pedagogical as the Weblab favours the variety and diversity of intercultural experiences a student could experience during his undergraduate studies. Because of this, the Weblab perfectly integrates in an engineer curriculum that is open to international exchanges. Un WebLab est une installation commandée à distance via internet. Nous développons une expérience de Weblab entre le département de Génie Chimique de l’Ecole Polytechnique de l’Université de São Paulo (EPUSP) et le département Génie des Procédés et Informatique de l’Ecole Nationale Supérieurs d’Ingénieurs en Arts Chimiques et Technologiques (ENSIACET). L’expérience consiste en la régulation de niveau dans un bac. L’objectif de l’expérience est de proposer et de valider des réglages pour la boucle de commande du système. Pour cela, les étudiants de l’EPUSP et de l’ENSIACET doivent travailler en synergie et proposer des modélisations et un réglage du contrôleur. Le Weblab constitue une vitrine de technologies innovantes et d’expériences originales, car il permet, depuis n’importe où, d’effectuer une commande à distance dans un environnement de supervision qui est de plus en plus adopté dans l’industrie. Les objectifs et intérêts du WebLab se situent plutôt au niveau pédagogique car il peut être un facteur multiplicatif du nombre d’expériences interculturelles pouvant être vécues par un étudiant tout au long de son cursus. Pour ces raisons le Weblab s’intègre parfaitement dans une formation d’ingénieurs qui se doit d’être ouverte à l’international

Cosmic rays beyond the boundary of the heliosphere

In August of 2012 the Voyager 1 space probe has left the solar-wind bubble of ionized gas we call the heliosphere and entered the denser and colder environment of the interstellar cloud surrounding the solar system. Energetic charged particles underwent dramatic changes past the heliopause: the heliospheric ions disappeared completely, while the galactic cosmic rays were for the first time measured in their unmodulated state. The interstellar medium turned out to be almost entirely devoid of turbulent magnetic fluctuations, therefore the transport of cosmic rays is governed by a large-scale geometry of the magnetic field. We discuss observations of heliospheric ions, including anomalous cosmic rays, near the heliopause transition, and propose interpretations of the measured intensities and pitch-angle distributions based on gradient drift in a weakly nonuniform magnetic field. The heliopause transition appears to be permeated by magnetic flux tubes connected to the interstellar space and facilitating particle escape. These flux tubes may be a product of interchange instability driven by a plasma pressure gradient across the heliopause. The curvature of magnetic field lines and the anti-sunward gradient in plasma kinetic pressure provide conditions favorable for an interchange. The two flux tube crossings by the spacecraft allowed an indirect measurement of the plasma radial velocity near the heliopause

Energetic Particle Anisotropies at the Heliospheric Boundary. II. Transient Features and Rigidity Dependence

In the preceding paper, we showed that large second-order anisotropies of heliospheric ions measured by the Voyager 1 space probe during the August 2012 boundary crossing event could be explained by a magnetic shear across the heliopause preventing particles streaming along the magnetic field from escaping the inner heliosheath. According to Stone et al., the penetration distance of heliospheric ions into the outer heliosheath had a strong dependence on the particle's Larmor radius. By comparing hydrogen, helium, and oxygen ions with the same energy per nucleon, these authors argued that this effect must be attributed to larger cyclotron radii of heavier species rather than differences in velocity. We propose that gradient drift in a nonuniform magnetic field was the cause of both the large second-order anisotropies and the spatial differentiation based on the ion's rigidity. A latitudinal gradient of magnetic field strength of about 10% per AU between 2012.7 and 2012.9 could have provided drift motion sufficient to match both LECP and CRS Voyager 1 observations. We explain the transient intensity dropout observed prior to the heliocliff using flux tube structures embedded in the heliosheath and magnetically connected to interstellar space. Finally, this paper reports a new indirect measurement of the plasma radial velocity at the heliopause on the basis of the time difference between two cosmic-ray telescopes measuring the same intensity dropout

Lizard epidermal gland secretions II : chemical characterization of the generation gland secretion of the sungazer, Cordylus giganteus

The original publication is available at http://pubs.acs.org/doi/full/10.1021/np1008366In lizards, the epidermal glands of the femoral and precloacal regions are involved in the production of semiochemicals. In addition to its femoral glands, the giant girdled lizard, or sungazer, Cordylus giganteus, which is endemic to South Africa, has generation glands as an additional potential source of semiochemicals. These epidermal glands are described as glandular scales that overlay the femoral glands and are included in the normal epidermal profile located in the femoral (thigh) and anterior antebrachial (fore-leg) regions of the male sungazer. GC-MS analysis of the generation gland secretions and the trimethylsilyl derivatives of some of the steroidal constituents was employed to identify 59 constituents, including alkenes, carboxylic acids, alcohols, ketones, aldehydes, esters, amides, nitriles, and steroids. The quantitative differences of the volatile constituents of the fore- and hind-leg generation glands were compared between individuals. This is the first report on the chemical composition of generation glandular material of lizards. © 2011 The American Chemical Society and American Society of Pharmacognosy.Post-prin

The appropriateness of patients' visits to an emergency department.

