804 research outputs found
Spectral signatures of photosynthesis I: Review of Earth organisms
Why do plants reflect in the green and have a 'red edge' in the red, and
should extrasolar photosynthesis be the same? We provide: 1) a brief review of
how photosynthesis works; 2) an overview of the diversity of photosynthetic
organisms, their light harvesting systems, and environmental ranges; 3) a
synthesis of photosynthetic surface spectral signatures; 4) evolutionary
rationales for photosynthetic surface reflectance spectra with regard to
utilization of photon energy and the planetary light environment. Given the
surface incident photon flux density spectrum and resonance transfer in light
harvesting, we propose some rules with regard to where photosynthetic pigments
will peak in absorbance: a) the wavelength of peak incident photon flux; b) the
longest available wavelength for core antenna or reaction center pigments; and
c) the shortest wavelengths within an atmospheric window for accessory
pigments. That plants absorb less green light may not be an inefficient legacy
of evolutionary history, but may actually satisfy the above criteria.Comment: 69 pages, 7 figures, forthcoming in Astrobiology March 200
Proton transfer reactions of N-aryl triazolium salts: unusual ortho-substituent effects
Previous studies of the C(3)-hydrogen/deuterium exchange reactions of the triazolium ion conjugate acids of triazolyl N-heterocyclic carbenes revealed a change of mechanism under acidic conditions with N1-protonation to a dicationic salt. Interestingly, the data suggested an increase in pKaN1 in the presence of a N-pentafluorophenyl substituent relative to other N-aryl substituents with hydrogens or methyl substituents rather than fluorines at the ortho-positions. To probe the presence of an apparent donor effect of a N-pentafluorophenyl substituent, which differs from the more common electron withdrawing effect of this group, we have studied the analogous deuterium exchange reactions of four triazolium salts with heteroatoms or heteroatom substituents in the 2-position and/or 6-position of the N-aryl ring. These include triazolium salts with N-2,4,6-tribromophenyl 11, N-2,6-dichlorophenyl 12, N-2-pyridyl 13 and N-2-pyrimidinyl 14 substituents. The log kex – pD profiles for 11, 12 and 14 were found to show similar trends at lower pDs as for the previously studied N-pentafluorophenyl triazolium salt, hence supporting the presence an apparent donor effect on pKaN1. Surprisingly, the log kex – pD profile for N-pyridyl salt 13 uniquely showed acid catalysis at lower pDs. We propose herein that this data is best explained by invoking an intramolecular general base role for the N-(2-pyridyl) substituent in conjunction with N1-protonation on the triazolium ring. Finally, the second order rate constants for deuteroxide ion catalysed C(3)-H/D exchange (kDO, M−1 s−1), which could be obtained from data at pDs >1.5, were used to provide estimates of C(3)-carbon acid pKaC3 values for the four triazolium salts 11, 12, 13, 14
Earthshine observation of vegetation and implication for life detection on other planets - A review of 2001 - 2006 works
The detection of exolife is one of the goals of very ambitious future space
missions that aim to take direct images of Earth-like planets. While
associations of simple molecules present in the planet's atmosphere (,
, etc.) have been identified as possible global biomarkers, we
review here the detectability of a signature of life from the planet's surface,
i.e. the green vegetation. The vegetation reflectance has indeed a specific
spectrum, with a sharp edge around 700 nm, known as the "Vegetation Red Edge"
(VRE). Moreover vegetation covers a large surface of emerged lands, from
tropical evergreen forest to shrub tundra. Thus considering it as a potential
global biomarker is relevant. Earthshine allows to observe the Earth as a
distant planet, i.e. without spatial resolution. Since 2001, Earthshine
observations have been used by several authors to test and quantify the
detectability of the VRE in the Earth spectrum. The egetation spectral
signature is detected as a small 'positive shift' of a few percents above the
continuum, starting at 700 nm. This signature appears in most spectra, and its
strength is correlated with the Earth's phase (visible land versus visible
ocean). The observations show that detecting the VRE on Earth requires a
photometric relative accuracy of 1% or better. Detecting something equivalent
on an Earth-like planet will therefore remain challenging, moreover considering
the possibility of mineral artifacts and the question of 'red edge'
universality in the Universe.Comment: Invited talk in "Strategies for Life Detection" (ISSI Bern, 24-28
April 2006) to appear in a hardcopy volume of the ISSI Space Science Series,
Eds, J. Bada et al., and also in an issue of Space Science Reviews. 13 pages,
8 figures, 1 tabl
Analyzing the Use of Gaseous Helium as a Pressurant with Cryogenic Propellants with Thermodynamic Venting System Modelling and Test Data
