Slip distribution inversion by trans-dimensional Monte Carlo sampling: application to the 2009 L’Aquila Earthquake (Central Italy)

Non-uniform slip distribution on a fault plane from geodetic data is usually estimated in two steps. First, the geometric fault parameters are inferred by non -linear inversion assuming a uniform slip on a rectangular fault. A second analysis, based on linear inversion techniques, infers the slip distribution on an arbitrary subdivision of the fault plane into patches. Two main concerns arise. First, the fault geometry determined under the assumption of a uniform slip i s not guaranteed to properly represent the fault geometry for a spatially variable slip distribution. Moreover, an arbitrary fault subdivision into patches u nrelated to the observed data could bias the model resolution, introducing spurious features. In recent years, the availability of large coverage data, such as DInSAR images, improved mapping the coseismic displacements. The large amount of geodetic da ta from the area surrounding earthquake faults allows for improving the slip models and refining the knowledge of earthquake dynamics. Less attention has been given to the development of new inversion algorithms that can resolve the main concerns above. In particular, the question is whether the data themselves ca n constrain the slip model complexity, i.e., the unknown number and distribution of the fault patches needed to fit the observations. The reversible jump Mar kov chain Monte Carlo (RJMCMC) algorithm has been recently introduced in the geosciences to solve a variety of non linear inverse problems. RJMCMC combines a classical Markov chain Monte Carlo method with the ability to shift between models with a different number of unknowns. A posterior probability distribution of the num ber of unknowns is obtained at the end of the Markov chain, so that the model resolution is determined by the observed data. In this study, we apply a RJMCMC method to the Mw 6.3 L’Aquila earthquake that occurred on April 6th 2009 in Central Italy. Three DInSAR images, mapping the c oseismic displacement, are inverted to constrain not only the slip distribution but also the number of unknowns (i.e., the number of fault patches) and the ge ometry of non-rectangular patches

A taxonomic revision of western Eupholidoptera bush crickets (Orthoptera: Tettigoniidae): testing the discrimination power of DNA barcode.

The genus Eupholidoptera includes 46 Mediterranean species distributed from Turkey to Greece, Italy and southern France. In the eastern part of its range, Eupholidoptera has been considered to consist of several distinct species, while in the Balkans and Italian peninsula only E. chabrieri has been recognized. However, the status of some Italian populations, confined to particular geographic areas, remains uncertain. To investigate the delimitation of the Italian taxa of Eupholidoptera, we performed both morphological and molecular analyses. Morphological analysis was carried out by considering diagnostic characters usually used to distinguish different taxa, such as the shape of titillators in males and the subgenital plate in females. Molecular analysis was performed by sequencing three mitochondrial genes: 12S rRNA, 16S rRNA, partially sequenced and the entire gene of cox1 . Molecular markers were used to infer phylogenetic relationships among the Italian Eupholidoptera species and to reconstruct the historical processes that shaped their current geographic distribution. Results from both morphological and molecular analyses were used to revise the taxonomic arrangement of species. On the whole we were able to distinguish nine lineages of Italian Eupholidoptera, of which E. tyrrhenica sp.n. from Corsica is described as a new species

Signal trends of microbial fuel cells fed with different food-industry residues

A microbial fuel cell (MFC) is an anaerobic bioreactor where soluble metabolites liberated by hydrolysis and fermentation of macromolecules are simultaneously available for anode respiring bacteria (ARB). ARB can be influenced by chemical imbalances in the liquid phase of the bioreactor. The objective of the work was to explore the trend of electric signals generated by MFCs, in relation to anaerobic biodegradation of four different solid food-industry residual substrates. Four sets of membraneless single-chamber MFCs were operated in batch mode, with solid waste substrates characterized by a different base component: i) mixed kitchen waste (fibers), ii) whey from dairy industries (sugar), iii) fisheries residues previously processed to recover oils (proteins), iv) pulp waste from citrus juice production (acidic). All the tested MFCs were able to produce an electric output with different trends, depending on the principal component of the solid substrate. MFC potential varied as function of the COD and the feeding cycle, as well as of the substrate. The pH variability during the fermentative process significantly affected the electric output. Citrus (acidic) pulp fed MFCs started to operate only when the pH raised up 6.5. MFCs fed with mix kitchen wastes had a relatively stable electric signal; fish based waste caused spiking in the MFC signal and an averaging in the COD degradation trend. This phenomenon was attributed to a pH instability induced by proteins degradation forming ammonia. The fermentation process was strongly predominant with respect the electrochemical process in MFCs and the coulombic efficiency (CE) was low, ranging between 2 and 10%. This result call for a deeper exploration of harvesting power from solid wastes and pointed also to the possibility of using a MFC to monitor important parameters of fermentation processes in biotech production plants

Analytical and 3-D numerical modelling of Mt. Etna (Italy) volcano inflation

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Crack Growth Studies in Railway Axles under Corrosion Fatigue: Full-scale Experiments and Model Validation

Abstract Crack initiation and growth in full scale railway axle in A1T mild steel have been studied, under three points rotating bending loading conditions and artificial rainwater as corrosive environment. A surface plastic replication technique has been used along with optical microscopy and Scanning Electron Microscopy to monitor the environment assisted fatigue at various stages.A modified Murtaza and Akid empirical model has been employed to predict the corrosion fatigue crack growth rates and a reasonable agreement has been found between experimental and calculated lifetime

Measuring individual overpotentials in an operating solid-oxide electrochemical cell

