110 research outputs found
Thermal expansion of the magnetically ordering intermetallics RTMg (R = Eu, Gd and T = Ag, Au)
We report measurements of the thermal expansion for two Eu- and two
Gd-based intermetallics which exhibit ferro- or antiferromagnetic phase
transitions. These materials show sharp positive (EuAgMg and GdAuMg) and
negative (EuAuMg and GdAgMg) peaks in the temperature dependence of the thermal
expansion coefficient which become smeared and/or displaced in an
external magnetic field. Together with specific heat data we determine the
initial pressure dependences of the transition temperatures at ambient pressure
using the Ehrenfest or Clausius-Clapeyron relation. We find large pressure
dependences indicating strong spin-phonon coupling, in particular for GdAgMg
and EuAuMg where a quantum phase transition might be reached at moderate
pressures of a few GPa.Comment: 6 pages, 3 figure
Electronic structure of AuMg and AgMg ( = Eu, Gd, Yb)
We have investigated the electronic structure of the equiatomic EuAuMg,
GdAuMg, YbAuMg and GdAgMg intermetallics using x-ray photoelectron
spectroscopy. The spectra revealed that the Yb and Eu are divalent while the Gd
is trivalent. The spectral weight in the vicinity of the Fermi level is
dominated by the mix of Mg , Au/Ag and bands, and not by the
. We also found that the Au and Ag bands are extraordinarily
narrow, as if the noble metal atoms were impurities submerged in a low density
metal host. The experimental results were compared with band structure
calculations, and we found good agreement provided that the spin-orbit
interaction in the Au an Ag bands is included and correlation effects in an
open shell are accounted for using the local density approximation +
Hubbard scheme. Nevertheless, limitations of such a mean-field scheme to
explain excitation spectra are also evident.Comment: 4 pages, 3 figures, Brief Repor
A Medium Resolution Near-Infrared Spectral Atlas of O and Early B Stars
We present intermediate resolution (R ~ 8,000 - 12,000) high signal-to-noise
H- and K-band spectroscopy of a sample of 37 optically visible stars, ranging
in spectral type from O3 to B3 and representing most luminosity classes.
Spectra of this quality can be used to constrain the temperature, luminosity
and general wind properties of OB stars, when used in conjunction with
sophisticated atmospheric model codes. Most important is the need for
moderately high resolutions (R > 5000) and very high signal-to-noise (S/N >
150) spectra for a meaningful profile analysis. When using near-infrared
spectra for a classification system, moderately high signal-to-noise (S/N ~
100) is still required, though the resolution can be relaxed to just a thousand
or two. In the appendix we provide a set of very high quality near-infrared
spectra of Brackett lines in six early-A dwarfs. These can be used to aid in
the modeling and removal of such lines when early-A dwarfs are used for
telluric spectroscopic standards.Comment: 12 pages, 3 tables, 14 figures. AASTex preprint style. To appear in
ApJS, November 2005. All spectra are available by contacting M.M. Hanso
Magnetoresistance, specific heat and magnetocaloric effect of equiatomic rare-earth transition-metal magnesium compounds
We present a study of the magnetoresistance, the specific heat and the
magnetocaloric effect of equiatomic Mg intermetallics with , Eu, Gd, Yb and , Au and of GdAuIn. Depending on the
composition these compounds are paramagnetic (, Yb) or they
order either ferro- or antiferromagnetically with transition temperatures
ranging from about 13 to 81 K. All of them are metallic, but the resistivity
varies over 3 orders of magnitude. The magnetic order causes a strong decrease
of the resistivity and around the ordering temperature we find pronounced
magnetoresistance effects. The magnetic ordering also leads to well-defined
anomalies in the specific heat. An analysis of the entropy change leads to the
conclusions that generally the magnetic transition can be described by an
ordering of localized moments arising from the half-filled
shells of Eu or Gd. However, for GdAgMg we find clear evidence
for two phase transitions indicating that the magnetic ordering sets in
partially below about 125 K and is completed via an almost first-order
transition at 39 K. The magnetocaloric effect is weak for the antiferromagnets
and rather pronounced for the ferromagnets for low magnetic fields around the
zero-field Curie temperature.Comment: 12 pages, 7 figures include
Dependence of the magnetic ordering temperature on hydorstatic pressure for the ternary intermetallic compounds GdAgMg, GdAuMg, EuAgMg, and EuAuMg
Quantum Matter and Optic
Antiferromagnetic ordering in heavy fermion system Ce2Au2Cd
La2Au2Cd and Ce2Au2Cd were prepared from the elements by reactions in sealed
tantalum tubes in a water-cooled sample chamber of an induction furnace. These
intermetallics crystallize with the tetragonal Mo2FeB2 type, space group
P4/mbm. While La2Au2Cd is Pauli paramagnetic, Ce2Au2Cd shows Curie-Weiss
behaviour above 100 K with an experimental magnetic moment of 2.41(2) muB/Ce
atom, indicating trivalent cerium. Antiferromagnetic ordering is detected for
Ce2Au2Cd at 5.01(2) K and magnetization measurements reveal a metamagnetic
transition at 3 K at a critical field of around 20 kOe with a saturation moment
of 1.50(2)muB/Ce atom at 80 kOe. The low-temperature heat capacity properties
characterize Ce2Au2Cd as a heavy fermion material with an electronic specific
heat coefficient (gamma) = 807(5) mJ/mol K2 as compared to La2Au2Cd with gamma
= 6(5) mJ/mol K2.Comment: Accepted for publication in Phys. Rev.
Unintentional high density p-type modulation doping of a GaAs/AlAs core-multi-shell nanowire
Achieving significant doping in GaAs/AlAs core/shell nanowires (NWs) is of
considerable technological importance but remains a challenge due to the
amphoteric behavior of the dopant atoms. Here we show that placing a narrow
GaAs quantum well in the AlAs shell effectively getters residual carbon
acceptors leading to an \emph{unintentional} p-type doping. Magneto-optical
studies of such a GaAs/AlAs core multi-shell NW reveal quantum confined
emission. Theoretical calculations of NW electronic structure confirm quantum
confinement of carriers at the core/shell interface due to the presence of
ionized carbon acceptors in the 1~nm GaAs layer in the shell.
Micro-photoluminescence in high magnetic field shows a clear signature of
avoided crossings of the Landau level emission line with the Landau
level TO phonon replica. The coupling is caused by the resonant hole-phonon
interaction, which points to a large 2D hole density in the structure.Comment: just published in Nano Letters
(http://pubs.acs.org/doi/full/10.1021/nl500818k
Enhanced Long-Path Electrical Conduction in ZnO Nanowire Array Devices Grown via Defect-Driven Nucleation
Vertical arrays of nanostructures have been widely used as major components in some of the most ground-breaking modern research-based devices, and ZnO nanowires have received particular attention because of their favorable electronic properties. Using a local multiprobe technique to measure the properties of individual ZnO nanowires in vertical arrays, we show for the first time that for metal-catalyzed ZnO nanowire growth the electrical contribution of individual wires to a device is highly dependent on the fate of the catalyst nanoparticle during growth. To overcome the limitations of metal-catalyzed growth, nanowires grown from a defect-driven nucleation process are shown to provide high-quality device structures with excellent long-path electrical conduction
- …