Cryogens are viable candidate propellants for NASA's Lunar and Mars exploration programs. To provide adequate mass flow to the system's engines and/or to prevent feed system cavitation, gaseous helium (GHe) is frequently considered as a pressurant. During low gravity operations, a Thermodynamic Venting System (TVS) is designed to maintain tank pressure during low gravity operations without propellant resettling. Therefore, a series of tests were conducted in the Multi-purpose Hydrogen Test Bed (MHTB) of Marshall Space Flight Center (MSFC) in order to evaluate the effects of GHe pressurant on pressure control performance of a TVS with liquid hydrogen (LH2) and nitrogen (LN2) as the test liquids. The TVS used in these test series consists of a recirculation pump, Joule-Thomson (J-T) expansion valve, and a parallel flow concentric tube heat exchanger combined with a longitudinal spray bar. Using a small amount of liquid extracted from the tank recirculation line, passing it through the J-T valve, and then through the heat exchanger, thermal energy is extracted from the bulk liquid and ullage thereby enabling pressure control. The LH2/GHe tests were performed at fill levels of 90%, 50%, and 25% and LN2/GHe tests were conducted at fill levels of 50% and 25%. Moreover, each test was conducted with a specified tank ullage pressure control band. A one-dimensional TVS performance program was used to analyze and correlate the test data. Predictions and comparisons with test data of ullage pressure and temperature and bulk liquid saturation pressure and temperature with test data are presented
The Primordial Inflation Explorer (PIXIE): A Nulling Polarimeter for Cosmic Microwave Background Observations
The Primordial Inflation Explorer (PIXIE) is an Explorer-class mission to
measure the gravity-wave signature of primordial inflation through its
distinctive imprint on the linear polarization of the cosmic microwave
background. The instrument consists of a polarizing Michelson interferometer
configured as a nulling polarimeter to measure the difference spectrum between
orthogonal linear polarizations from two co-aligned beams. Either input can
view the sky or a temperature-controlled absolute reference blackbody
calibrator. PIXIE will map the absolute intensity and linear polarization
(Stokes I, Q, and U parameters) over the full sky in 400 spectral channels
spanning 2.5 decades in frequency from 30 GHz to 6 THz (1 cm to 50 um
wavelength). Multi-moded optics provide background-limited sensitivity using
only 4 detectors, while the highly symmetric design and multiple signal
modulations provide robust rejection of potential systematic errors. The
principal science goal is the detection and characterization of linear
polarization from an inflationary epoch in the early universe, with
tensor-to-scalar ratio r < 10^{-3} at 5 standard deviations. The rich PIXIE
data set will also constrain physical processes ranging from Big Bang cosmology
to the nature of the first stars to physical conditions within the interstellar
medium of the Galaxy.Comment: 37 pages including 17 figures. Submitted to the Journal of Cosmology
and Astroparticle Physic
Palaeoproterozoic magnesite: lithological and isotopic evidence for playa/sabkha environments
Magnesite forms a series of 1- to 15-m-thick beds within the approximate to2.0 Ga (Palaeoproterozoic) Tulomozerskaya Formation, NW Fennoscandian Shield, Russia. Drillcore material together with natural exposures reveal that the 680-m-thick formation is composed of a stromatolite-dolomite-'red bed' sequence formed in a complex combination of shallow-marine and non-marine, evaporitic environments. Dolomite-collapse breccia, stromatolitic and micritic dolostones and sparry allochemical dolostones are the principal rocks hosting the magnesite beds. All dolomite lithologies are marked by delta C-13 values from +7.1 parts per thousand to +11.6 parts per thousand (V-PDB) and delta O-18 ranging from 17.4 parts per thousand to 26.3 parts per thousand (V-SMOW). Magnesite occurs in different forms: finely laminated micritic; stromatolitic magnesite; and structureless micritic, crystalline and coarsely crystalline magnesite. All varieties exhibit anomalously high delta C-13 values ranging from +9.0 parts per thousand to +11.6 parts per thousand and delta O-18 values of 20.0-25.7 parts per thousand. Laminated and structureless micritic magnesite forms as a secondary phase replacing dolomite during early diagenesis, and replaced dolomite before the major phase of burial. Crystalline and coarsely crystalline magnesite replacing micritic magnesite formed late in the diagenetic/metamorphic history. Magnesite apparently precipitated from sea water-derived brine, diluted by meteoric fluids. Magnesitization was accomplished under evaporitic conditions (sabkha to playa lake environment) proposed to be similar to the Coorong or Lake Walyungup coastal playa magnesite. Magnesite and host dolostones formed in evaporative and partly restricted environments; consequently, extremely high delta C-13 values reflect a combined contribution from both global and local carbon reservoirs. A C- 13-rich global carbon reservoir (delta C-13 at around +5 parts per thousand) is related to the perturbation of the carbon cycle at 2.0 Ga, whereas the local enhancement in C-13 (up to +12 parts per thousand) is associated with evaporative and restricted environments with high bioproductivity
