Synthesis and characterisation of LK-99

Recently, two arXiv preprints (arXiv:2307.12008, arXiv:2307.12037) reported signatures of superconductivity above room temperature and at ambient pressure, striking worldwide experimental research efforts to replicate the results3-7, as well as theoretical attempts to explain the purported superconductivity8-12. The material of interest has chemical formula Pb$_{10-x}$Cu$_x$(PO$_4$)$_6$O, where $x \approx 1$, and was named by the authors as LK-99. It belongs to lead apatite family, and was synthesised from two precursors, lanarkite (PbSO$_4\cdot$PbO) and copper phosphide (Cu$_3$P). Here we performed a systematic study on LK-99, starting from solid-state synthesis, followed by characterisation and transport measurements. We did not observe any signatures of superconductivity in our samples of LK-99

Machine learning approach to genome of two-dimensional materials with flat electronic bands

Many-body physics of electron-electron correlations plays a central role in condensed mater physics, it governs a wide range of phenomena, stretching from superconductivity to magnetism, and is behind numerous technological applications. To explore this rich interaction-driven physics, two-dimensional (2D) materials with flat electronic bands provide a natural playground thanks to their highly localised electrons. Currently, thousands of 2D materials with computed electronic bands are available in open science databases, awaiting such exploration. Here we used a new machine learning algorithm combining both supervised and unsupervised machine intelligence to automate the otherwise daunting task of materials search and classification, to build a genome of 2D materials hosting flat electronic bands. To this end, a feedforward artificial neural network was employed to identify 2D flat band materials, which were then classified by a bilayer unsupervised learning algorithm. Such a hybrid approach of exploring materials databases allowed us to reveal completely new material classes outside the known flat band paradigms, offering new systems for in-depth study on their electronic interactions

Magnetization Signature of Topological Surface States in a Non-Symmorphic Superconductor

Superconductors with nontrivial band structure topology represent a class of materials with unconventional and potentially useful properties. Recent years have seen much success in creating artificial hybrid structures exhibiting the main characteristics of 2D topological superconductors. Yet, bulk materials known to combine inherent superconductivity with nontrivial topology remain scarce, largely because distinguishing their central characteristic—the topological surface states—has proved challenging due to a dominant contribution from the superconducting bulk. In this work, a highly anomalous behavior of surface superconductivity in topologically nontrivial 3D superconductor In2Bi, where the surface states result from its nontrivial band structure, itself a consequence of the non-symmorphic crystal symmetry and strong spin–orbit coupling, is reported. In contrast to smoothly decreasing diamagnetic susceptibility above the bulk critical field, Hc2, as seen in conventional superconductors, a near-perfect, Meissner-like screening of low-frequency magnetic fields well above Hc2 is observed. The enhanced diamagnetism disappears at a new phase transition close to the critical field of surface superconductivity, Hc3. Using theoretical modeling, the anomalous screening is shown to be consistent with modification of surface superconductivity by the topological surface states. The possibility of detecting signatures of the surface states using macroscopic magnetization provides a new tool for the discovery and identification of topological superconductor

Magnetization Signature of Topological Surface States in a Non-Symmorphic Superconductor

Superconductors with nontrivial band structure topology represent a class of materials with unconventional and potentially useful properties. Recent years have seen much success in creating artificial hybrid structures exhibiting the main characteristics of 2D topological superconductors. Yet, bulk materials known to combine inherent superconductivity with nontrivial topology remain scarce, largely because distinguishing their central characteristic—the topological surface states—has proved challenging due to a dominant contribution from the superconducting bulk. In this work, a highly anomalous behavior of surface superconductivity in topologically nontrivial 3D superconductor In2Bi, where the surface states result from its nontrivial band structure, itself a consequence of the non-symmorphic crystal symmetry and strong spin–orbit coupling, is reported. In contrast to smoothly decreasing diamagnetic susceptibility above the bulk critical field, Hc2, as seen in conventional superconductors, a near-perfect, Meissner-like screening of low-frequency magnetic fields well above Hc2 is observed. The enhanced diamagnetism disappears at a new phase transition close to the critical field of surface superconductivity, Hc3. Using theoretical modeling, the anomalous screening is shown to be consistent with modification of surface superconductivity by the topological surface states. The possibility of detecting signatures of the surface states using macroscopic magnetization provides a new tool for the discovery and identification of topological superconductor

Magnetization Signature of Topological Surface States in a Non‐Symmorphic Superconductor

From Wiley via Jisc Publications RouterHistory: received 2021-04-28, rev-recd 2021-06-16, pub-electronic 2021-08-08Article version: VoRPublication status: PublishedFunder: European Union's Horizon 2020 research and innovation programme; Grant(s): 785219, 881603Funder: EPSRC; Id: http://dx.doi.org/10.13039/501100000266; Grant(s): EP/L01548XAbstract: Superconductors with nontrivial band structure topology represent a class of materials with unconventional and potentially useful properties. Recent years have seen much success in creating artificial hybrid structures exhibiting the main characteristics of 2D topological superconductors. Yet, bulk materials known to combine inherent superconductivity with nontrivial topology remain scarce, largely because distinguishing their central characteristic—the topological surface states—has proved challenging due to a dominant contribution from the superconducting bulk. In this work, a highly anomalous behavior of surface superconductivity in topologically nontrivial 3D superconductor In2Bi, where the surface states result from its nontrivial band structure, itself a consequence of the non‐symmorphic crystal symmetry and strong spin–orbit coupling, is reported. In contrast to smoothly decreasing diamagnetic susceptibility above the bulk critical field, Hc2, as seen in conventional superconductors, a near‐perfect, Meissner‐like screening of low‐frequency magnetic fields well above Hc2 is observed. The enhanced diamagnetism disappears at a new phase transition close to the critical field of surface superconductivity, Hc3. Using theoretical modeling, the anomalous screening is shown to be consistent with modification of surface superconductivity by the topological surface states. The possibility of detecting signatures of the surface states using macroscopic magnetization provides a new tool for the discovery and identification of topological superconductors

Novel approach to Room Temperature Superconductivity problem

A long-standing problem of observing Room Temperature Superconductivity is finally solved by a novel approach. Instead of increasing the critical temperature Tc of a superconductor, the temperature of the room was decreased to an appropriate Tc value. We consider this approach more promising for obtaining a large number of materials possessing Room Temperature Superconductivity in the near future