We use photo-electrons as a non-contact probe to measure local electrical potentials in a solid-oxide electrochemical cell. We characterize the cell in operando at near-ambient pressure using spatially-resolved X-ray photoemission spectroscopy. The overpotentials at the interfaces between the Ni and Pt electrodes and the yttria-stabilized zirconia (YSZ) electrolyte are directly measured. The method is validated using electrochemical impedance spectroscopy. Using the overpotentials, which characterize the cell's inefficiencies, we compare without ambiguity the electro-catalytic efficiencies of Ni and Pt, finding that on Ni H_2O splitting proceeds more rapidly than H2 oxidation, while on Pt, H2 oxidation proceeds more rapidly than H2O splitting.Comment: corrected; Phys. Chem. Chem. Phys., 201

Hydroxyapatite-Based Electrodes for Metal Detection in Wastewater

Hydroxyapatite (HAp) is a biocompatible versatile material of formula Ca10(PO4)6(OH)2, insoluble in water within a wide pH range, chemically stable, relatively cheap and largely available. This mineral calcium phosphate has caught attention of scientists working in different fields of applied science, from medical engineering, to catalysis and pollution remediation. For environmental application, the absorbent nature of HAp is, probably, the most valuable feature. In particular, heavy metal retention ability is attributed to ion-exchange (Ca2+/ metal ion), surface adsorption/complexation, dissolution-precipitation mechanism, with single or combined action depending on the metal nature. Combining intrinsic affinities of HAp for metals with ductility of electrochemistry is a valuable route to develop monitoring systems and/or pollution remediation protocols. In doing so, the main obstacle for the exploitation of HAp as electrode materials is its electrical insulation nature. To overcome this limitation combination with conductive substrate is necessary, preparing either blends or composite materials. In this context, a series of carbon-containing hydroxyapatite composites (C-HAp) have been prepared by co-precipitation synthesis, by varying the conductive carbon source. The prepared materials have been characterized by various physical-chemical techniques (FT-IR spectroscopy, XRPD, TEM-EDX, N2-adsorption/desorption analyses) and the electrical conductivity has been determined as a function of the carbon source. The most promising C-HAp composites have been used as electrode substrates to quantify some of the common heavy metals found in waste water from urban and/or industrial sites (e.g., Pb2+, Cd2+, Cu2+, Zn2+) using cyclic and differential voltammetry techniques. The sensitivity of C-HAp electrodes was compared with that of glassy carbon ones, chosen as reference material. Different electrode geometries have been taken into consideration (C-HAp powder pressed into a cavity electrode, or free-standing C-HAp one). The work is still in progress and among possible alternative routes we are going to prepare directly HAp-based electrodes by in situ electrodeposition of calcium phosphate on low cost electron collectors such as steel. The final aim is to employ the HAp-based electrode as cathode in microbial fuel cells that could act as sensors for the on-line detection of metal traces in the treated wastes

The radio relic in Abell 2256: overall spectrum and implications for electron acceleration

The galaxy cluster Abell 2256 hosts one of the most intriguing examples in the class of radio relics. It has been found that this radio relic has a rather flat integrated spectrum at low frequencies that would imply an injection spectral index for the electrons that is inconsistent with the flattest allowed by the test particle diffusive shock acceleration (DSA). We performed new high-frequency observations at 2273, 2640, and 4850 MHz. Combining these new observations with images available in the literature, we constrain the radio integrated spectrum of the radio relic in Abell 2256 over the widest sampled frequency range collected so far for this class of objects (63 -10450 MHz). Moreover, we used X-ray observations of the cluster to check the temperature structure in the regions around the radio relic. We find that the relic keeps an unusually flat behavior up to high frequencies. Although the relic integrated spectrum between 63 and 10450 MHz is not inconsistent with a single power law with $\alpha_{63}^{10450}= 0.92\pm 0.02$, we find hints of a steepening at frequencies > 1400 MHz. The two frequency ranges 63-1369 MHz and 1369-10450 MHz are, indeed, best represented by two different power laws, with $\alpha_{63}^{1369}= 0.85\pm 0.01$ and $\alpha_{1369}^{10450}= 1.00\pm 0.02$. This broken power law would require special conditions to be explained in terms of test-particle DSA, e.g., non-stationarity of the spectrum and/or non-stationarity of the shock. On the other hand, the single power law would make of this relic the one with the flattest integrated spectrum known so far, even flatter than what allowed in the test-particle approach to DSA. We find a rather low temperature ratio of $T_2/T_1 \sim 1.7$ across the G region of the radio relic and no temperature jump across the H region.Comment: 18 pages, 11 figures, 9 tables. Accepted for publication in Astronomy & Astrophysic

Electrochemical behavior of archaeological arsenical bronzes according to the concentration of arsenic in the alloy|Comportamento elettrochimico di bronzi archeologici arsenicali in funzione della concentrazione dell'arsenico in lega

n questo studio si è voluto comprendere come la concentrazione di arsenico in lega influenzi i fenomeni di corrosione in leghe di rame archeologiche. Sono state condotte analisi elettrochimiche su tre leghe in triplicato (denominate CuAs-1, CuAs-3, CuAs-5 sulla base delle diverse percentuali in peso di As in lega). I risultati elettrochimici, confrontati con quelli di campioni di rame puro, indicano che la presenza di arsenico comporta un sostanziale miglioramento del comportamento a corrosione e la lega migliore è quella con il più alto contenuto di arsenico. Questi dati sono confermati dalle analisi spet- troscopiche che indicano la formazione di uno strato di ossidi protettivi misti di rame e arsenico. La minore resistenza alla corrosione del rame è stata invece collegata alla presenza in superficie di sali solubili