Hybrid TiO2 Solar Cells Produced from Aerosolized Nanoparticles of Water-Soluble Polythiophene Electron Donor Layer

Hybrid solar cells (HSCs) with water soluble polythiophene sodium poly[2-(3-thienyl)-ethyloxy-4-butylsulfonate] (PTEBS) thin films produced using electrospray deposition (ESD) were fabricated, tested, and modeled and compared to devices produced using conventional spin coating. A single device structure of FTO/TiO2/PTEBS/Au was used to study the effects of ESD of the PTEBS layer on device performance. ESD was found to increase the short circuit current density (Jsc) by a factor of 2 while decreasing the open circuit voltage (Voc) by half compared to spin coated PTEBS films. Comparable efficiencies of 0.009% were achieved from both device construction types. Current-voltage curves were modeled using the characteristic solar cell equation and showed a similar increase in generated photocurrent with an increase by two orders of magnitude in the saturation current in devices from ESD films. Increases in Jsc are attributed to an increase in the interfacial contact area between the TiO2 and PTEBS layers, while decreases in Voc are attributed to incomplete film formation from ESD

An HST/COS legacy survey of intervening SiIII absorption in the extended gaseous halos of low-redshift galaxies

Doubly ionized silicon (SiIII) is a powerful tracer of diffuse ionized gas inside and outside of galaxies. It can be observed in the local Universe in ultraviolet (UV) absorption against bright extragalactic background sources. We here present an extensive study of intervening SiIII-selected absorbers and their relation to the circumgalactic medium (CGM) of galaxies at low redshift (z<=0.1), based on the analysis of UV absorption spectra along 303 extragalactic lines of sight obtained with the Cosmic Origins Spectrograph (COS) on board the Hubble Space Telescope (HST). Along a total redshift path of Dz=24 we identify 69 intervening SiIII systems that all show associated absorption from other low and high ions. We derive a bias-corrected number density of dN/dz(SiIII)=2.5 for absorbers with column densities log N(SiIII)>12.2. We develop a geometrical model for the absorption-cross section of the CGM around the local galaxy population and find excellent agreement between the model predictions and the observations. We further compare redshifts and positions of the absorbers with that of ~64,000 galaxies using archival galaxy-survey data. For the majority of the absorbers we identify possible host galaxies within 300 km/s of the absorbers and derive impact parameters rho<200 kpc, demonstrating that the spatial distributions of SiIII absorbers and galaxies are highly correlated. Our study indicates that the majority of SiIII-selected absorbers in our sample trace the CGM of nearby galaxies within their virial radii at a typical covering fraction of ~70 per cent. From a detailed ionization model we estimate that diffuse gas in the CGM around galaxies, as traced by SiIII, contains substantially more baryonic mass than their neutral interstellar medium.Comment: 32 pages, 17 figures; final version accepted for publication in A&

Marked increase in PROP taste responsiveness following oral supplementation with selected salivary proteins or their related free amino acids

The genetic predisposition to taste 6-n-propylthiouracil (PROP) varies among individuals and is associated with salivary levels of Ps-1 and II-2 peptides, belonging to the basic proline-rich protein family (bPRP). We evaluated the role of these proteins and free amino acids that selectively interact with the PROP molecule, in modulating bitter taste responsiveness. Subjects were classified by their PROP taster status based on ratings of perceived taste intensity for PROP and NaCl solutions. Quantitative and qualitative determinations of Ps-1 and II-2 proteins in unstimulated saliva were performed by HPLC-ESI-MS analysis. Subjects rated PROP bitterness after supplementation with Ps-1 and II-2, and two amino acids (L-Arg and L-Lys) whose interaction with PROP was demonstrated by (1)H-NMR spectroscopy. ANOVA showed that salivary levels of II-2 and Ps-1 proteins were higher in unstimulated saliva of PROP super-tasters and medium tasters than in non-tasters. Supplementation of Ps-1 protein in individuals lacking it in saliva enhanced their PROP bitter taste responsiveness, and this effect was specific to the non-taster group.(1)H-NMR results showed that the interaction between PROP and L-Arg is stronger than that involving L-Lys, and taste experiments confirmed that oral supplementation with these two amino acids increased PROP bitterness intensity, more for L-Arg than for L-Lys. These data suggest that Ps-1 protein facilitates PROP bitter taste perception and identifies a role for free L-Arg and L-Lys in PROP tasting

