172 research outputs found

    Percolation in deposits for competitive models in (1+1)-dimensions

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    The percolation behaviour during the deposit formation, when the spanning cluster was formed in the substrate plane, was studied. Two competitive or mixed models of surface layer formation were considered in (1+1)-dimensional geometry. These models are based on the combination of ballistic deposition (BD) and random deposition (RD) models or BD and Family deposition (FD) models. Numerically we find, that for pure RD, FD or BD models the mean height of the percolation deposit hˉ\bar h grows with the substrate length LL according to the generalized logarithmic law hˉ(ln(L))γ\bar h\propto (\ln (L))^\gamma, where γ=1.0\gamma=1.0 (RD), γ=0.88±0.020\gamma=0.88\pm 0.020 (FD) and γ=1.52±0.020\gamma=1.52\pm 0.020 (BD). For BD model, the scaling law between deposit density pp and its mean height hˉ\bar h at the point of percolation of type pphˉ1/νhp-p_\infty \propto \bar h^{-1/\nu_h} are observed, where νh=1.74±0.02\nu_h =1.74\pm0.02 is a scaling coefficient. For competitive models the crossover, %in hh versus LL corresponding to the RD or FD -like behaviour at small LL and the BD-like behaviour at large LL are observed.Comment: 8 pages,4 figures, Latex, uses iopart.cl

    The QUinapril Ischemic Event Trial (QUIET) design and methods: Evaluation of chronic ACE inhibitor therapy after coronary artery intervention

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    The rationale, trial design, and statistical aspects of QUIET, the QUinapril Ischemic Event Trial, are described. QUIET is a prospective, double-blind placebo-controlled study that will assess the ability of the angiotensin-converting enzyme (ACE) inhibitor quinapril to reduce the rate of cardiac ischemic events and to slow or prevent the development of coronary artery atherosclerosis as assessed by serial angiography in a normolipidemic population without left ventricular dysfunction. The study began in September 1991 and has completed recruitment with 1740 patients across 38 centers (28 U.S., 4 Canada, 6 Europe) by the end of 1992. Patients are randomized to 20 mg of quinapril or placebo once daily and continue in the study for 3 years. Study completion is projected for 1995.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44614/1/10557_2004_Article_BF00878518.pd

    Impurity generation during intense lower hybrid heating experiments on the Alcator C tokamak

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    and disposal, in whole or in part by or for the United States govern-ment is permitted. By acceptance of this article, the publisher and/or recipient ac-knowledges the U.S. Government's right to retain a non-exclusive, royalty-free license in and to any copyright covering this paper. Experiments are underway on the Alcator C Tokamak with over 1 MW of RF power injected into the plasma at a frequency of 4.6 GHz to study both heating and current drive effects. During these studies, impurity genera-tion from limiter structures has been observed. The RF induced impurity influx is a strongly nonlinear function of net injected power. For Prf < 500 kW, only small effects are seen. As Prf approaches 1 MW, however, sharp increases in impurity influxes and Zeff are observed. Three different lim-iter materials have been used during these studies: molybdenum, graphite, and silicon-carbide coated graphite. In each case, the materials of the limiter structure are seen to dominate the increased impurity influx. In a typical case, with Prf = 1.0 MW e = 1.3 x 1014 cm- 3, and the SiC coated limiters, Zeff is seen to increase from 1.5 before the RF pulse to about 4 during the heating. At the same time, central Te increases from 2000 eV to 3000 eV and central Ti from 1200 eV to 1800 eV. Similar effects are seen in both H2 and D2 working gas discharges. The contribution to impurity genera-tion of nonthermal electrons, which are produced by the RF, is under investi-gation. Changes in edge plasma temperature and density, as well as the possibility that the particle transport is affected by the RF, are also being examined. Results of the experiments with the three different limiter materials are compared, and contributions of impurity radiation to the overall power balance are estimated

    Lessons We Learned Designing and Building the Chandra Telescope

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    2014 marks the crystal (15th) anniversary of the launch of the Chandra Xray Observatory. This paper offers some of the major lessons learned by some of the key members of the Chandra Telescope team. We offer some of the lessons gleaned from our experiences developing, designing, building and testing the telescope and its subsystems, with 15 years of hindsight. Among the topics to be discussed are the early developmental tests, known as VETAI and VETAII, requirements derivation, the impact of late requirements and reflection on the conservatism in the design process

    Templating hydrogels

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    Templating processes for creating polymerized hydrogels are reviewed. The use of contact photonic crystals and of non-contact colloidal crystalline arrays as templates are described and applications to chemical sensing and device fabrication are illustrated. Emulsion templating is illustrated in the formation of microporous membranes, and templating on reverse emulsions and double emulsions is described. Templating in solutions of macromolecules and micelles is discussed and then various applications of hydrogel templating on surfactant liquid crystalline mesophases are illustrated, including a nanoscale analogue of colloidal crystalline array templating, except that the bead array in this case is a cubic array of nonionic micelles. The use of particles as templates in making core-shell and hollow microgel beads is described, as is the use of membrane pores as another illustration of confinement templating

    Towards sustainable polymeric nano-carriers and surfactants: facile low temperature enzymatic synthesis of bio-based amphiphilic copolymers in scCO2

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    We demonstrate that useful bio-based amphiphilic polymers can be produced enzymatically at a mild temperature, in a solvent-free system and using renewably sourced monomers, by exploiting the unique properties of supercritical CO2 (scCO2). We present the use of a novel near-ambient temperature approach to prepare renewable amphiphilic ABA copolymers in scCO2. Bio-based commercially available monomers have been polymerised to prepare chains with targeted molecular weight. The amphiphilic materials were prepared by end-capping the synthesised polymers with methoxy poly(ethylene glycol) (MPEG) chains in a one-pot high pressure reaction utilising Candida Antarctica Lipase B (CaLB) as a catalyst at a temperature as low as 35 °C. The block copolymers are characterised by 1H-NMR, GPC and DSC in order to carefully assess their structural and thermal properties. These polymers form self-assembled aggregates in aqueous environment and these nanostructures are studied through DLS, TEM and UV-Vis. Highly hydrophobic Coumarin-6 was used as a model to prove dispersion in water of lipophilic molecules. Maximum bubble pressure tests demonstrate the reduction in surface tension of these polymers and comparisons are made directly to commercial polymeric non-ionic surfactants
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