Actinobacillus pleuropneumoniae serovar 8 predominates in England and Wales
This work was supported by a Longer and Larger (LoLa) grant from the Biotechnology and Biological Sciences Research Council (BBSRC grant numbers BB/G020744/1, BB/G019177/1, BB/G019274/1 and BB/G018553/1) and Zoetis (formerly Pfizer Animal Health) awarded to the Bacterial Respiratory Diseases of Pigs-1 Technology (BRaDP1T) Consortium
Variable-range hopping in quasi-one-dimensional electron crystals
We study the effect of impurities on the ground state and the low-temperature
dc transport in a 1D chain and quasi-1D systems of many parallel chains. We
assume that strong interactions impose a short-range periodicicity of the
electron positions. The long-range order of such an electron crystal (or
equivalently, a charge-density wave) is destroyed by impurities. The 3D
array of chains behaves differently at large and at small impurity
concentrations . At large , impurities divide the chains into metallic
rods. The low-temperature conductivity is due to the variable-range hopping of
electrons between the rods. It obeys the Efros-Shklovskii (ES) law and
increases exponentially as decreases. When is small, the metallic-rod
picture of the ground state survives only in the form of rare clusters of
atypically short rods. They are the source of low-energy charge excitations. In
the bulk the charge excitations are gapped and the electron crystal is pinned
collectively. A strongly anisotropic screening of the Coulomb potential
produces an unconventional linear in energy Coulomb gap and a new law of the
variable-range hopping . remains
constant over a finite range of impurity concentrations. At smaller the
2/5-law is replaced by the Mott law, where the conductivity gets suppressed as
goes down. Thus, the overall dependence of on is nonmonotonic.
In 1D, the granular-rod picture and the ES apply at all . The conductivity
decreases exponentially with . Our theory provides a qualitative explanation
for the transport in organic charge-density wave compounds.Comment: 20 pages, 7 figures. (v1) The abstract is abridged to 24 lines. For
the full abstract, see the manuscript (v2) several changes in presentation
per referee's comments. No change in result
A comparative study of electrical potential sensors and Ag/AgCl electrodes for characterising spontaneous and event related electroencephalagram signals
For exactly 90 years researchers have used electroencephalography (EEG) as a window into the activities of the brain. Even now its high temporal resolution coupled with relatively low cost compares favourably to other neuroimaging techniques such as magnetoencephalography (MEG) and functional magnetic resonance imaging (fMRI). For the majority of this time the standard electrodes used for non-invasive monitoring of electrical activities of the brain have been Ag/AgCl metal electrodes. Although these electrodes provide a reliable method for recording EEG they suffer from noise, such as offset potential drift, and usability issues, for example, difficult skin preparation and cross-coupling of adjacent electrodes. In order to tackle these issues a prototype Electric Potential Sensor (EPS) device based on an auto-zero operational amplifier has been developed and evaluated. The absence of 1/f noise in these devices makes them ideal for use with signal frequencies of ~10 Hz or less. The EPS is a novel active ultrahigh impedance capacitively coupled sensor. The active electrodes are designed to be physically and electrically robust and chemically and biochemically inert. They are electrically insulated (anodized) and scalable. A comprehensive study was undertaken to compare the results of neural signals recorded by the EPS with a standard commercial EEG system. These studies comprised measurements of both free running EEG and Event Related Potentials (ERPs). Results demonstrate that the EPS provides a promising alternative, with many added benefits compared to standard EEG sensors, including reduced setup time, elimination of sensor cross-coupling, lack of a ground electrode and distortion of electrical potentials encountered when using standard gel electrodes. Quantitatively, highly similar signals were observed between the EPS and EEG sensors for both free running and evoked brain activity with cross correlations of higher than 0.9 between the EPS and a standard benchmark EEG system. Future developments of EPS-based neuroimaging include the implementation of a whole head ultra-dense EPS array, and the mapping of distributions of scalp recorded electrical potentials remotely
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