Aim: The appropriateness of patient visits to an emergency unit was investigated in this study. Method: This descriptive study included 2968 patient cards from the National District Hospital, Bloemfontein emergency unit during 2003. Patient information was evaluated according to predetermined criteria to determine whether a visit was appropriate or not. Results: The patient's ages varied between 0 to 97 years (median 29 year) and 50.8% was female. Informal residencies presented 26.4% of patient's neighbourhoods. The most common chronic condition was hypertension (7.9%). Only 8.4% of patients already used medication for their presenting condition. Most (72.4%) patients presented after hours and 36.6% presented during weekends. The total number of injuries was 22.9% and 75.6% were examined for medical or surgical problems. The criterion with the most visits was the trauma category (21.8%). The criterion with the least patients (0.3%) was the criterion for significant bleeding. According to the results more than a third (35.4% ; 95% CI 33.7% ; 37.2%) of the patient visits can be seen as inappropriate. Conclusion: The emergency unit is used inappropriately South African Family Practice Vol. 49 (4) 2007: pp. 1

Estimating the carbon content of the deep mantle with Icelandic melt inclusions

Earth’s carbon budget is central to our understanding of the long-term co-evolution of life and the planet. Direct observations of surface reservoirs allow for the detailed quantification of their carbon content. However, the carbon content of Earth’s deep interior remains poorly constrained. Here we study olivine-hosted melt inclusions from two Icelandic eruptions, with those from the Miðfell eruption allowing us to investigate the carbon content of the deep mantle. Comparison with the previously studied Borgarhraun eruption highlights the presence of deep, plume-sourced mantle material within the Miðfell source region. Miðfell contains trace element-depleted melt inclusions undersaturated in CO2, which have high CO2/Ba (= 396 ± 48) and CO2/Nb (= 1832 ± 316), though some inclusions preserve even greater relative carbon enrichment. These observations allow us to reconstruct the CO2 content of the bulk Miðfell source as being > 690 ppm. By identifying that Miðfell is a mixture of depleted and deep mantle components, we can estimate a CO2 content for the deep mantle component of 1350 ± 350 ppm; a concentration that is over ten times higher than depleted MORB mantle estimates. Assuming that the deep mantle component identified in Miðfell is representative of a global reservoir, then with our new CO2 estimate and by considering a range of representative mantle fractions for this reservoir, we calculate that it contains up to 14 times more carbon than that of the atmosphere, oceans, and crust combined. Our result of elevated CO2/Ba and CO2/Nb ratios, and carbon enrichment support geochemical bulk Earth carbon models that call for the presence of carbon-rich deep mantle domains to balance Earth’s relatively carbon-poor upper mantle and surface environment

Numerical model validation for mooring systems: Method and application for wave energy converters

Copyright © 2015 Elsevier. NOTICE: this is the author’s version of a work that was accepted for publication in Renewable Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Renewable Energy Vol. 75 (2015), DOI: 10.1016/j.renene.2014.10.063The design of wave energy mooring systems is challenging: overdesign incurs a significant cost penalty, underdesign may lead to a premature failure and incorrect design could reduce the power production. Consequently, compliant mooring systems are being developed for wave energy applications. This paper presents tank test results for a scale model of the buoy and mooring used at the South West Mooring Test Facility (SWMTF), an offshore facility developed to conduct long-term sea trials for wave energy device moorings. A compliant three leg catenary mooring system using Nylon ropes in the water column is investigated. Preliminary static, quasi-static, decay, regular and irregular wave tests were conducted on the 1:5 scale model, using the Ifremer basin in Brest. A corresponding numerical model was developed with a time-domain mooring modelling tool, inputting hydrodynamic data from a radiation/diffraction potential modelling program. After the calibration of several hydrodynamic parameters, the numerical model demonstrated good agreement with the experiment. However, numerical results show large differences with the field test results, mainly because of unknowns in the anchor position. The methods and procedures presented will allow the effective validation of numerical models to enable the development of appropriate mooring systems in wave energy applications.MERiFICMARINETPRIMaR