The rapid onset of stellar bars in the baryon-dominated centers of disk galaxies

Recent observations of high-redshift galactic disks ($z\approx 1-3$) show a strong negative trend in the dark matter fraction $f_{DM}$ with increasing baryonic surface density. For this to be true, the inner baryons must dominate over dark matter in early massive galaxies, as observed in the Milky Way today. If disks are dominant at early times, we show that stellar bars form promptly within these disks, leading to a high bar fraction at early times. New JWST observations provide the best evidence to date for mature stellar bars in this redshift range. The disk mass fraction $f_{disk}$ within $R_s=2.2 R_{disk}$ is the dominant factor in determining how rapidly a bar forms. Using 3D hydro simulations of halo-disk-bulge galaxies, we confirm the "Fujii relation" for the exponential dependence of the bar formation time $\tau_{bar}$ as a function of $f_{disk}$. For $f_{disk} > 0.3$, the bar formation time declines exponentially fast with increasing $f_{disk}$. This relation is a challenge to simulators - barred models with inadequate resolution fall off this curve. Instead of Fujii's arbitrary threshold for when a bar forms, for the first time, we exploit the exponential growth timescale associated with a positive feedback cycle as the bar emerges from the underlying disk. A modified, mass-dependent trend is observed for halos relevant to systems at cosmic noon ($10.5 < \log M_{halo} < 12$), where the bar onset is slower for higher mass halos at a fixed $f_{disk}$. If baryons dominate over dark matter within $R \approx R_s$, we predict that a high fraction of bars will be found in high-redshift disks long before $z = 1$. Due to its widespread use in simulations, we investigate the Efstathiou-Lake-Negroponte criterion for bar instability: this sub-optimal parameter is inversely related to $f_{disk}$, with a secondary dependence on $M_{halo}$.Comment: 27 pages, 8 figures, 1 table - Astrophysical Journal, accepted (9 March 2023

Electrokinetic separation of co-solutes into bimodal fibers by electrospinning

Composite and chemically/physically distinct fibers of sodium poly[2-(3-thienyl)-ethoxy-4-butylsulfonate] (PTEBS) and polyethylene oxide (PEO) were formed by electrospinning from a homogeneous aqueous solution containing PTEBS and PEO co-solutes. Composite nanofibers of diameter of ∼60nm were electrospun from an aqueous solution. The addition of ammonium hydroxide (NH4OH) to the water solution resulted in “bimodal” electrospun fibers consisting of distinct large diameter white PEO fiber segments and small diameter black PTEBS fiber segments. The optical absorptionspectrum of the composite PTEBS/PEO nanofibers did not exhibit the characteristic peak around 460nm, which is present in the bulk spectrum

The problem of moisture in poultry house litter, Bulletin, no. 338

The Bulletin is a publication of the New Hampshire Agricultural Experiment Station, College of Life Sciences and Agriculture, University of New Hampshire, Durham, New Hampshire

Controlled lasing from active optomechanical resonators

Planar microcavities with distributed Bragg reflectors (DBRs) host, besides confined optical modes, also mechanical resonances due to stop bands in the phonon dispersion relation of the DBRs. These resonances have frequencies in the sub-terahertz (10E10-10E11 Hz) range with quality factors exceeding 1000. The interaction of photons and phonons in such optomechanical systems can be drastically enhanced, opening a new route toward manipulation of light. Here we implemented active semiconducting layers into the microcavity to obtain a vertical-cavity surface-emitting laser (VCSEL). Thereby three resonant excitations -photons, phonons, and electrons- can interact strongly with each other providing control of the VCSEL laser emission: a picosecond strain pulse injected into the VCSEL excites long-living mechanical resonances therein. As a result, modulation of the lasing intensity at frequencies up to 40 GHz is observed. From these findings prospective applications such as THz laser control and stimulated phonon emission may emerge

Prospective dark matter annihilation signals from the Sagittarius Dwarf Spheroidal

The Sagittarius Dwarf Spheroidal galaxy (Sgr) is investigated as a target for dark matter (DM) annihilation searches utilizing J-factor distributions calculated directly from a high-resolution hydrodynamic simulation of the infall and tidal disruption of Sgr around the Milky Way. In contrast to past studies, the simulation incorporates DM, stellar and gaseous components for both the Milky Way and the Sgr progenitor galaxy. The simulated distributions account for significant tidal disruption affecting the DM density profile. Our estimate of the J-factor value for Sgr, JSgr = 1.48 × 1010 M2☉ kpc−5 (6.46 × 1016 GeV cm−5), is significantly lower than found in prior studies. This value, while formally a lower limit, is likely close to the true J-factor value for Sgr. It implies a DM cross-section incompatibly large in comparison with existing constraints would be required to attribute recently observed gamma-ray emission from Sgr to DM annihilation. We also calculate a J-factor value using a NFW profile fitted to the simulated DM density distribution to facilitate comparison with past studies. This NFW J-factor value supports the conclusion that most past studies have overestimated the dark matter density of Sgr on small scales. This, together with the fact that the Sgr has recently been shown to emit gamma-rays of astrophysical origin, complicate the use of Sgr in indirect DM detection searches

Extracting finite structure from infinite language

This paper presents a novel connectionist memory-rule based model capable of learning the finite-state properties of an input language from a set of positive examples. The model is based upon an unsupervised recurrent self-organizing map [T. McQueen, A. Hopgood, J. Tepper, T. Allen, A recurrent self-organizing map for temporal sequence processing, in: Proceedings of Fourth International Conference in Recent Advances in Soft Computing (RASC2002), Nottingham, 2002] with laterally interconnected neurons. A derivation of functionalequivalence theory [J. Hopcroft, J. Ullman, Introduction to Automata Theory, Languages and Computation, vol. 1, Addison-Wesley, Reading, MA, 1979] is used that allows the model to exploit similarities between the future context of previously memorized sequences and the future context of the current input sequence. This bottom-up learning algorithm binds functionally related neurons together to form states. Results show that the model is able to learn the Reber grammar [A. Cleeremans, D. Schreiber, J. McClelland, Finite state automata and simple recurrent networks, Neural Computation, 1 (1989) 372–381] perfectly from a randomly generated training set and to generalize to sequences beyond the length of those found in the training set