2,435 research outputs found
Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
A variety of terminal alkynes are facilely convertible into cis-boryl(stannyl)alkenes with inverse regioselectivity to those of the previous borylstannylation by the copper-catalyzed three-component reaction using a masked diboron. The synthetic utility of the resulting boryl(stannyl)alkenes has been demonstrated by chemoselective coupling reactions
Visualization and Interpretation of Attosecond Electron Dynamics in Laser-Driven Hydrogen Molecular Ion using Bohmian Trajectories
We analyze the attosecond electron dynamics in hydrogen molecular ion driven
by an external intense laser field using ab-initio numerical simulations of the
corresponding time-dependent Schr{\"{o}}dinger equation and Bohmian
trajectories. To this end, we employ a one-dimensional model of the molecular
ion in which the motion of the protons is frozen. The results of the Bohmian
trajectory calculations do agree well with those of the ab-initio simulations
and clearly visualize the electron transfer between the two protons in the
field. In particular, the Bohmian trajectory calculations confirm the recently
predicted attosecond transient localization of the electron at one of the
protons and the related multiple bunches of the ionization current within a
half cycle of the laser field. Further analysis based on the quantum
trajectories shows that the electron dynamics in the molecular ion can be
understood via the phase difference accumulated between the Coulomb wells at
the two protons. Modeling of the dynamics using a simple two-state system leads
us to an explanation for the sometimes counter-intuitive dynamics of an
electron opposing the classical force of the electric field on the electron.Comment: 8 pages, 6 figures. The following article has been submitted to The
Journal of Chemical Physics. After it is published, it will be found at
http://jcp.aip.org
Fast Purcell-enhanced single photon source in 1,550-nm telecom band from a resonant quantum dot-cavity coupling
High-bit-rate nanocavity-based single photon sources in the 1,550-nm telecom
band are challenges facing the development of fibre-based long-haul quantum
communication networks. Here we report a very fast single photon source in the
1,550-nm telecom band, which is achieved by a large Purcell enhancement that
results from the coupling of a single InAs quantum dot and an InP photonic
crystal nanocavity. At a resonance, the spontaneous emission rate was enhanced
by a factor of 5 resulting a record fast emission lifetime of 0.2 ns at 1,550
nm. We also demonstrate that this emission exhibits an enhanced anti-bunching
dip. This is the first realization of nanocavity-enhanced single photon
emitters in the 1,550-nm telecom band. This coupled quantum dot cavity system
in the telecom band thus provides a bright high-bit-rate non-classical single
photon source that offers appealing novel opportunities for the development of
a long-haul quantum telecommunication system via optical fibres.Comment: 16 pages, 4 figure
Polycation-siRNA nanoparticles can disassemble at the kidney glomerular basement membrane
Despite being engineered to avoid renal clearance, many cationic polymer (polycation)-based siRNA nanoparticles that are used for systemic delivery are rapidly eliminated from the circulation. Here, we show that a component of the renal filtration barrier—the glomerular basement membrane (GBM)—can disassemble cationic cyclodextrin-containing polymer (CDP)-based siRNA nanoparticles and, thereby, facilitate their rapid elimination from circulation. Using confocal and electron microscopies, positron emission tomography, and compartment modeling, we demonstrate that siRNA nanoparticles, but not free siRNA, accumulate and disassemble in the GBM. We also confirm that the siRNA nanoparticles do not disassemble in blood plasma in vitro and in vivo. This clearance mechanism may affect any nanoparticles that assemble primarily by electrostatic interactions between cationic delivery components and anionic nucleic acids (or other therapeutic entities)
Measurement of the double-\beta decay half-life of ^{136}Xe with the KamLAND-Zen experiment
We present results from the KamLAND-Zen double-beta decay experiment based on
an exposure of 77.6 days with 129 kg of Xe. The measured two-neutrino
double-beta decay half-life of Xe is yr, consistent with a recent
measurement by EXO-200. We also obtain a lower limit for the neutrinoless
double-beta decay half-life, yr at 90%
confidence level (C.L.), which corresponds to almost a five-fold improvement
over previous limits.Comment: 6 pages, 4 figures. Version as published in PR
Measurement of 1.7 to 74 MeV polarised gamma rays with the HARPO TPC
Current {\gamma}-ray telescopes based on photon conversions to
electron-positron pairs, such as Fermi, use tungsten converters. They suffer of
limited angular resolution at low energies, and their sensitivity drops below 1
GeV. The low multiple scattering in a gaseous detector gives access to higher
angular resolution in the MeV-GeV range, and to the linear polarisation of the
photons through the azimuthal angle of the electron-positron pair.
HARPO is an R&D program to characterise the operation of a TPC (Time
Projection Chamber) as a high angular-resolution and sensitivity telescope and
polarimeter for {\gamma} rays from cosmic sources. It represents a first step
towards a future space instrument. A 30 cm cubic TPC demonstrator was built,
and filled with 2 bar argon-based gas. It was put in a polarised {\gamma}-ray
beam at the NewSUBARU accelerator in Japan in November 2014. Data were taken at
different photon energies from 1.7 MeV to 74 MeV, and with different
polarisation configurations. The electronics setup is described, with an
emphasis on the trigger system. The event reconstruction algorithm is quickly
described, and preliminary measurements of the polarisation of 11 MeVphotons
are shown.Comment: Proceedings VCI201
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